3-aminopropyl(p-methoxyphenyl)telluride | 166830-96-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-aminopropyl(p-methoxyphenyl)telluride
• 英文别名: 3-(4-methoxyphenyltelluro)propylamine；(4-methoxyphenyltelluro)propylamine；4-(methoxyphenyltelluro)propylamine；3-(4-Methoxyphenyl)tellanylpropan-1-amine
• CAS: 166830-96-2
• 化学式: C₁₀H₁₅NOTe
• 分子量: 292.835
• InChiKey: YSKVMGWUBOGDGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-aminopropyl(p-methoxyphenyl)telluride 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 24.0h， 生成 2-[1-(3-(4-methoxyphenyltellanyl)propylamino)ethyl]phenol
  参考文献：
  名称：

  四种对称和不对称有机碲 (II) 化合物的合成、光谱表征：4-MeOC6H4TeCH2CH2CH2N=C(CH3)C6H4-2- 的 X 射线晶体结构中的 O-H…N、CH…π 和 CH…O 二次相互作用OH (1) 和 Te[CH2CH2CH2N=C(CH3)C6H4-2-

  摘要：

  3-(4-甲氧基苯基碲)丙胺和双(3-氨基丙基)碲化物与2-羟基苯乙酮缩合形成两个席夫碱2-[1-(3-(4-甲氧基苯基碲基)丙基亚氨基)乙基]苯酚(1)和Bis分别为 2-[1-(3-亚氨基丙基四烯丙基)乙基]苯酚 (2)。1 和 2 的还原分别得到化合物 2-[1-(3-(4-甲氧基苯基四氢萘基)丙基氨基)乙基]苯酚 (3) 和双 2-[1-(3-氨基丙基四氢萘基)乙基]苯酚 (4)。这四种新的有机碲化合物 (1-4) 通过 1H 和 13C NMR 和 FTIR 光谱以及原子吸收分光光度计 (AAS) (Te) 进行表征。通过元素分析（C、H 和 N）确定了 1 和 2 的电导和分子量以及组成。化合物4还通过13C DEPT-135 NMR光谱表征。化合物1和3是不对称的，2和4是对称型碲醚。生长了1和2的单晶，通过单晶X射线衍射确定了它们的分子结构。发现 1 中的 ArC-Te 键长为

  DOI：

  10.1002/hc.21262
• 作为产物：
  描述：

  bis(4-methoxyphenyl)ditelluride 、 3-氯丙胺盐酸盐 在 sodium tetrahydroborate 、 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成 3-aminopropyl(p-methoxyphenyl)telluride
  参考文献：
  名称：

  四种对称和不对称有机碲 (II) 化合物的合成、光谱表征：4-MeOC6H4TeCH2CH2CH2N=C(CH3)C6H4-2- 的 X 射线晶体结构中的 O-H…N、CH…π 和 CH…O 二次相互作用OH (1) 和 Te[CH2CH2CH2N=C(CH3)C6H4-2-

  摘要：

  3-(4-甲氧基苯基碲)丙胺和双(3-氨基丙基)碲化物与2-羟基苯乙酮缩合形成两个席夫碱2-[1-(3-(4-甲氧基苯基碲基)丙基亚氨基)乙基]苯酚(1)和Bis分别为 2-[1-(3-亚氨基丙基四烯丙基)乙基]苯酚 (2)。1 和 2 的还原分别得到化合物 2-[1-(3-(4-甲氧基苯基四氢萘基)丙基氨基)乙基]苯酚 (3) 和双 2-[1-(3-氨基丙基四氢萘基)乙基]苯酚 (4)。这四种新的有机碲化合物 (1-4) 通过 1H 和 13C NMR 和 FTIR 光谱以及原子吸收分光光度计 (AAS) (Te) 进行表征。通过元素分析（C、H 和 N）确定了 1 和 2 的电导和分子量以及组成。化合物4还通过13C DEPT-135 NMR光谱表征。化合物1和3是不对称的，2和4是对称型碲醚。生长了1和2的单晶，通过单晶X射线衍射确定了它们的分子结构。发现 1 中的 ArC-Te 键长为

  DOI：

  10.1002/hc.21262

文献信息

• Schiff bases of 1′-hydroxy-2′-acetonaphthone containing chalcogen functionalities and their complexes with and (p-cymene)Ru(II), Pd(II), Pt(II) and Hg(II): Synthesis, structures and applications in C–C coupling reactions
  作者：Arun Kumar、Monika Agarwal、Ajai K. Singh

  DOI：10.1016/j.jorganchem.2008.07.024

  日期：2008.11

  single-crystal structures of ligands L1, L3 and L6 and complexes of Pd(II) with L1, L2, L3 and L5 have been determined. The geometry of Pd is close to square planar in all the complexes and the ligands coordinate in a uni-negative tridentate mode. The Pd–N bond lengths are in the range 1.996(7)–2.019(5) Ǻ. The Pd–Se bond distance is 2.3600(5) Ǻ whereas Pd–Te is 2.5025(7) Ǻ. The Pd(II) complexes of L1–L5

  含硫族元素官能团的1'-羟基-2'-丙酮萘（HAN）的席夫碱，1-HO–C 10 H 6 -2-CH 3）CN–（CH 2）n EC 6 H 4 -4-R（R = H或OMe；n  = 2或3；已合成E = S（L 1 - L 2），Se（L 3 - L 4）或Te（L 5 - L 6），产率为90-95％。它们显示出特征1 H，13 C 1 H} 77 Se 1H}和125 Te 1 H}（分别在硒化和碲化的情况下）的NMR光谱。研究了它们与Pd（II），Pt（II），Hg（II）和（p- Cymene）Ru（II）的络合作用。配体L 1，L 3和L 6的单晶结构以及Pd（II）与L 1，L 2，L 3和L 5的配合物已经确定。在所有络合物中，Pd的几何形状均接近于正方形平面，并且配体以单负三齿模式进行配位。Pd–N键的长度范围为1.996（7）–2.019（5）range。Pd-Se的键距为2
• Pd(II)-complexes of telluro-substituted Schiff base ligands: Effect of the pendant alkyl group on Suzuki and Heck coupling through in situ generated palladium nanoparticles
  作者：Poonam Kaswan、Nisha Yadav、Divya Choudhary、Chandra Mohan Srivastava、Bharat Kumar、Jahangeer Ahmed、Gyandshwar Kumar Rao

  DOI：10.1016/j.ica.2023.121671

  日期：2023.10

  been carried out using multinuclear NMR and elemental analysis. The ligand L2 showed a Smectic liquid crystalline phase and melts at 81 °C into isotropic liquid whereas L1 and complexes (1/2) did not show any liquid crystalline property. The square planar Pd(II)-complexes (1/2) have been formed through the coordination of ligands (L1/L2) respectively in mono-anionic tridentate mode (Te,N,O−) and the

  合成了两种具有不同侧链碳链（L1中的−Me 和L2中的−C 10 H 21 ）的碲取代席夫碱L1 / L2及其相应的方形平面Pd(II)-配合物( 1/2 ) 及其结构使用多核核磁共振和元素分析进行​​了表征。配体L2显示出近晶液晶相，并在 81 °C 时熔化成各向同性液体，而L1和配合物 ( 1 / 2 ) 则不显示任何液晶特性。方形平面 Pd(II) 配合物 ( 1 / 2）通过配体（L1 / L2）分别以单阴离子三齿模式（Te，N，O -）配位形成，钯中心的第四配位层被氯离子占据。两种配合物1 / 2（1 至 2 mol%）均已 作为 Suzuki 和 Heck 偶联反应的催化剂进行了检验，其活性很大程度上取决于烷基侧链的长度。从Hg-/PPh 3中毒和Suzuki-Miyaura耦合的三相测试获得的结果表明受配体或其片段保护的均质和异质钯物质的参与。
• Synthesis and multinuclear NMR studies of 3-aminopropyl(aryl)chalcogenides, NH2CH2CH2CH2EAr (E = Se, Te), and their complexes with Pt(II) and Pd(II)
  作者：Anju Khanna、Anju Bala、B.L. Khandelwal

  DOI：10.1016/0022-328x(95)05403-c

  日期：1995.5

  The asymmetric ligands, 3-aminopropyl(aryl)tellurides (1a, 1b) [Ar = Ph (a); C6H4-OMe (b)] and 3-aminopropyl(phenyl)selenide (2) and their complexes with platinum(II) and palladium(II), viz. [PtCl2(1a, 1b)] (3, 4), [PtCl2(2)] (5), [PdCl2(1a, 1b)] (6, 7), [PdCl2(2)] (8), [(Me)ClPd(1b)] (9) and [(Me)ClPd(1b)(2)](10) have been made and characterized. Complexes 3-8, have square planar geometry around the metal (Pd or Pt) with the (Te,N)- or (Se,N)-ligand coordinated in a bidentate mode and the two chlorines cis to each other. Complex 9 also has a square planar geometry, with Me trans to nitrogen and Cl trans to tellurium. In complex 10 where Pd appears to be in a square planar geometry the two tellurium atoms are judged to be trans to each other.
• Organoselenium/Tellurium-Bearing Macroacyclic and Cyclic Ligand Systems and Their Complexation Reactions
  作者：M. Nasim、S. K. Tripathi、S. B. Mishra、B. L. Khandelwal

  DOI：10.1080/10426500590906229

  日期：2005.2.23

  A series of phenol-substitated acyclic Schiff bases, 2,6-RE(CH2)(n)N=C(CH3)](2)C6H2(4-CH3)(OH), (E = Te: R = C6H5, n = 2(L-a), 3(L-b); R = C6H4-4-OCH3, n = 2(L-c), 3(L-d);E = Se:R C6H5, n = 2(L-e), 3(L-f)), of the type E2N2O have been synthesized by condensation of 2,6-diacetyl-4-methylphenol with arylchalcogenoalkylamines. This ligand framework is useful for designing molecular complexes with a variety of coordination modes depending upon the nature of the central metal atom. The reactivity of the tellurium-bearing macroacyclics ligands towards Zn(II), Cd(II), and Hg(II) has been exantined. The ligands L-a-L-d with Zn(II) and Cd(II), and only L-a and L-b with Hg(II) form complexes of composition M2XAL, (X = Cl or Br), whereas L-c and L-d with Hg(II) give products of composition HgBr2L. The modes of ligand interaction with Zn(II) and Cd(II) are different than that with Hg(II).Following a multistep reaction involving abstraction of bridged Br atoms and subsequent addition of more ligand, the mercury complex, Hg2Br4L has been used for developing metallocyclic system of the type [Hg2Br2L2](2+). The latter has been found to encapsulate Zn(II) and Cd(II) to give multimetallic systems.
• Dichloromethane assisted oxidation of Pt(O) via cleavage of TeCARYL bond of an asymmetric telluride leading to the formation of trans-[PtCl(Ar)(PPh3)2]
  作者：Anju Khanna、B.L. Khandelwal、Ajay K. Saxena、T.P. Singh

  DOI：10.1016/0277-5387(95)00131-b

  日期：1995.9

  3-Aminopropyl (aryl) tellurides react with [Pt(PPh(3))(2)(C2H4)] in dichloromethane to form tellurium-free platinum(II) complexes [PtCl(Ar)(PPh(3))(2)] [Ar = Ph(A), C6H4-4-OMe(A')] along with Te(CH2Cl) (CH2)(3)NH2)(B). The presence of Cl in the products clearly establishes the involvement of dichloromethane in the reaction. A free radical mechanism, involving Cl . and CH2Cl . radicals from dichloromethane has been proposed for the reaction. The products have been characterized by H-1, P-31H-1} and Pt-195H-1} NMR and IR spectra. The structures of A and A' have been determined by X-ray crystallography. The crystals belong to the orthorhombic crystal system, space group Pbca. The structure of the complex A' has been described in detail. It adopts a square planar arrangement of the ligands around the Pt atom. The P-Pt-P angle is 173.3(1)degrees, indicating the trans arrangement of the two triphenylphosphine groups around Pt. The Pt-Cl distance is 2.40(4) Angstrom and the Pt-C(1) distance is 2.01(1) Angstrom, whereas the Pt-P(1) and Pt-P(2) distances are 2.318(5) and 2.306(5) Angstrom, respectively. The square plane formed by P(1)ClP(2)C(1) is inclined at 70.0(5)degrees with respect to the plane of the six-membered ring attached to the Pt atom.