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(E)-4-oxodec-2-enoic acid | 86303-05-1

中文名称
——
中文别名
——
英文名称
(E)-4-oxodec-2-enoic acid
英文别名
β-Oenanthoylacrylsaeure;4-oxo-dec-2t-enoic acid;4-oxo-dec-2-enoic acid;4-Oxo-dec-2t-ensaeure;4-Oxo-dec-2-ensaeure;e-4-Oxodec-2-enoic acid
(E)-4-oxodec-2-enoic acid化学式
CAS
86303-05-1
化学式
C10H16O3
mdl
——
分子量
184.235
InChiKey
GRJDSDYCDCWOJW-BQYQJAHWSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    2.2
  • 重原子数:
    13
  • 可旋转键数:
    7
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.6
  • 拓扑面积:
    54.4
  • 氢给体数:
    1
  • 氢受体数:
    3

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为产物:
    参考文献:
    名称:
    Random Packs and Their Use in Modeling Heterogeneous Solid Propellant Combustion
    摘要:
    It is shown that random packs of spheres of various sizes can be constructed that model ammonium-perchloratein-binder propellants in the sense that both the size distributions and the packing fractions of industrial propellant packs can be matched, Strategies for dealing with fractional numbers of large particles are addressed, as are strategies for dealing with a large number of very fine particles (fine powder), Fine powder is necessary in a three-dimensional pack to achieve the required stoichiometric ratio of ammonium perchlorate to fuel binder, but is not necessary in a two-dimensional (disk) pack, Some preliminary calculations of the two-dimensional combustion field supported by a disk pack are presented, in which full coupling between the gas phase, the condensed phase, and the retreating nonplanar propellant surface is accounted for.
    DOI:
    10.2514/2.5820
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文献信息

  • Allylic Oxidations Catalyzed by Dirhodium Catalysts under Aqueous Conditions
    申请人:Doyle Michael P.
    公开号:US20090093638A1
    公开(公告)日:2009-04-09
    The present invention relates to compositions and methods for achieving the efficient allylic oxidation of organic molecules, especially olefins and steroids, under aqueous conditions. The invention concerns the use of dirhodium (II,II) “paddlewheel complexes, and in particular, dirhodium carboximate and tert-butyl hydroperoxide as catalysts for the reaction. The use of aqueous conditions is particularly advantageous in the allylic oxidation of 7-keto steroids, which could not be effectively oxidized using anhydrous methods, and in extending allylic oxidation to enamides and enol ethers.
    本发明涉及在水相条件下实现有机分子的高效烯丙基氧化的组合物和方法,特别是烯烃和类固醇。该发明涉及使用二铑(II,II)“桨轮”配合物,特别是二铑羧酸酯和叔丁基过氧化氢作为催化剂进行反应。在烯丙基氧化7-酮类固醇中使用水相条件特别有优势,无法使用无水方法有效氧化,以及将烯丙基氧化扩展到烯酰胺和烯醇醚。
  • Ernest; Jelinkova, Collection of Czechoslovak Chemical Communications, 1959, vol. 24, p. 3341,3345
    作者:Ernest、Jelinkova
    DOI:——
    日期:——
  • Meldrum's acid ? A reagent for the synthesis of unsaturated ?-lactones and ?-acylacrylic acids
    作者:S. I. Zav'yalov、A. G. Zavozin、N. E. Kravchenko
    DOI:10.1007/bf00961384
    日期:1991.5
    The thermal cyclization of 2,2-dimethyl-5-(2-aryl-2-oxoethyl)-1,3-dioxan-4,6-diones forms 5-aryl-beta, gamma-butenolides. Regioselective chlorination of 2,2-di-methyl-5-[2-aryl(alkyl)-2-oxoethyl]-1,3-dioxane-4,6-diones by SO2Cl2 gives the 5-chloro derivatives; these are cleaved by aqueous AcOH to the E-beta-acylacrylic acids, which are synthones for unsaturated gamma-lactones.
  • US4990331A
    申请人:——
    公开号:US4990331A
    公开(公告)日:1991-02-05
  • Random Packs and Their Use in Modeling Heterogeneous Solid Propellant Combustion
    作者:S. Kochevets、J. Buckmaster、T. L. Jackson、A. Hegab
    DOI:10.2514/2.5820
    日期:2001.7
    It is shown that random packs of spheres of various sizes can be constructed that model ammonium-perchloratein-binder propellants in the sense that both the size distributions and the packing fractions of industrial propellant packs can be matched, Strategies for dealing with fractional numbers of large particles are addressed, as are strategies for dealing with a large number of very fine particles (fine powder), Fine powder is necessary in a three-dimensional pack to achieve the required stoichiometric ratio of ammonium perchlorate to fuel binder, but is not necessary in a two-dimensional (disk) pack, Some preliminary calculations of the two-dimensional combustion field supported by a disk pack are presented, in which full coupling between the gas phase, the condensed phase, and the retreating nonplanar propellant surface is accounted for.
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