中文名称 | 英文名称 | CAS号 | 化学式 | 分子量 |
---|---|---|---|---|
对氯苯乙酸乙酯 | 4-chloro-benzeneacetic acid, ethyl ester | 14062-24-9 | C10H11ClO2 | 198.649 |
4-氯苯甲酰甲酸乙酯 | ethyl 2-(4-chlorophenyl)-2-oxoacetate | 34966-48-8 | C10H9ClO3 | 212.633 |
对氯苯乙酸 | 4-chlorophenylacetic Acid | 1878-66-6 | C8H7ClO2 | 170.595 |
中文名称 | 英文名称 | CAS号 | 化学式 | 分子量 |
---|---|---|---|---|
—— | 2-(4-chlorophenyl)-acrylic acid | 51747-43-4 | C9H7ClO2 | 182.606 |
—— | 2-(4-chlorophenyl)acryloyl chloride | —— | C9H6Cl2O | 201.052 |
Rhodium-catalyzed C–H allylation of acrylamide derivatives with various allyl acetates was reported. The use of weakly coordinating directing group resulted in high reaction efficiency and excellent γ-selectivity. This reaction displays broad functional group tolerance, which opens a new synthetic pathway for the access of functionalized 1,4-diene skeletons.