1-(4'-phenylsulfonylphenyl)benzimidazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1-(4'-phenylsulfonylphenyl)benzimidazole
• 英文别名: 1-[4-(benzenesulfonyl)phenyl]benzimidazole
• 化学式: C₁₉H₁₄N₂O₂S
• 分子量: 334.398
• InChiKey: GQUVWXHYZOOPIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  60.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(4'-phenylsulfonylphenyl)benzimidazole 在 双(三甲基硅烷基)氨基钾 作用下， 以 1,4-二氧六环 、 二氯甲烷 、 甲苯 为溶剂， 反应 32.0h， 生成 mer-tris[1-(4'-phenylsulfonylphenyl)-3-methylbenzimidazol-2-ylidene-C2,C2']-iridium(III)
  参考文献：
  名称：

  페노티아진-Ｓ-옥시드 또는 페노티아진-Ｓ,Ｓ-디옥시드 기를 함유하는 실란 및 이의 ＯＬＥＤ에서의 용도

  摘要：

  This is a patent related to a luminescent layer containing silane that includes phenothiazine S-oxide or phenothiazine S,S-dioxide, an organic light-emitting diode containing the silane, and a luminescent layer containing one or more of the silane and one or more triplet emitters. The invention also relates to a method for producing the silane according to the invention, as well as the use of the silane in the organic light-emitting diode, preferably as a matrix material and/or blocking material for triplet emitters.

  公开号：

  KR101502187B1
• 作为产物：
  描述：

  苯并咪唑 、 4-氯二苯砜 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 32.17h， 以91%的产率得到1-(4'-phenylsulfonylphenyl)benzimidazole
  参考文献：
  名称：

  페노티아진-Ｓ-옥시드 또는 페노티아진-Ｓ,Ｓ-디옥시드 기를 함유하는 실란 및 이의 ＯＬＥＤ에서의 용도

  摘要：

  This is a patent related to a luminescent layer containing silane that includes phenothiazine S-oxide or phenothiazine S,S-dioxide, an organic light-emitting diode containing the silane, and a luminescent layer containing one or more of the silane and one or more triplet emitters. The invention also relates to a method for producing the silane according to the invention, as well as the use of the silane in the organic light-emitting diode, preferably as a matrix material and/or blocking material for triplet emitters.

  公开号：

  KR101502187B1

文献信息

• SILANES CONTAINING PHENOTHIAZINE-S-OXIDE OR PHENOTHIAZINE-S,S-DIOXIDE GROUPS AND THE USE THEREOF IN OLEDS
  申请人：Langer Nicolle

  公开号：US20100187980A1

  公开（公告）日：2010-07-29

  Silanes comprising phenothiazine S-oxide or phenothiazine S,S-dioxide groups, organic light-emitting diodes comprising the inventive silanes, a light-emitting layer comprising at least one inventive silane and at least one triplet emitter, a process for preparing the inventive silanes and the use of the inventive silanes in organic light-emitting diodes, preferably as matrix materials and/or blocker materials for triplet emitters.

  本发明涉及含有苯并噻嗪S-氧化物或苯并噻嗪S，S-二氧化物基团的硅烷化合物，包括该创新硅烷化合物的有机发光二极管，其中包括至少一种创新硅烷和至少一种三重态发射体的发光层，制备该创新硅烷的方法以及在有机发光二极管中使用该创新硅烷，优选作为三重态发射体的基质材料和/或阻断材料。
• USE OF ACRIDINE DERIVATIVES AS MATRIX MATERIALS AND/OR ELECTRON BLOCKERS IN OLEDS
  申请人：Kahle Klaus

  公开号：US20100219406A1

  公开（公告）日：2010-09-02

  The present invention relates to the use of (hetero)aryl-substituted acridine derivatives as matrix materials in a light-emitting layer of organic light-emitting diodes (OLEDs) and/or in a blocking layer for electrons in organic light-emitting diodes. The present invention further relates to a light-emitting layer which comprises at least one emitter material and at least one matrix material, wherein the matrix material used is at least one (hetero)aryl-substituted acridine derivative, and to an organic light-emitting diode which comprises at least one inventive light-emitting layer, to an organic light-emitting diode which comprises at least one acridine derivative of the formula (I) in a blocking layer for electrons, and to a device selected from stationary and mobile visual display units and illumination units which comprise at least one inventive organic light-emitting diode.

  本发明涉及使用(杂)芳基取代的吖啶衍生物作为有机发光二极管(OLEDs)中发光层的基质材料和/或用于有机发光二极管中电子阻挡层的材料。本发明还涉及一种发光层，其中包含至少一种发射材料和至少一种基质材料，所使用的基质材料至少为一种(杂)芳基取代的吖啶衍生物，以及包括至少一个本发明的发光层的有机发光二极管，包括至少一种公式(I)的吖啶衍生物用于电子阻挡层的有机发光二极管，以及包括至少一个本发明的有机发光二极管的静态和移动的可视显示器和照明装置。
• Silanes containing phenothiazine-S-oxide or phenothiazine-S,S-dioxide groups and the use thereof in OLEDs
  申请人：BASF SE

  公开号：US07989091B2

  公开（公告）日：2011-08-02

  Silanes comprising phenothiazine S-oxide or phenothiazine S,S-dioxide groups, organic light-emitting diodes comprising the inventive silanes, a light-emitting layer comprising at least one inventive silane and at least one triplet emitter, a process for preparing the inventive silanes and the use of the inventive silanes in organic light-emitting diodes, preferably as matrix materials and/or blocker materials for triplet emitters.

  本发明涉及含有苯并噻吩S-氧化物或苯并噻吩S，S-二氧化物基团的硅烷化合物，包括该硅烷的有机发光二极管，其中至少一个含有该硅烷的发光层和至少一个三重态发射剂，制备该硅烷的方法以及在有机发光二极管中使用该硅烷，优选作为三重态发射剂的基质材料和/或阻挡材料。
• Use of acridine derivatives as matrix materials and/or electron blockers in OLEDs
  申请人：Kahle Klaus

  公开号：US08384068B2

  公开（公告）日：2013-02-26

  The present invention relates to the use of (hetero)aryl-substituted acridine derivatives as matrix materials in a light-emitting layer of organic light-emitting diodes (OLEDs) and/or in a blocking layer for electrons in organic light-emitting diodes. The present invention further relates to a light-emitting layer which comprises at least one emitter material and at least one matrix material, wherein the matrix material used is at least one (hetero)aryl-substituted acridine derivative, and to an organic light-emitting diode which comprises at least one inventive light-emitting layer, to an organic light-emitting diode which comprises at least one acridine derivative of the formula (I) in a blocking layer for electrons, and to a device selected from stationary and mobile visual display units and illumination units which comprise at least one inventive organic light-emitting diode.

  本发明涉及(hetero)aryl取代的吖啶衍生物在有机发光二极管（OLEDs）的发光层中作为基质材料的使用，以及在有机发光二极管中用于电子阻挡层的使用。本发明还涉及一种发光层，其包括至少一种发射材料和至少一种基质材料，其中所使用的基质材料是至少一种(hetero)aryl取代的吖啶衍生物，以及一种有机发光二极管，其包括至少一层本发明的发光层，以及一种在电子阻挡层中包含式(I)的吖啶衍生物的有机发光二极管，以及一种选自固定和移动的视觉显示器和照明装置，其包括至少一种本发明的有机发光二极管。
• SILANE ENTHALTEND PHENOTHIAZIN-S-OXID ODER PHENOTHIAZIN-S,S-DIOXID-GRUPPEN UND DEREN VERWENDUNG IN OLEDS
  申请人：BASF SE

  公开号：EP2150556A1

  公开（公告）日：2010-02-10