N-chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: N-chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine
• 英文别名: N,2,3,4,4,5,6-heptachlorocyclohexa-2,5-dien-1-imine
• 化学式: C₆Cl₇N
• 分子量: 334.244
• InChiKey: RGHAGLZUNYIUMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine 在 盐酸 作用下， 以 四氯化碳 为溶剂， 反应 10.0h， 以83%的产率得到2,3,4,4,5,6-六氯-2,5-环己二烯-1-酮
  参考文献：
  名称：

  N-CHLORO-2,3,4,4,5,6-HEXACHLOROCYCLOHEXA- 2,5-DIENYLIDENEAMINE AS A MILD AND HIGHLY REGIOSELECTIVE CHLORINATING REAGENT

  摘要：

  N-Chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine was used as a new, mild and highly regioselective chlorinating reagent in the chlorination of phenol and o-cresol in CCl4, DMF and CH3CN. The effects Of C2H5OH, C5H5N, DMF and Et3N on the regioselectivity in CCl4 have also been examined.

  DOI：

  10.1081/scc-120002512
• 作为产物：
  描述：

  N,N,2,3,4,5,6-七氯苯胺 在 碘 作用下， 以 四氯化碳 为溶剂， 反应 20.0h， 以75%的产率得到N-chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine
  参考文献：
  名称：

  N-CHLORO-2,3,4,4,5,6-HEXACHLOROCYCLOHEXA- 2,5-DIENYLIDENEAMINE AS A MILD AND HIGHLY REGIOSELECTIVE CHLORINATING REAGENT

  摘要：

  N-Chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine was used as a new, mild and highly regioselective chlorinating reagent in the chlorination of phenol and o-cresol in CCl4, DMF and CH3CN. The effects Of C2H5OH, C5H5N, DMF and Et3N on the regioselectivity in CCl4 have also been examined.

  DOI：

  10.1081/scc-120002512
• 作为试剂：
  描述：

  邻甲酚 在 N-chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine 作用下， 以 四氯化碳 为溶剂， 反应 30.0h， 生成 4-氯-2-甲基苯酚 、 2-氯-6-甲酚
  参考文献：
  名称：

  N-CHLORO-2,3,4,4,5,6-HEXACHLOROCYCLOHEXA- 2,5-DIENYLIDENEAMINE AS A MILD AND HIGHLY REGIOSELECTIVE CHLORINATING REAGENT

  摘要：

  N-Chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine was used as a new, mild and highly regioselective chlorinating reagent in the chlorination of phenol and o-cresol in CCl4, DMF and CH3CN. The effects Of C2H5OH, C5H5N, DMF and Et3N on the regioselectivity in CCl4 have also been examined.

  DOI：

  10.1081/scc-120002512

文献信息

• <i>N</i>-CHLORO-2,3,4,4,5,6-HEXACHLOROCYCLOHEXA- 2,5-DIENYLIDENEAMINE AS A MILD AND HIGHLY REGIOSELECTIVE CHLORINATING REAGENT
  作者：M. Mamaghani、M. A. Zolfigol、M. Shojaei

  DOI：10.1081/scc-120002512

  日期：2002.1.1

  N-Chloro-2,3,4,4,5,6-hexachlorocyclohexa-2,5-dienylideneamine was used as a new, mild and highly regioselective chlorinating reagent in the chlorination of phenol and o-cresol in CCl4, DMF and CH3CN. The effects Of C2H5OH, C5H5N, DMF and Et3N on the regioselectivity in CCl4 have also been examined.