1,3-bis(4-glycidyloxyphenyl)adamantane

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,3-bis(4-glycidyloxyphenyl)adamantane
• 英文别名: 2-[[4-[3-[4-(oxiran-2-ylmethoxy)phenyl]-1-adamantyl]phenoxy]methyl]oxirane
• 化学式: C₂₈H₃₂O₄
• 分子量: 432.56
• InChiKey: KYVHCBBLPLWQTB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-bis(4-glycidyloxyphenyl)adamantane 、 甲基丙烯酸 在 三乙胺 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 5.0h， 以88%的产率得到1,3-bis[4-(3-methacryloyloxy-2-hydroxypropoxy)phenyl]adamantane
  参考文献：
  名称：

  脂環式（メタ）アクリル化合物を含む硬化性組成物

  摘要：

  【问题】提供一种具有优异的力学物性和审美性，同时具有优异的操作性的硬化性组成物，可提供硬化物。 【解决方案】含有脂环式（甲基）丙烯酸化合物（A），聚合起始剂（B）和无机颗粒（C），其中脂环式（甲基）丙烯酸化合物（A）是由式（I）表示的脂环式（甲基）丙烯酸化合物（A）-I以及选择自羧酰胺基连接的脂环式（甲基）丙烯酸化合物的群中至少一种，无机颗粒（C）的平均粒径为0.001〜10μm的硬化性组成物。（其中R1和R2分别是独立的（甲基）丙烯酰基；X是二价非取代/取代的碳氢基；m和n是独立的0〜30的整数）【选择图】无

  公开号：

  JP2018193342A
• 作为产物：
  描述：

  4,4’-(1,3-金刚烷二基）二苯酚 、 环氧氯丙烷 在 sodium hydroxide 作用下， 以 二甲基亚砜 、 丁酮 为溶剂， 生成 1,3-bis(4-glycidyloxyphenyl)adamantane
  参考文献：
  名称：

  ADAMANTYL GROUP-CONTAINING EPOXY-MODIFIED (METH)ACRYLATE AND RESIN COMPOSITION CONTAINING THE SAME

  摘要：

  本发明提供了一种含有金刚烷基的环氧改性（甲基）丙烯酸酯及其树脂组合物，具有透明度、光学特性（耐久性）和热稳定性等优良机械性能。例如，它们是具有以下一般式（I）的含有金刚烷基的环氧改性（甲基）丙烯酸酯及其组合物。在该式中，R1代表氢原子或甲基基团，R2代表卤素原子或可能包含杂原子的脂肪烃基团。复数的R2可能相同或不同，m表示0到4的整数，n表示0或更多的整数。

  公开号：

  US20090099330A1

文献信息

• ADAMANTANE DERIVATIVE, RESIN COMPOSITION CONTAINING SAME, AND OPTOELECTRONIC MEMBER AND SEALING AGENT FOR ELECTRONIC CIRCUIT USING THOSE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1985616A1

  公开（公告）日：2008-10-29

  Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.

  本发明涉及一种金刚烷衍生物，其提供了在光学特性（如透明度和耐光性）、长期耐热性、电学特性（如介电常数）和低吸水性等方面表现出色的固化产物。本发明还涉及一种含有金刚烷衍生物的树脂组合物，以及使用该树脂组合物的电子电路密封剂、光电子元件、半导体器件和铜覆盖层层压板，以及一种辐射敏感的树脂组合物，其中包含上述金刚烷衍生物作为交联剂。具体公开了以下公式（I-1）所表示的金刚烷衍生物，以及含有该金刚烷衍生物的树脂组合物、电子电路密封剂、光电子元件、半导体器件和铜覆盖层层压板，以及含有上述金刚烷衍生物作为交联剂的辐射敏感的树脂组合物。
• ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1985617A1

  公开（公告）日：2008-10-29

  To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions. An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Yrepresentsagrouprepresented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16-m) and p and q are each an integer of 1 to 5.

  为提供一种金刚烷衍生物、一种具有金刚烷骨架的化合物、含有它们的组合物，可提供具有优异光学性能（如透明度和耐光性）、长期耐热性和电特性（如介电常数）的固化产品以及使用这些组合物的光电子元件。该金刚烷衍生物由通式（I）表示，具有金刚烷骨架的化合物由通式（VII）或（VIII）表示，含有它们的组合物以及使用树脂组合物的光电子元件。在公式中，W代表氢原子，X代表由通式（II）表示的基团，Y代表由公式（V）或（VI）表示的基团，R1代表甲基基团或乙基基团，R2代表含有O或S的C1至C10烃基团，m为2至4的整数，k为0至（16-m）的整数，p和q均为1至5的整数。
• Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
  申请人：——

  公开号：US20030105268A1

  公开（公告）日：2003-06-05

  A process for manufacturing an &agr;-dihydroxy derivative from an aryl allyl ether wherein such &agr;-dihydroxy derivative can be used to prepare an &agr;-halohydrin intermediate and an epoxy resin prepared therefrom including epoxidizing an &agr;-halohydrin intermediate produced from a halide substitution of an &agr;-dihydroxy derivative which has been obtained by a dihydroxylation reaction of an aryl allyl ether in the presence of an oxidant or in the presence of an oxidant and a catalyst.

  从芳基丙烯醚中制备α-二羟基衍生物的工艺，其中这种α-二羟基衍生物可用于制备α-卤代醇中间体和由此制备的环氧树脂，包括将从α-二羟基衍生物的卤化物取代反应中产生的α-卤代醇中间体环氧化，该α-二羟基衍生物是在氧化剂或氧化剂和催化剂存在下从芳基丙烯醚的双羟基化反应中获得的。
• Adamantyl group-containing epoxy-modified (meth)acrylate and resin composition containing the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US07790917B2

  公开（公告）日：2010-09-07

  The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties. For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.

  本发明提供了一种含有金刚烷基的环氧改性（甲基）丙烯酸酯以及含有该酯的树脂组合物，这些组合物具有透明度、耐光性等光学特性、耐热性和良好的机械性能。例如，它们是具有以下通式（I）的含有金刚烷基的环氧改性（甲基）丙烯酸酯和含有它的组合物。在该式中，R1代表氢原子或甲基基团，R2代表卤素原子或可能含有杂原子的脂肪烃基团。多个R2可能相同或不同，m表示0到4的整数，n表示0或更多的整数。
• ADAMANTANE DERIVATIVE, EPOXY RESIN, AND OPTICAL ELECTRONIC MEMBER USING RESIN COMPOSITION COMPRISING THEM
  申请人：Ito Hajime

  公开号：US20090137775A1

  公开（公告）日：2009-05-28

  This invention provides an adamantane derivative that can provide a cured product having excellent optical properties such as transparency and lightfastness, long-term heat resistance, and electric characteristics such as permittivity, and an epoxy resin having an adamantane skeleton, a resin composition comprising them, and an optical electronic member using the resin composition. The adamantane derivative is represented by general formula (I). The epoxy resin having an adamantane skeleton is represented by general formula (V) or (VI). The resin composition comprises them. The optical electronic member uses the resin composition. In the formula, W represents, for example, a hydrogen atom, X represents a group represented by general formula (II), Y represents, for example, —O—, Z represents a group represented by formula (III) or (IV), R 1 represents a methyl or ethyl group, R 2 represents an alkyl group having 1 to 4 carbon atoms, k is an integer of 0 to 10, m is an integer of 0 to 14, n is an integer of 2 to 16, m+n=16, and p and q are an integer of 0 to 5.

  本发明提供了一种可以提供具有优异光学性能（如透明度和耐光性）、长期耐热性和电特性（如介电常数）的固化产品的金刚烷衍生物，以及具有金刚烷骨架的环氧树脂、包含它们的树脂组合物和使用该树脂组合物的光电元件。金刚烷衍生物由通式（I）表示。具有金刚烷骨架的环氧树脂由通式（V）或（VI）表示。树脂组合物包括它们。光电元件使用该树脂组合物。在式中，W代表例如氢原子，X代表由通式（II）表示的基团，Y代表例如-O-，Z代表由式（III）或（IV）表示的基团，R1代表甲基或乙基基团，R2代表具有1到4个碳原子的烷基，k是0到10的整数，m是0到14的整数，n是2到16的整数，m+n=16，p和q是0到5的整数。