3,4-di(decyloxy)phenylamine | 96070-02-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4-di(decyloxy)phenylamine
• 英文别名: 3,4-di(decyloxy)aniline；3,4-didecyloxyaniline；3,4-Didecyloxy-anilin；3,4-Bis(decyloxy)aniline；3,4-didecoxyaniline
• CAS: 96070-02-9
• 化学式: C₂₆H₄₇NO₂
• 分子量: 405.665
• InChiKey: XTZKXTFRTYIPJK-UHFFFAOYSA-N

物化性质

• 熔点：
  44-45 °C
• 沸点：
  515.4±30.0 °C(Predicted)
• 密度：
  0.928±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  29
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  44.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,4-di(decyloxy)phenylamine 在 盐酸 、 溶剂黄146 、 sodium nitrite 、 sodium azide 作用下， 以 水 为溶剂， 生成 4-azido-1,2-didecoxybenzene
  参考文献：
  名称：

  Bent-core luminescent and electroactive bis(triazolyl)triazines with compact columnar mesomorphism

  摘要：

  报告了基于新型结构 2-甲氧基-4,6-双(1′,2′,3′-三唑-4′-基)-1,3,5-三嗪的弯曲核分子的批量自组装及其发光和电化学特性。研究了两个具有不同长度侧枝的化合物家族。发现了具有短堆积距离和周期性扭曲结构的柱状介形。一种化合物呈现出两种六角柱状介相，显示出不同的发射光谱，并从双分子组装过渡到单分子组装。

  DOI：

  10.1039/c4ra02926g
• 作为产物：
  描述：

  4-硝基儿茶酚 在 tin(ll) chloride 作用下， 生成 3,4-di(decyloxy)phenylamine
  参考文献：
  名称：

  Mesomorphic Dithiooxamide Complexes of Platinum(II)

  摘要：

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.

  DOI：

  10.1080/10587250008024795

文献信息

• Liquid crystalline properties of bis(salicylaldiminato)copper(II) complexes: the first columnar discotics derived from salicylaldimine Schiff bases
  作者：Chung K. Lai、Chung-hsiung Chang、Chun-hsien Tsai

  DOI：10.1039/a707091h

  日期：——

  The synthesis and mesomorphic properties of a homologous series ofN-(2-hydroxy-4-n-alkoxybenzylidene)-3′,4′-di-n-alkoxylanilines and their copper(ii) complexes bis[(N-3′,4′-dialkoxyphenyl)-4-n-alkoxylsalicylaldiminato]copper(ii) are reported. The disc-like copper complexes exhibited columnar hexagonal disordered mesophases, which were characterized by DSC analysis and optical polarized microscopy. The structure of the mesophases was confirmed by X-ray powder diffraction (XRD). The mesomorphic properties for these copper complexes were compared with other similar metallomesogenic bis(salicylaldiminato)copper(ii) complexes in terms of molecular structural differences.

  报道了一组N-(2-羟基-4-正烷氧基苯亚甲基)-3′,4′-二-正烷氧基苯胺及其铜(II)配合物双[(N-3′,4′-二烷氧基苯基)-4-正烷氧基水杨醛亚胺]铜(II)的合成与液晶性质。盘状铜配合物表现出无序的柱状六方相，通过差示扫描量热分析和偏光显微镜进行了表征。通过X射线粉末衍射(XRD)确定了其相结构。与其他类似的金属配位液晶双(水杨醛亚胺)铜(II)配合物相比，这些铜配合物的液晶性质与其分子结构差异有关。
• Supramolecular Helical Fluid Columns from Self-Assembly of Homomeric Dipeptides
  作者：Channabasaveshwar V. Yelamaggad、Govindaswamy Shanker、R. V. Ramana Rao、Doddamane S. Shankar Rao、Subbarao Krishna Prasad、Vommina V. Suresh Babu

  DOI：10.1002/chem.200801607

  日期：2008.11.17

  regarded as intermediates between polycatenars and taper-shaped amphiphiles because they possess two lipophilic segments interlinked by a peptide unit (spacer). Two pairs of enantiomers and their respective diastereomers derived from these amino acids are evidenced to self-organize into a helical columnar phase through hydrogen bonding by means of FTIR, UV/Vis, and chiroptical circular dichroism (CD) spectral

  在本文中，我们证明，随着残基构图和自相适应的蛋白原氨基酸的立体化学限制的广泛主题，可以得到新的和丰富的一类同质二肽，其表现出具有二维排序的二维流体聚集体。特别地，已经实现了获得一类功能性二肽的简单方法，其中选择的第一和第二残基是L- / D-丙氨酸和L- / D-亮氨酸。合成的超分子可被视为多类和锥形两亲物之间的中间体，因为它们具有两个通过肽单元（间隔子）相互连接的亲脂性链段。通过FTIR，UV / Vis和手性圆二色性（CD）光谱分析以及光学分析，证明了两对对映异构体及其衍生自这些氨基酸的非对映异构体通过氢键自组织成螺旋柱状相，量热，电开关和X射线研究。CD和X射线研究表明，流体超分子柱状结构的晶格手性（手性）和晶面平面外波动幅度仅由间隔物中编码的立体化学指示。具有特殊意义的是，由L- / D-丙氨酸衍生的一对对映异构体形成的，不太常见的斜螺旋柱状相表现出铁电行为，这与衍生自其他氨基酸的
• Liquid crystals based on semiperfluorinated imines and salicylaldimato metal complexes. A comparative study of alkyl, alkoxy and polyether substituents
  作者：Belkız Bilgin-Eran、Çiğdem Yörür、Carsten Tschierske、Marko Prehm、Ute Baumeister

  DOI：10.1039/b618403k

  日期：——

  Three series of imines containing fluoroalkyl, polyether, alkyl and alkoxy peripheral chains have been prepared. The phase behaviour of the semiperfluorinated compounds has been investigated by optical polarizing microscopy, differential scanning calorimetry and X-ray scattering. The thermal behaviour of the semiperfluorinated imines1–10 depends on the number of chains, the substitution pattern and the number of fluorine atoms in the fluoroalkyl chains. Increasing the number of fluorine atoms in the fluoroalkyl chains leads to a stabilization of smectic and columnar mesophases. The effect of polyether side chains on the mesomorphic behaviour of imine compounds has also been investigated. In addition, first examples of mesogenic copper(II) complexes carrying semiperfluorinated alkyl chains at their peripheries and a palladium complex have been synthesized and their liquid crystalline properties have been investigated.

  已制备三系列含氟烷基、聚醚、烷基和烷氧基外围链的亚氟化亚胺。通过光偏振显微镜、差示扫描量热法和X射线散射研究了亚氟化化合物的相行为。亚氟化亚胺1-10的热行为依赖于链的数量、取代模式和氟烷基链中氟原子的数量。增加氟烷基链中氟原子的数量可使层相和柱状中相得到稳定。此外，还研究了聚醚侧链对亚胺化合物中相行为的影响。此外，合成了首例在边缘具有亚氟化烷基链的中间相铜(II)配合物及一个钯配合物，并研究了它们的液晶性质。
• New star-shaped triarylamines: synthesis, mesomorphic behavior, and photophysical properties
  作者：Yueh-Ju Wang、Hwo-Shuenn Sheu、Chung K. Lai

  DOI：10.1016/j.tet.2006.11.058

  日期：2007.2

  mesomorphic properties were also investigated. Compounds 1–4 and 5,6 were prepared from p,p′,p″-triformyltriphenylamine and p,p′-diformyltriphenylamine with appropriate alkoxyphenylamines. The phase behavior of these mesogenic compounds was characterized and studied by differential scanning calorimetry, polarized optical microscopy, and powder XRD diffraction. Compounds 1–3 exhibited columnar mesophase

  共有18个化合物1 - 6从三苯胺作为核心组衍生的制备和表征，以及它们的介晶性能进行了研究。化合物1 - 4和5，6是从制备p，p '，p “和-triformyltriphenylamine p，p具有适当alkoxyphenylamines'-diformyltriphenylamine。这些介晶化合物的相行为已通过差示扫描量热法，偏振光学显微镜和粉末XRD衍射进行了表征和研究。化合物1 - 3展出柱状相，然而，化合物4 - 6是nonmesogenic。化合物中观察到的中间相1 - 3被认为是侧依赖性的。附有一个，两个或三个侧链的化合物1a，2a和3a表现为层状柱状（Col L）相，具有四个或六个侧链的化合物2b和3b形成六方柱状（Col h）相。中间相（层状或柱状中间相）的形成可能是由–CH 2之间形成的氢键引起的。NH组。循环伏安法测定的氧化过程显示出两个氧化还原波，一个在220-255
• Optical compensators
  申请人：CHISSO CORPORATION

  公开号：EP1054049A1

  公开（公告）日：2000-11-22

  There are provided optical compensators for liquid crystal displays containing columnar complexes consisting of substituted melamines (compound 1) and disubstituted benzoic acids (compound 2 or 3), or mixtures made thereof, having negative optical birefringence, and liquid crystal displays held between crossed polarizers and the optical compensator, wherein n is 6 to 20 respectively in the above-described R's.

  本发明提供了用于液晶显示器的光学补偿器，该补偿器含有由具有负光学双折射的取代三聚氰胺（化合物 1）和二取代苯甲酸（化合物 2 或 3）或其混合物组成的柱状复合物，以及在交叉偏振器和光学补偿器之间固定的液晶显示器、 其中上述 R 的 n 分别为 6 至 20。