甲基(13E)-13-二十二碳烯酸酯 | 56630-69-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 甲基(13E)-13-二十二碳烯酸酯
• 英文名称: 13-docosenoic acid methyl ester
• 英文别名: methyl erucate；docos-13-enoic acid methyl ester；Docos-13-ensaeure-methylester；Erukasaeuremethylester；Methyl docos-13-enoate
• CAS: 56630-69-4
• 化学式: C₂₃H₄₄O₂
• 分子量: 352.601
• InChiKey: ZYNDJIBBPLNPOW-UHFFFAOYSA-N

物化性质

• 沸点：
  422.9±14.0 °C(Predicted)
• 密度：
  0.869±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  25
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲基(13E)-13-二十二碳烯酸酯 在 溶剂黄146 作用下， 生成 壬醛
  参考文献：
  名称：

  Noller; Adams, Journal of the American Chemical Society, 1926, vol. 48, p. 1087

  摘要：

  DOI：
• 作为产物：
  描述：

  甲醇 、 alkaline earth salt of/the/ methylsulfuric acid 生成 甲基(13E)-13-二十二碳烯酸酯
  参考文献：
  名称：

  Meyer,H., Monatshefte fur Chemie, 1901, vol. 22, p. 418

  摘要：

  DOI：

文献信息

• Safe Use of a Toxic Compound: Heterogeneous OsO₄Catalysis in a Nanobrush Polymer Microreactor
  作者：K. C. Basavaraju、Siddharth Sharma、Ram Awatar Maurya、Dong-Pyo Kim

  DOI：10.1002/anie.201301124

  日期：2013.6.24

  Putting osmium in its place: The immobilization of hazardous OsO4 on polymer nanobrushes in a microreactor is a safe, effective, and green concept. The method allows reactions to be performed in a time‐ and chemical‐saving manner, with little environmental impact, as compared to spill‐over bulk processes.

  放置in：在微型反应器中将危险的OsO 4固定在聚合物纳米刷上是一种安全，有效和绿色的概念。与溢出的散装工艺相比，该方法允许以节省时间和化学药品的方式进行反应，而对环境的影响很小。
• Novel liquid fatty acid derivatives
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0713855A1

  公开（公告）日：1996-05-29

  A fatty acid derivative of formula (1) wherein each of X, Y and Z, which are the same or different, is a C₁-C₁₀ alkyloxy group or a C₃-C₁₀ cycloalkyloxy group, at least one of X, Y and Z being a C₁-C₁₀ alkyloxy group or a C₃-C₁₀ cycloalkyloxy group, each of a, b, c and d, which are the same or different, is an integer of 0 to 17 and the value of a + b + c + d is from 13 to 17; and salts thereof.

  式（1）的脂肪酸衍生物，其中X、Y和Z分别为C₁-C₁₀烷氧基或C₃-C₁₀环烷氧基，可以相同也可以不同，X、Y和Z中至少有一个为C₁-C₁₀烷氧基或C₃-C₁₀环烷氧基，a、b、c和d分别为0到17的整数，且a + b + c + d的值为13到17；以及其盐。
• FATTY ACID BLENDS AND USES THEREFOR
  申请人：Knuth Mark E.

  公开号：US20100058651A1

  公开（公告）日：2010-03-11

  Provided herein are blends oils or fatty acids comprising more than 50% medium chain fatty acids, or the fatty acid alkyl esters thereof, and having low melting points. Such blends are useful as a fuel or as a starting material for the production of, for example, a biodiesel. Also provided genetically altered or modified plants, modified such that the amount of medium chain fatty acids generated by the plant are increased. Further provided is a method of predicting the melting point of a blend of fatty acid methyl esters and the use of such a method for identifying blends suitable for use as, for example, a biodiesel.

  本文提供了混合油或脂肪酸，其中含有超过50％的中链脂肪酸或其脂肪酸烷基酯，并具有低熔点。这种混合物可用作燃料或用作生产生物柴油的起始材料。此外，还提供了经过基因改造或修改的植物，使其生成的中链脂肪酸的数量增加。还提供了一种预测脂肪酸甲酯混合物熔点的方法，并利用这种方法来确定适用于生物柴油等用途的混合物。
• ALKYLESTER FATTY ACID BLENDS AND USES THEREFOR
  申请人：Knuth Mark E.

  公开号：US20110023352A1

  公开（公告）日：2011-02-03

  Provided herein are blends oils or fatty acids comprising more than 50% medium chain fatty acids, or the fatty acid alkyl esters thereof, and having low melting points. Such blends are useful as a fuel or as a starting material for the production of, for example, a biodiesel. Also provided genetically altered or modified plants, modified such that the amount of medium chain fatty acids generated by the plant are increased. Further provided is a method of predicting the melting point of a blend of fatty acid methyl esters and the use of such a method for identifying blends suitable for use as, for example, a biodiesel.

  本文提供的是混合油或脂肪酸，其中含有超过50％的中链脂肪酸或其脂肪酸烷基酯，并具有低熔点。这样的混合物可用作燃料或用作生产生物柴油等起始材料。此外，还提供了经遗传改造或改良的植物，这些植物被改造以增加植物产生的中链脂肪酸的数量。进一步提供了一种预测脂肪酸甲酯混合物熔点的方法，并利用这种方法识别适用于用作生物柴油等的混合物。
• Furyl compounds, their use as fungicides and their preparation
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0219154A2

  公开（公告）日：1987-04-22

  The present invention provides in one aspect a method of combating a fungus at a locus, characterised by treating the locus with a fungicidally effective amount of a compound of general formula I wherein each of R' and R2 independently represents a hydrogen atom or an optionally substituted alkyl, alkenyl, alkynyl, aryl or aralkyl group; or an optionally substituted cycloalkyl, bicycloalkyl, cycloalkenyl or bicycloalkenyl group containing up to 12 ring atoms, in which at least one methylene group is optionally replaced by an oxygen atom or by a sulphone or sulphoxide group; or a group of general formula in which m is 0 and p is 0 or 1, or m is 1 and p is 0, and RS is an optionally substituted alkyl, alkenyl, aryl or aralkyl group; or R' and R2 together with the interjacent carbon atoms form an optionally substituted cycloalkylene, bicycloalkylene, tricycloalkylene, cycloalkenylene, bicycloalkenylene or tricycloalkenylene group containing up to 18 ring atoms, in which at least one methylene group is optionally replaced by an oxygen or sulphur atom or by a sulphone or sulphoxide group; or an optionally substituted dihydronaphthylene, tetrahydronaphthylene, dihydrophenanthrylene or dihydroacenaphthylene group; each of R3 and R4 independently represents a hydrogen atom or an alkyl group or together represent a single chemical bond; or R' and R3 together with the interadjacent carbon atom form an optionally substituted cycloalkyl, bicycloalkyl, cycloalkenyl or bicycloalkenyl group containing up to 12 ring atoms, in which at least one methylene group is optionally replaced by an oxygen atom or a sulphone or sulphoxide group; provided that when R3 and R4 do not together represent a single chemical bond, at least one of R', R2, R3 and R4 is a hydrogen atom. Also certain of such compounds per se, and their preparation.

  本发明的一个方面是提供了一种在基因座上防治真菌的方法，其特征在于用杀真菌有效量的通式 I 化合物处理基因座 其中，R'和 R2 各自独立地代表氢原子或任选取代的烷基、烯基、炔基、芳基或芳烷基；或任选取代的环烷基、双环烷基、环烯基或双环烯基，这些基团含有多达 12 个环原子，其中至少一个亚甲基任选被氧原子或砜基或亚砜基取代；或通式基团 其中 m 为 0，p 为 0 或 1，或 m 为 1，p 为 0，RS 为任选取代的烷基、烯基、芳基或芳烷基；或 R' 和 R2 与相邻碳原子一起形成任选取代的环亚烷基、双环亚烷基、三环亚烷基、环亚烯基、双环亚烯基或三环亚烯基，最多包含 18 个环原子，其中至少一个亚甲基任选被氧原子或硫原子或砜基或亚砜基取代；或任选取代的二氢萘基、四氢萘基、二氢菲基或二氢苊基；R3 和 R4 各自独立地代表一个氢原子或一个烷基，或共同代表一个单化学键；或 R' 和 R3 与相邻碳原子一起形成一个任选取代的环烷基、双环烷基、环烯基或双环烯基，其中最多包含 12 个环原子，其中至少一个亚甲基任选被一个氧原子或一个砜基或亚砜基取代；但当 R3 和 R4 不共同代表一个单化学键时，R'、R2、R3 和 R4 中至少有一个是氢原子。还包括某些此类化合物本身及其制备方法。