N-amyl-3,6-bis(thiophen-2-yl)carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: N-amyl-3,6-bis(thiophen-2-yl)carbazole
• 英文别名: 9-Pentyl-3,6-dithiophen-2-ylcarbazole；9-pentyl-3,6-dithiophen-2-ylcarbazole
• 化学式: C₂₅H₂₃NS₂
• 分子量: 401.596
• InChiKey: CDRGOXDQKBFLOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-pentyl-9H-carbazole 在 四(三苯基膦)钯 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 生成 N-amyl-3,6-bis(thiophen-2-yl)carbazole
  参考文献：
  名称：

  Development in synthesis and electrochemical properties of thienyl derivatives of carbazole

  摘要：

  A convenient and higher yielding synthetic route to N-alkyl-bis(thiophene)- and N-alkyl-bis(ethylenedioxythiophene) carbazole derivatives is reported and their aggregation, and electrochemical properties are characterized. The key step in the synthesis of this group of compounds has been the Stille-type coupling reaction between the N-alkyldibromocarbazole and tin derivatives of thiophene or ethylenedioxythiophene, as the best way for preparation of conjugated N-alkylcarbazole derivatives. For this group of compounds we also present an electrochemical polymerization effect. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.09.142

文献信息

• Development in synthesis and electrochemical properties of thienyl derivatives of carbazole
  作者：Joanna Cabaj、Krzysztof Idzik、Jadwiga Sołoducho、Antoni Chyla

  DOI：10.1016/j.tet.2005.09.142

  日期：2006.1

  A convenient and higher yielding synthetic route to N-alkyl-bis(thiophene)- and N-alkyl-bis(ethylenedioxythiophene) carbazole derivatives is reported and their aggregation, and electrochemical properties are characterized. The key step in the synthesis of this group of compounds has been the Stille-type coupling reaction between the N-alkyldibromocarbazole and tin derivatives of thiophene or ethylenedioxythiophene, as the best way for preparation of conjugated N-alkylcarbazole derivatives. For this group of compounds we also present an electrochemical polymerization effect. (c) 2005 Elsevier Ltd. All rights reserved.