2-butyl (7E)-tetradecenoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-butyl (7E)-tetradecenoate
• 英文别名: butan-2-yl (E)-tetradec-7-enoate
• 化学式: C₁₈H₃₄O₂
• 分子量: 282.467
• InChiKey: RBSDKFRRNIJFNR-ZHACJKMWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  20
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (R)-(-)-2-丁醇 、 2-butyl (7E)-tetradecenoate 在 吡啶 作用下， 生成
  参考文献：
  名称：

  摘要：

  The sex pheromone of the vine bud moth, Theresimima ampellophaga, released at the 3rd-5th abdominal tergites, was identified by coupled GC-EAG, GC-MS, and synthesis as (2S)-butyl (7Z)-tetradecenoate. For the first time, full stereochemistry is unambiguously defined for the sex pheromone of a member of the Zygaenidae. The synthetic compound caught significant numbers of males in field-trapping experiments.

  DOI：

  10.1023/a:1022438717287
• 作为产物：
  描述：

  (7E)-tetradec-7-enioc acid 在 吡啶 、 草酰氯 、 N,N-二甲基甲酰胺 作用下， 以 二氯甲烷 为溶剂， 生成 2-butyl (7E)-tetradecenoate
  参考文献：
  名称：

  摘要：

  The sex pheromone of the vine bud moth, Theresimima ampellophaga, released at the 3rd-5th abdominal tergites, was identified by coupled GC-EAG, GC-MS, and synthesis as (2S)-butyl (7Z)-tetradecenoate. For the first time, full stereochemistry is unambiguously defined for the sex pheromone of a member of the Zygaenidae. The synthetic compound caught significant numbers of males in field-trapping experiments.

  DOI：

  10.1023/a:1022438717287

文献信息

• ——
  作者：M. Subchev、A. Harizanov、W. Francke、S. Franke、E. Plass、A. Reckziegel、F. Schröder、J. A. Pickett、L. J. Wadhams、C. M. Woodcock

  DOI：10.1023/a:1022438717287

  日期：——

  The sex pheromone of the vine bud moth, Theresimima ampellophaga, released at the 3rd-5th abdominal tergites, was identified by coupled GC-EAG, GC-MS, and synthesis as (2S)-butyl (7Z)-tetradecenoate. For the first time, full stereochemistry is unambiguously defined for the sex pheromone of a member of the Zygaenidae. The synthetic compound caught significant numbers of males in field-trapping experiments.