pentadecafluoroheptylbenzene | 1548-88-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentadecafluoroheptylbenzene
• 英文别名: perfluoro-n-heptylbenzene；Perfluoroheptylbenzene；(Perfluorheptyl)-benzol；Perfluorheptyl-benzol；Perfluorpentyl-benzol；Perfluorheptylbenzol；(Pentadecafluoroheptyl)benzene；1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-pentadecafluoroheptylbenzene
• CAS: 1548-88-5
• 化学式: C₁₃H₅F₁₅
• 分子量: 446.159
• InChiKey: BZWJFGUKLIXANG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  pentadecafluoroheptylbenzene 在 氯磺酸 作用下， 以55%的产率得到m-perfluoro-n-heptylbenzenesulfonyl chloride
  参考文献：
  名称：

  Perfluoroalkylbenzenesulfonyl chlorides, perfluoroalkylnaphthalenesulfonyl chlorides, and their metal salts

  摘要：

  Meta-perfluoro-n-alkylbenzenesulfonyl chlorides and 1-perfluoro-n-alkylnaphthalene-5-sulfonyl chlorides were synthesized from the corresponding perfluoroalkylaromatics in good yield by the action of chlorosulfonic acid. From the acid chlorides, salts (RSO3M, where M = Li, K, Ba, Zn and Al) were prepared and their TGA curves obtained. With the exception of the aluminum salts, the materials were stable to at least 350-degrees-C. All the salts were essentially insoluble in Cl(CFClCF2)3-4Cl.

  DOI：

  10.1016/s0022-1139(00)80959-8
• 作为产物：
  描述：

  十三氟庚酰氯 在 三氯化铝 、 sulfur tetrafluoride 作用下， 生成 pentadecafluoroheptylbenzene
  参考文献：
  名称：

  Preparation and properties of perflouroalkylated benzene sulfonates

  摘要：

  DOI：

  10.1016/s0022-1139(00)83354-0

文献信息

• Trifluoromethylation of aromatic compounds with bis(trifluoroacetyl) peroxide
  作者：Hideo Sawada、Masaharu Nakayama、Masato Yoshida、Tatsuro Yoshida、Nobumasa Kamigata

  DOI：10.1016/s0022-1139(00)82927-9

  日期：1990.3

  Bis(trifluoroacety) peroxide was found to be thermally stable, and trifluoromenthylation of aromatic compounds was studied using this peroxide. Thrifluoromethylation of electron-rich benzenes, furan, thiophene, or their benzo derivatives proceeded with the peroxide in moderate to high yields.

  发现双（三氟乙氧基）过氧化物是热稳定的，并且使用该过氧化物研究了芳族化合物的三氟乙酰化。富电子的苯，呋喃，噻吩或其苯并衍生物的三氟甲基化与过氧化物一起以中等至高收率进行。
• Method for production of fluorine-containing aromatic derivative
  申请人：Nippon Oil & Fars Co., Ltd.

  公开号：US04631151A1

  公开（公告）日：1986-12-23

  A fluorine-containing aromatic derivative is produced by causing a di(haloacyl)peroxide to react upon benzene, a mono-substituted benzene, naphthalene, or a mono-substituted naphthalene thereby introducing an X(CF.sub.2).sub.n -group into the benzene ring or the naphthalene ring.

  通过使二(卤代酰基)过氧化物与苯、单取代苯、萘或单取代萘反应，从而将X(CF.sub.2).sub.n-基引入苯环或萘环中，从而产生含氟芳香衍生物。
• A route to fluoroalkyl-substituted aromatic compounds involving fluoroalkylcopper intermediates
  作者：V.C.R. Mcloughlin、J. Thrower

  DOI：10.1016/s0040-4020(01)83100-8

  日期：——
• Fluorinated organometallics: Perfluoroalkyl and functionalized perfluoroalkyl organometallic reagents in organic synthesis
  作者：Donald J. Burton、Zhen-Yu Yang

  DOI：10.1016/s0040-4020(01)88139-4

  日期：——
• Dehalogenation process
  申请人：ETHYL CORPORATION

  公开号：EP0245679B1

  公开（公告）日：1991-03-13