1-O-ethyl 3-O-(2-methylpropyl) propanedioate | 57218-62-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-O-ethyl 3-O-(2-methylpropyl) propanedioate
• CAS: 57218-62-9
• 化学式: C₉H₁₆O₄
• 分子量: 188.224
• InChiKey: RKUGYQABTFQPPR-UHFFFAOYSA-N

物化性质

• 沸点：
  219.6±8.0 °C(Predicted)
• 密度：
  1.020±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  丙二酸单乙酯 、 氯甲酸异丁酯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以93%的产率得到1-O-ethyl 3-O-(2-methylpropyl) propanedioate
  参考文献：
  名称：

  丙二酸半酯的温和，快速和便捷的酯化反应

  摘要：

  描述了一种新的丙二酸半酯与氯甲酸酯酯化的方法。反应进行混合酸酐，然后自发脱羧。

  DOI：

  10.1016/s0040-4039(00)98555-1

文献信息

• Blocked isocyanate group-containing resin composition and thermosetting composition containing the same
  申请人：Kansai Paint Co., Ltd.

  公开号：EP1236751A1

  公开（公告）日：2002-09-04

  A blocked isocyanate group-containing resin composition and a thermosetting resin composition using the same that comprise a resin (C) obtainable by modifying a resin (A) having two or more blocked isocyanate groups of a specific molecular structure in one molecule with a specific monohydric alcohol (B), and by replacing the substituent of the blocked isocyanate groups with a group having a larger number of carbon atoms, thereby lowering solubility parameter value. The compositions exhbit good storage stability and good compatibility with base resins for paint.

  一种含封端异氰酸酯基团的树脂组合物和一种使用该树脂组合物的热固性树脂组合物，其中包含一种树脂（C），该树脂（C）可通过用特定的一元醇（B）对在一个分子中具有两个或多个特定分子结构的封端异氰酸酯基团的树脂（A）进行改性，并用具有更多碳原子数的基团取代封端异氰酸酯基团的取代基，从而降低溶解度参数值。这种组合物具有良好的储存稳定性和与涂料用基础树脂的良好兼容性。
• AQUEOUS PAINT COMPOSITION AND METHOD FOR FORMING COATING
  申请人：KANSAI PAINT CO., LTD.

  公开号：EP2835404A1

  公开（公告）日：2015-02-11

  An object of the present invention is to provide an aqueous coating composition that can form a coating with excellent smoothness, distinctness of image, water resistance, and chipping resistance, and that has excellent wash-off properties, and a method for forming the coating film. As means for achieving this object, the present invention provides an aqueous coating composition for use as an aqueous first colored coating composition in a multilayer coating-forming method, the coating composition containing an aqueous film-forming resin (A), a crosslinking agent (B), and acrylic urethane resin composite particles (C). The acrylic resin of the acrylic urethane resin composite particles (C) is obtained by using, as constituent monomers, 30 to 80 mass% of a polymerizable unsaturated monomer (c-1-1) having one polymerizable unsaturated group per molecule and having a C4-22 alkyl group, 1 to 20 mass% of a polymerizable unsaturated monomer (c-2) having two or more polymerizable unsaturated groups per molecule, and 0 to 69 mass% of a polymerizable unsaturated monomer (c-1-2) having one polymerizable unsaturated group per molecule and being other than the polymerizable unsaturated monomer (c-1-1).

  本发明的目的是提供一种水性涂料组合物，该组合物可以形成具有优异平滑度、图像清晰度、耐水性和抗崩角性的涂层，并且具有优异的冲洗性能，以及一种形成涂膜的方法。作为实现这一目标的方法，本发明提供了一种水性涂料组合物，可用作多层涂料形成方法中的水性第一有色涂料组合物，该涂料组合物含有水性成膜树脂（A）、交联剂（B）和丙烯酸聚氨酯树脂复合颗粒（C）。丙烯酸聚氨酯树脂复合颗粒（C）中的丙烯酸树脂是通过使用 30% 至 80% 的可聚合不饱和单体（c-1-1）作为组成单体获得的，该单体每个分子具有一个可聚合不饱和基团，并具有一个 C4-22 烷基、1 至 20 质量百分比的可聚合不饱和单体 (c-2)，其每个分子具有两个或两个以上的可聚合不饱和基团；以及 0 至 69 质量百分比的可聚合不饱和单体 (c-1-2)，其每个分子具有一个可聚合不饱和基团，且与可聚合不饱和单体 (c-1-1) 不同。
• METHOD FOR FORMING MULTILAYER COATING FILM
  申请人：KANSAI PAINT CO., LTD.

  公开号：EP2898960A1

  公开（公告）日：2015-07-29

  An object of the present invention is to provide a method for forming a multilayer coating film, capable of achieving excellent curability under low-temperature, short-time conditions, and forming a multilayer coating film having excellent chipping resistance and an excellent finished appearance. This method comprises sequentially applying an aqueous first colored coating composition (X), an aqueous second colored coating composition (Y), and a clear coating composition (Z) to a substrate, and simultaneously bake-curing the resulting multilayer coating film. In this method, the aqueous first colored coating composition (X) comprises an aqueous film-forming resin (A) and a specific blocked polyisocyanate compound (B), and the clear coating composition (Z) comprises a hydroxy-containing acrylic resin (K) having a hydroxy value in a specific range, a polyisocyanate compound (L), and an organometallic catalyst (M) containing a metal compound (M1) selected from a specific range and an amidine compound (M2).

  本发明的目的是提供一种形成多层涂膜的方法，该方法能够在低温、短时间条件下实现优异的固化性，并形成具有优异抗崩角性和出色成品外观的多层涂膜。该方法包括依次将水性第一有色涂层组合物（X）、水性第二有色涂层组合物（Y）和透明涂层组合物（Z）涂覆到基底上，并同时对所得到的多层涂膜进行烘烤固化。在该方法中，水性第一有色涂层组合物（X）包括水性成膜树脂（A）和特定封端的多异氰酸酯化合物（B），透明涂层组合物（Z）包括羟值在特定范围内的含羟基丙烯酸树脂（K）、多异氰酸酯化合物（L）和有机金属催化剂（M），其中有机金属催化剂（M）包含选自特定范围的金属化合物（M1）和脒化合物（M2）。
• AQUEOUS COATING COMPOSITION
  申请人：Kansai Paint Co., Ltd

  公开号：EP4052806A1

  公开（公告）日：2022-09-07

  Provided is an aqueous coating composition that can exhibit high coating film performance even when cured at a relatively low temperature. The present invention pertains to an aqueous coating composition comprising (A) a hydroxyl group-containing resin and (B) a blocked polyisocyanate compound. The weight average molecular weight of the blocked polyisocyanate compound (B) is in a range of 20,000-200,000.

  本发明提供了一种水性涂料组合物，即使在相对较低的温度下固化，也能表现出较高的涂膜性能。本发明涉及一种水性涂料组合物，包括 (A) 含羟基树脂和 (B) 封端多异氰酸酯化合物。封端多异氰酸酯化合物 (B) 的重量平均分子量在 20,000-200,000 之间。
• Method for forming multilayer coated film
  申请人：KANSAI PAINT CO., LTD.

  公开号：US10717895B2

  公开（公告）日：2020-07-21

  A method for forming a multilayer coated film on an electrodeposition-coated alloyed hot-dip galvanized steel plate include step (1) of applying an aqueous intermediate coating composition (X), step (2) of applying an aqueous base coating composition (Y), step (3) of applying a clear coating composition (Z) containing an epoxide, and step (4) of heat-curing each coated film. The coating composition (X) contains a hydroxyl group-containing acrylic resin (A), a polyurethane resin (B), a hydroxyl group-containing polyester resin (C), a melamine resin (D), and an active methylene-blocked polyisocyanate compound (E). The ratio of (A) to (B) is controlled to a specific range, and an elongation at break, Young's modulus and Tukon hardness of the coated film of the coating composition (X) are controlled to specific ranges.

  一种在电沉积涂层合金热镀锌钢板上形成多层涂膜的方法，包括步骤(1)涂敷水性中间涂层组合物(X)，步骤(2)涂敷水性基底涂层组合物(Y)，步骤(3)涂敷含有环氧化物的透明涂层组合物(Z)，以及步骤(4)热固化各涂膜。涂层组合物 (X) 包含含羟基的丙烯酸树脂 (A)、聚氨酯树脂 (B)、含羟基的聚酯树脂 (C)、三聚氰胺树脂 (D) 和活性亚甲基封端多异氰酸酯化合物 (E)。(A)与(B)的比例控制在特定范围内，涂层组合物(X)涂膜的断裂伸长率、杨氏模量和图孔硬度控制在特定范围内。