9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole | 1484-96-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole
• 英文别名: trans-1,2-di(9H-carbazol-9-yl)cyclobutane；trans-1,2-di(9-carbazolyl)cyclobutane；9-[(1R,2R)-2-carbazol-9-ylcyclobutyl]carbazole
• CAS: 1484-96-4
• 化学式: C₂₈H₂₂N₂
• 分子量: 386.496
• InChiKey: HGJYDHFRXRTNGV-VSGBNLITSA-N

物化性质

• 熔点：
  196-198 °C
• 沸点：
  637.5±55.0 °C(Predicted)
• 密度：
  1.26±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole 在 三氯氧磷 作用下， 以 乙醇 为溶剂， 反应 20.0h， 生成 9-(2-(3-((2-ethyl-2-phenylhydrazono)-methyl)-9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole-3-carbaldehyde N-methyl-N-phenylhydrazone
  参考文献：
  名称：

  Synthesis and Properties of Glass-Forming Hydrazones II [1]. Hydrazones Containing Bicarbazolyl Units

  摘要：

  A series of new glass-forming hydrazones containing bicarbazolyl units were synthesized starting from 9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole and 9-(6-(9H-carbazol-9-yl)-hexyl)-9H-carbazole, and their thermal properties were studied. The correlation between their inclination to form glasses and their chemical structures are discussed. The results of a preliminary investigation of the photoelectric properties of amorphous films of the title compounds are briefly reported. The highest hole drift mobility was observed for 9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole-3-carbaldehyde N,N-diphenylhydrazone; at high electric fields, it approaches 1 . 10(-3) cm(2)/VS.

  DOI：

  10.1007/s007060200032
• 作为产物：
  描述：

  N-乙烯基咔唑 在 2,4,6-tri-(p-methoxyphenyl) pyrylium tetrafluoroborate 作用下， 以 丙酮 为溶剂， 以99%的产率得到9-(2-(9H-carbazol-9-yl)-cyclobutyl)-9H-carbazole
  参考文献：
  名称：

  Synthesis of cyclobutane lignans via an organic single electron oxidant–electron relay system

  摘要：

  本文介绍了一种通过光诱导电子转移合成木质素环丁烷及其类似物的直接方法。该方法采用了多种含氧烯烃，以提供具有完全区域控制的末端或取代环丁烷加合物，从而产生具有反式立体化学性质的环加合物。将芳香族电子中继器（ER）的加入是最大限度地减少竞争性环化反应的关键。这种方法已用于合成天然产物木犀草素和佩鲁西丁 A。

  DOI：

  10.1039/c3sc50643f

文献信息

• DIHETERO AMINES IN ELECTRICALLY CONDUCTIVE POLYMER COMPOSITIONS
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20190097137A1

  公开（公告）日：2019-03-28

  Disclosed are electrically conductive polymer compositions, and their use in organic electronic devices. The electrically conductive polymer compositions include an intrinsically electrically conductive polymer having Formula II: In Formula II: Q is the same or different at each occurrence and is S, P, Se, Te, O, P═O, or NR o ; R o is the same or different at each occurrence and is H, D, alkyl, deuterated alkyl, aryl, or deuterated aryl; R, R′, and R″ are the same or different at each occurrence and are H, D, alkyl, alkoxy, ether, polyether, fluoroalkyl, aryl, aryloxy, heteroaryl, silyl, siloxane, siloxy, germyl, deuterated alkyl, deuterated partially-fluorinated alkyl, deuterated alkoxy, deuterated ether, deuterated polyether, deuterated aryl, deuterated heteroaryl, deuterated silyl, deuterated siloxane, deuterated siloxy, and deuterated germyl; wherein two R′ groups can together represent a single bond which forms a fused ring; with the proviso that any non-H/D group may be terminated by a functional group selected from the group consisting of hydroxyl, alcohol, alkoxy, ether, amine, amide, ester, carboxylic acid, sulfonic acid, phosphate, or deuterated analogs thereof; m is an integer from 1 - 5; n is an integer from 1 - 5; and o is an integer from 2 - 2000. The electrically conducting polymer is doped with a non-fluorinated acid polymer.

  揭示了电导聚合物组合物及其在有机电子器件中的应用。电导聚合物组合物包括具有化学式II的固有电导性聚合物： 在化学式II中：Q在每次出现时相同或不同，为S、P、Se、Te、O、P═O或NR o ；R o 在每次出现时相同或不同，为H、D、烷基、氘代烷基、芳基或氘代芳基；R、R′和R″在每次出现时相同或不同，为H、D、烷基、烷氧基、醚、聚醚、氟烷基、芳基、芳氧基、杂芳基、硅基、硅氧烷、硅氧基、锗基、氘代烷基、氘代部分氟代烷基、氘代烷氧基、氘代醚、氘代聚醚、氘代芳基、氘代杂芳基、氘代硅基、氘代硅氧烷、氘代硅氧基和氘代锗基；其中两个R′基可共同表示形成融合环的单键；但任何非H/D基可能由羟基、醇、烷氧基、醚、胺、酰胺、酯、羧酸、磺酸、磷酸酯或其氘代类似物中选择的官能团终止；m为整数，范围为1-5；n为整数，范围为1-5；o为整数，范围为2-2000。该电导聚合物掺杂有非氟酸聚合物。
• Ketopyrroles useful as ligands in organic iridium compositions
  申请人：Chichak Kelly Scott

  公开号：US20080027028A1

  公开（公告）日：2008-01-31

  The present invention provides novel ketopyrroles having structure XXIV wherein R 2 is independently at each occurrence a deuterium atom, a halogen, a nitro group, an amino group, a C 3 -C 40 aromatic radical, a C 1 -C 50 aliphatic radical, or a C 3 -C 40 cyclcoaliphatic radical; “a” is an integer from 0 to 3; and X 1 and X 2 are independently at each occurrence a bromine atom, a hydroxy group, or the group OR 10 , and wherein the group R 10 is independently at each occurrence a deuterium atom, a halogen, a nitro group, an amino group, a C 3 -C 40 aromatic radical, a C 1 -C 50 aliphatic radical, or a C 3 -C 40 cyclcoaliphatic radical. Ketopyrroles XXIV are useful ligands for the preparation of Type (1) and Type (2) organic iridium compositions. In one aspect, the present invention provides deuterated analogs of XXIV. Organic iridium compositions are useful in the preparation optoelectronic devices, such as OLED devices and photovoltaic devices exhibiting enhanced performance characteristics.

  本发明提供了具有结构XXIV的新型酮吡咯，其中R2在每次出现时独立地是氘原子、卤素、硝基、氨基、C3-C40芳香基、C1-C50脂肪基或C3-C40环脂基；“a”是从0到3的整数；X1和X2在每次出现时独立地是溴原子、羟基或基团OR10，其中基团R10在每次出现时独立地是氘原子、卤素、硝基、氨基、C3-C40芳香基、C1-C50脂肪基或C3-C40环脂基。酮吡咯XXIV是用于制备类型（1）和类型（2）有机铱配合物的有用配体。在一个方面，本发明提供了XXIV的氘代物。有机铱配合物在制备光电子器件方面很有用，例如OLED器件和光伏器件，表现出增强的性能特征。
• COMPOUND COMPRISING PHENYL PYRIDINE UNITS
  申请人：Ye Qing

  公开号：US20090289547A1

  公开（公告）日：2009-11-26

  Organic compounds of formula I may be used in optoelectronic devices wherein R 1 is, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; R2 is, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; b is, independently at each occurrence, an integer ranging from 0-3; Ar 1 is a direct bond or heteroaryl, aryl, or alkyl or cycloalkyl; Ar 2 is heteroaryl, aryl, or alkyl or cycloalkyl; c is 0, 1 or 2; and n is an integer ranging from 2-4.

  化学式I的有机化合物可用于光电子器件，其中R1在每次出现时独立地是C1-C20脂肪基、C3-C20芳香基或C3-C20环脂肪基；R2在每次出现时独立地是C1-C20脂肪基、C3-C20芳香基或C3-C20环脂肪基；a在每次出现时独立地是0-4之间的整数；b在每次出现时独立地是0-3之间的整数；Ar1是直接键或杂环芳基、芳基、烷基或环烷基；Ar2是杂环芳基、芳基、烷基或环烷基；c为0、1或2；n是2-4之间的整数。
• USE OF PT-AND PD-BIS-AND TETRA-CARBON COMPLEXES WITH BRIDGED CARBON LIGANDS IN OLEDS
  申请人：Strassner Thomas

  公开号：US20090326237A1

  公开（公告）日：2009-12-31

  The use of Pt- and Pd-bis- and tetracarbene complexes with bridged carbene ligands in organic light-emitting diodes, organic light-emitting diodes comprising at least one aforementioned Pt- or Pd-carbene complex, at least one transition metal-carbene complex of the general formula I and/or II, organic light-emitting diodes where the at least one transition metal-carbene complex of the general formula I and/or II is present in the light-emitting layer, a blocking layer for electrons, a blocking layer for excitons and/or a blocking layer for holes, a light-emitting layer comprising at least one aforementioned Pt- or Pd-carbene complex, organic light-emitting diodes comprising at least one inventive light-emitting layer, and devices which comprise at least one inventive organic light-emitting diode.

  在有机发光二极管中使用具有桥联卡宾配体的Pt和Pd双和四卡宾配合物，包括至少一种上述Pt或Pd卡宾配合物的有机发光二极管，至少一种通式I和/或II的过渡金属卡宾配合物，其中至少一种通式I和/或II的过渡金属卡宾配合物存在于发光层中的有机发光二极管，用于电子的阻挡层，用于激子和/或空穴的阻挡层，包括至少一种上述Pt或Pd卡宾配合物的发光层，包括至少一种创新发光层的有机发光二极管，以及包括至少一种创新有机发光二极管的器件。
• 9,10-Dicyanoanthracene-sensitized photo-oxygenation of trans-1,2-di-(carbazol-9-yl)cyclobutane via electron-transfer
  作者：Kazuhiko Mizuno、Kazuhiro Murakami、Nobuhiro Kamiyama、Yoshio Otsuji

  DOI：10.1039/c39830000462

  日期：——

  9,10-Dicyanoanthracene-sensitized photo-oxygenation of trans-1,2-di(carbazol-9-yl)cyclobutane in acetonitrile efficiently affords 3,6-di(carbazol-9-yl)-1,2-dioxan.

  在乙腈中对反式-1,2-二（咔唑-9-基）环丁烷进行9,10-二氰基蒽敏感的光氧合可有效提供3,6-二（咔唑-9-基）-1,2-二恶烷。