2,3-dihydroxy-6,7,10,11-tetrakis(pentyloxy)triphenylene | 168847-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3-dihydroxy-6,7,10,11-tetrakis(pentyloxy)triphenylene
• 英文别名: 2,2-dihydroxy-6,7,10,11-tetrapentyloxytriphenylene；2,3-dihydroxy-6,7,10,11-tetrapentyloxytriphenylene；6,7,10,11-Tetrapentoxytriphenylene-2,3-diol
• CAS: 168847-17-4
• 化学式: C₃₈H₅₂O₆
• 分子量: 604.827
• InChiKey: BVGQYMLZMLIPGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  44
• 可旋转键数：
  20
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3-dihydroxy-6,7,10,11-tetrakis(pentyloxy)triphenylene 在 ammonium cerium(IV) nitrate 作用下， 以 乙腈 为溶剂， 反应 0.5h， 以90%的产率得到6,7,10,11-tetrapentyloxytriphenylene-2,3-dione
  参考文献：
  名称：

  Synthesis of phenanthro[b] phenazine, a novel heterocyclic ring structure for discotic liquid crystals

  摘要：

  Phenanthro[b]phenazine. a new heterocyclic ring structure of both biological and physical interests, has been prepared by coupling 1, 2-phenylenediamine with triphenylene-2, 3-quinone derivative. The first derivative of this novel core, 2,3,6,7-tetrapentyloxyphenanthro[b]phenazine shows a monotropic columnar phase.

  DOI：

  10.1080/10587250008024428
• 作为产物：
  描述：

  2-Hydroxy-3-methoxy-6,7,10,11-tetrapentyloxytriphenylene 在 正丁基锂 、 三溴化硼 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 反应 1.5h， 以52%的产率得到2,3-dihydroxy-6,7,10,11-tetrakis(pentyloxy)triphenylene
  参考文献：
  名称：

  Closs, Fritz; Haeubling, Lukas; Henderson, Philippe, Journal of the Chemical Society. Perkin transactions I, 1995, # 7, p. 829 - 838

  摘要：

  DOI：

文献信息

• Highly ordered columnar superlattice nanostructures with improved charge carrier mobility by thermotropic self-assembly of triphenylene-based discotics
  作者：Jingze Bi、Hao Wu、Zhenhu Zhang、Ao Zhang、Huanzhi Yang、Yuwen Feng、Yi Fang、Lina Zhang、Zhengran Wang、Wentao Qu、Feng Liu、Chunxiu Zhang

  DOI：10.1039/c9tc04349g

  日期：——

  A series of triphenylene esters with two ester groups at different substituent positions was synthesized and investigated. 3,6-substituted molecule formed a helical hexagonal columnar superstructure, leading to improved charge carrier mobility.

  一系列在不同取代位置具有两个酯基团的三苯基酯被合成并研究。3,6-取代分子形成了螺旋六角柱状超结构，从而提高了载流子迁移率。
• Synthesis of Crown Ether-Linked Discotic Triphenylenes
  作者：Juanjuan Li、Zhiqun He、Hemant Gopee、Andrew N Cammidge

  DOI：10.1021/ol902637z

  日期：2010.2.5

  triphenylene dimers linked by a central crown ether core have been synthesized and characterized. The crown ether is most conveniently formed as a final step to permit purification and isolation of ion-free material, and extension of the protocol permits synthesis of triad structures linked though a 27-crown-9 macrocycle. The latter compounds present a new discotic motif that supports mesophase formation.

  已经合成并表征了通过中央冠醚核连接的新型三亚苯基二聚体。冠醚最方便地形成为最终步骤，以纯化和分离无离子物质，并且该方案的扩展允许合成通过27冠9大环连接的三单元组结构。后者化合物呈现出支持中间相形成的新盘状基序。
• Bushby; Lu, Synthesis, 2001, # 5, p. 763 - 767
  作者：Bushby、Lu

  DOI：——

  日期：——
• Closs, Fritz; Haeubling, Lukas; Henderson, Philippe, Journal of the Chemical Society. Perkin transactions I, 1995, # 7, p. 829 - 838
  作者：Closs, Fritz、Haeubling, Lukas、Henderson, Philippe、Ringsdorf, Helmut、Schuhmacher, Peter

  DOI：——

  日期：——
• Synthesis of phenanthro[b] phenazine, a novel heterocyclic ring structure for discotic liquid crystals
  作者：Sandeep Kumar、M. Manickam

  DOI：10.1080/10587250008024428

  日期：2000.1.1

  Phenanthro[b]phenazine. a new heterocyclic ring structure of both biological and physical interests, has been prepared by coupling 1, 2-phenylenediamine with triphenylene-2, 3-quinone derivative. The first derivative of this novel core, 2,3,6,7-tetrapentyloxyphenanthro[b]phenazine shows a monotropic columnar phase.