N-[(1R,2S)-2-methyl-1-indanyl]-2-methoxyacetamide | 730980-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: N-[(1R,2S)-2-methyl-1-indanyl]-2-methoxyacetamide
• 英文别名: 2-methoxy-N-[(1R,2S)-2-methyl-2,3-dihydro-1H-inden-1-yl]acetamide
• CAS: 730980-61-7
• 化学式: C₁₃H₁₇NO₂
• 分子量: 219.283
• InChiKey: VENDXJOYXQORBH-TVQRCGJNSA-N

物化性质

• 沸点：
  392.3±31.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-[(1R,2S)-2-methyl-1-indanyl]-2-methoxyacetamide 在 盐酸 、 水 作用下， 以 乙醇 为溶剂， 反应 12.0h， 生成 (1R,2S)-1-amino-2-methylindane hydrochloride
  参考文献：
  名称：

  Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators

  摘要：

  氨基-1,3,5-三嗪经手性双环基团N-取代，其制备方法，组合物及其作为除草剂和植物生长调节剂的用途。该发明涉及化学式(I)或其盐的光学活性化合物：其中各符号如描述中定义，其制备方法，组合物及其作为除草剂或植物生长调节剂的用途。该发明还涉及描述中定义的化学式(III)、(V)和(XIII)的新中间体。

  公开号：

  US20040157739A1
• 作为产物：
  描述：

  trans-1-amino-2-methylindane 、 甲氧基乙酸甲酯 在 Novozym 435 盐酸 作用下， 以 甲基叔丁基醚 、 乙醇 、 二氯甲烷 为溶剂， 反应 4.0h， 生成 N-[(1R,2S)-2-methyl-1-indanyl]-2-methoxyacetamide 、 (1S,2R)-1-amino-2-methylindane hydrochloride
  参考文献：
  名称：

  Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators

  摘要：

  氨基-1,3,5-三嗪经手性双环基团N-取代，其制备方法，组合物及其作为除草剂和植物生长调节剂的用途。该发明涉及化学式(I)或其盐的光学活性化合物：其中各符号如描述中定义，其制备方法，组合物及其作为除草剂或植物生长调节剂的用途。该发明还涉及描述中定义的化学式(III)、(V)和(XIII)的新中间体。

  公开号：

  US20040157739A1

文献信息

• Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators.
  申请人：Bayer CropScience AG

  公开号：EP2305655A2

  公开（公告）日：2011-04-06

  Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators. The invention relates to an optically active compound of formula (I) or a salt thereof: wherein the various symbols are as defined in the description, to proceses for their preparation, to compositions thereof, and to their use as herbicides or plant growth regulators. The invention also relates to novel intermediates of formula (III), (V) and (XIII) as defined in the description.

  N-取代手性双环基的氨基-1,3,5-三嗪、其制备工艺、其组合物及其作为除草剂和植物生长调节剂的用途。 本发明涉及一种具有光学活性的式 (I) 化合物或其盐： 其中各种符号如描述中所定义，涉及其制备工艺、其组合物及其作为除草剂或植物生长调节剂的用途。本发明还涉及如描述中所定义的式 (III)、(V) 和 (XIII) 的新型中间体。
• AMINO 1, 3, 5-TRIAZINES N-SUBSTITUTED WITH CHIRAL BICYCLIC RADICALS, PROCESS FOR THEIR PREPARATION, COMPOSITIONS THEREOF AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS
  申请人：Bayer CropScience GmbH

  公开号：EP1592674A1

  公开（公告）日：2005-11-09
• US8114991B2
  申请人：——

  公开号：US8114991B2

  公开（公告）日：2012-02-14
• [EN] AMINO 1, 3, 5-TRIAZINES N-SUBSTITUTED WITH CHIRAL BICYCLIC RADICALS, PROCESS FOR THEIR PREPARATION, COMPOSITIONS THEREOF AND THEIR USE AS HERBICIDES AND PLANT GROWTH REGULATORS<br/>[FR] AMINO-1, 3, 5-TRIAZINES N-SUBSTITUEES AVEC DES RADICAUX BICYCLIQUES CHIRAUX, PROCEDE PERMETTANT LEUR PREPARATION, COMPOSITIONS LES CONTENANT ET LEUR UTILISATION EN TANT QU'HERBICIDES ET REGULATEURS DE CROISSANCE VEGETALE
  申请人：BAYER CROPSCIENCE GMBH

  公开号：WO2004069814A1

  公开（公告）日：2004-08-19

  The invention relates to an optically active compound of formula (I) or a salt thereof, wherein the various symbols are as defined in the description, to processes for their preparation, to compositions thereof, and to their use as herbicides or plant growth regulators. The invention also relates to novel intermediates of formula (III), (V) and (XIII) as defined in the description.
• Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators
  申请人：——

  公开号：US20040157739A1

  公开（公告）日：2004-08-12

  Amino-1,3,5-triazines N-substituted with chiral bicyclic radicals, process for their preparation, compositions thereof, and their use as herbicides and plant growth regulators. The invention relates to an optically active compound of formula (I) or a salt thereof: 1 wherein the various symbols are as defined in the description, to proceses for their preparation, to compositions thereof, and to their use as herbicides or plant growth regulators. The invention also relates to novel intermediates of formula (III), (V) and (XIII) as defined in the description.

  氨基-1,3,5-三嗪经手性双环基团N-取代，其制备方法，组合物及其作为除草剂和植物生长调节剂的用途。该发明涉及化学式(I)或其盐的光学活性化合物：其中各符号如描述中定义，其制备方法，组合物及其作为除草剂或植物生长调节剂的用途。该发明还涉及描述中定义的化学式(III)、(V)和(XIII)的新中间体。