methyl 3-(2-methoxyethoxy)-2-methyl-4-nitrobenzoate | 1031359-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl 3-(2-methoxyethoxy)-2-methyl-4-nitrobenzoate
• CAS: 1031359-42-8
• 化学式: C₁₂H₁₅NO₆
• 分子量: 269.254
• InChiKey: DFODESGEAZXFQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  90.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  methyl 3-(2-methoxyethoxy)-2-methyl-4-nitrobenzoate 在 sodium tungstate 、 N,N-二甲基甲酰胺 、 sodium iodide 4-二甲氨基吡啶 、 sodium hydroxide 、 草酰氯 、 水 、 双氧水 、 potassium carbonate 、 溶剂黄146 、 三乙胺 、 丙酮氰醇 作用下， 以 四氢呋喃 、 甲醇 、 氯仿 、 水 、 N,N-二甲基甲酰胺 、 丙酮 、 乙腈 为溶剂， 反应 17.92h， 生成 1-(4-(3-(2-methoxyethoxy)-2-methyl-4-(methylsulfonyl)benzoyl)-1-methyl-1H-pyrazol-5-yloxy)ethyl ethylcarbonate
  参考文献：
  名称：

  WO2008/65907

  摘要：

  公开号：
• 作为产物：
  描述：

  2-氯乙基甲基醚 、 3-羟基-2-甲基-4-硝基苯甲酸甲酯 在 potassium iodide potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.0h， 生成 methyl 3-(2-methoxyethoxy)-2-methyl-4-nitrobenzoate
  参考文献：
  名称：

  WO2008/65907

  摘要：

  公开号：

文献信息

• BENZOYLPYRAZOLE COMPOUNDS, PROCESS FOR THEIR PRODUCTION AND HERBICIDES CONTAINING THEM
  申请人：Komyoji Terumasa

  公开号：US20100075855A1

  公开（公告）日：2010-03-25

  The present invention provides a novel herbicide showing excellent herbicidal effects, which has a wide application range including agricultural fields and non-agricultural fields and various application methods including soil treatment and foliage treatment. A benzoylpyrazole compound represented by the formula (I) or its salt: wherein R 1 is alkyl, R 2 is a hydrogen atom or alkyl, R 3 is alkyl, R 4 is alkyl or halogen, R 5 is alkyl substituted by one Y 1 , haloalkoxy, alkoxy substituted by one Y 2 , or alkoxycarbonyl, R 6 is alkylsulfonyl, A is alkylene substituted by at least one alkyl, Y 1 is alkoxy or haloalkoxy, and Y 2 is alkoxy; a process for its production; a herbicide containing it as an active ingredient; and a method for controlling undesired plants or inhibiting their growth, which comprises applying a herbicidally effective amount thereof to the undesired plants or to a place where they grow.

  本发明提供了一种新型除草剂，具有广泛的应用范围，包括农业领域和非农业领域，以及各种应用方法，包括土壤处理和叶面处理。该除草剂是一种苯甲酰吡唑化合物，表示为公式(I)或其盐：其中，R1是烷基，R2是氢原子或烷基，R3是烷基，R4是烷基或卤素，R5是被Y1取代的烷基，卤代烷氧基，被Y2取代的烷氧基或烷氧羰基，R6是烷基磺酰基，A是至少被一个烷基取代的烷基，Y1是烷氧基或卤代烷氧基，Y2是烷氧基；还提供了其制备方法、以其为活性成分的除草剂以及控制不良植物或抑制其生长的方法，其中将其施用于不良植物或它们生长的地方的除草有效量。
• Benzoylpyrazole compounds, process for their production and herbicides containing them
  申请人：Ishihara Sangyo Kaisha, Ltd.

  公开号：US08119569B2

  公开（公告）日：2012-02-21

  The present invention provides a novel herbicide showing excellent herbicidal effects, which has a wide application range including agricultural fields and non-agricultural fields and various application methods including soil treatment and foliage treatment. A benzoylpyrazole compound represented by the formula (I) or its salt: wherein R1 is alkyl, R2 is a hydrogen atom or alkyl, R3 is alkyl, R4 is alkyl or halogen, R5 is alkyl substituted by one Y1, haloalkoxy, alkoxy substituted by one Y2, or alkoxycarbonyl, R6 is alkylsulfonyl, A is alkylene substituted by at least one alkyl, Y1 is alkoxy or haloalkoxy, and Y2 is alkoxy; a process for its production; a herbicide containing it as an active ingredient; and a method for controlling undesired plants or inhibiting their growth, which comprises applying a herbicidally effective amount thereof to the undesired plants or to a place where they grow.

  本发明提供了一种新型除草剂，具有优异的除草效果，广泛适用于农田、非农田和各种施用方法，包括土壤处理和叶面处理。该除草剂化合物为苯甲酰吡唑化合物，其表示式为（I）或其盐：其中R1为烷基，R2为氢原子或烷基，R3为烷基，R4为烷基或卤素，R5为被Y1取代的烷基、卤代烷氧基、被Y2取代的烷氧基或烷氧羰基，R6为烷基磺酰基，A为至少一个烷基取代的亚烷基，Y1为烷氧基或卤代烷氧基，Y2为烷氧基；其制备方法；以及以其为活性成分的除草剂和控制不良植物或抑制其生长的方法，包括将其除草有效量施用于不良植物或其生长的地方。
• HERBICIDE CONTAINING BENZOYLPYRAZOLE COMPOUND
  申请人：Shimoharada Hiroshi

  公开号：US20100317528A1

  公开（公告）日：2010-12-16

  To provide a novel herbicide which has a wide range of applications to agricultural or non-agricultural fields and various methods for application such as soil treatment and foliage treatment and which exhibits excellent herbicidal effects. A herbicide containing a benzoylpyrazole compound represented by the formula (I) or its salt, as an active ingredient: wherein R 1 is alkyl or cycloalkyl, R 2 is a hydrogen atom or alkyl, R 3 is hydroxy, R 4 is alkyl, haloalkyl or the like, R 5 is halogen, cyano, cyanoalkyl or the like, and R 6 is haloalkyl, halogen or the like.

  提供一种新型的除草剂，具有广泛的农业或非农业领域应用和各种应用方法，如土壤处理和叶面处理，并表现出优异的除草效果。一种包含苯甲酰吡唑化合物的除草剂，所述苯甲酰吡唑化合物由式（I）或其盐表示，作为活性成分：其中，R1是烷基或环烷基，R2是氢原子或烷基，R3是羟基，R4是烷基、卤代烷基或类似物，R5是卤素、氰基、氰基烷基或类似物，R6是卤代烷基、卤素或类似物。
• US8119569B2
  申请人：——

  公开号：US8119569B2

  公开（公告）日：2012-02-21
• [EN] BENZOYLPYRAZOLE COMPOUNDS, PROCESS FOR THEIR PRODUCTION AND HERBICIDES CONTAINING THEM<br/>[FR] COMPOSÉS DE BENZOYLPYRAZOLE, LEUR PROCÉDÉ DE FABRICATION ET HERBICIDES LES CONTENANT
  申请人：ISHIHARA SANGYO KAISHA

  公开号：WO2008065907A1

  公开（公告）日：2008-06-05

  [EN] The present invention provides a novel herbicide showing excellent herbicidal effects, which has a wide application range including agricultural fields and non-agricultural fields and various application methods including soil treatment and foliage treatment. A benzoylpyrazole compound represented by the formula (I) or its salt: wherein R₁ is alkyl, R₂ is a hydrogen atom or alkyl, R₃ is alkyl, R₄ is alkyl or halogen, R₅ is alkyl substituted by one Y₁, haloalkoxy, alkoxy substituted by one Y₂, or alkoxycarbonyl, R₆ is alkylsulfonyl, A is alkylene substituted by at least one alkyl, Y₁ is alkoxy or haloalkoxy, and Y₂ is alkoxy; a process for its production; a herbicide containing it as an active ingredient; and a method for controlling undesired plants or inhibiting their growth, which comprises applying a herbicidally effective amount thereof to the undesired plants or to a place where they grow.
  [FR] La présente invention concerne un nouvel herbicide présentant d'excellents effets herbicides, qui possède une large gamme d'applications comprenant les domaines agricoles et les domaines non agricoles et divers procédés d'application comprenant un traitement du sol et un traitement du feuillage. L'invention porte sur un composé de benzoylpyrazole représenté par la formule (I) ou son sel : dans laquelle R₁ est alkyle, R₂ est un atome d'hydrogène ou alkyle, R₃ est alkyle, R₄ est alkyle ou halogène, R₅ est alkyle substitué par un Y₁, haloalcoxy, alcoxy substitué par un Y₂, ou alcoxycarbonyle, R₆ est alkylsulfonyle, A est alkylène substitué par au moins un alkyle, Y₁ est alcoxy ou haloalcoxy, et Y₂ est alcoxy ; sur un procédé de fabrication de ce composé ; sur un herbicide le contenant comme ingrédient actif ; et sur un procédé pour lutter contre les plantes non désirées ou inhiber leur croissance, qui comprend l'application d'une quantité de celui-ci efficace du point de vue herbicide, aux plantes non désirées ou à un endroit où elles poussent.