2-cyano-3-difluoromethoxyphenylsulfonyl chloride | 889097-54-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-cyano-3-difluoromethoxyphenylsulfonyl chloride
• 英文别名: 2-cyano-3-difluoromethoxy-benzenesulfonyl chloride；2-cyano-3-(difluoromethoxy)benzenesulfonyl chloride
• CAS: 889097-54-5
• 化学式: C₈H₄ClF₂NO₃S
• 分子量: 267.64
• InChiKey: KSQPBJWALJYBEJ-UHFFFAOYSA-N

物化性质

• 沸点：
  403.6±45.0 °C(Predicted)
• 密度：
  1.62±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  75.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-cyano-3-difluoromethoxyphenylsulfonyl chloride 在 盐酸 、 乙醇 、 水 、 锌 作用下， 反应 2.0h， 生成 2-difluoromethoxy-6-mercapto-benzamide
  参考文献：
  名称：

  WO2008/90048

  摘要：

  公开号：
• 作为产物：
  描述：

  2-氨基-3-硝基苯酚 在 盐酸 、 氢溴酸 、 potassium carbonate 、 tin(ll) chloride 、 lithium bromide 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 水 、 溶剂黄146 、 N,N-二甲基甲酰胺 、 异丙醇 为溶剂， 反应 2.67h， 生成 2-cyano-3-difluoromethoxyphenylsulfonyl chloride
  参考文献：
  名称：

  [EN] 2-CYANOBENZENSULFONAMIDE DERIVATIVES HAVING PESTICIDAL PROPERTIES
  [FR] COMPOSÉS CHIMIQUES

  摘要：

  公开号：

  WO2009109539A3

文献信息

• Novel 2-Cyano-3(Halo)Alkoxy-Benzenesulfonamide Compounds for Combating Animal Pests
  申请人：von Deyn Wolfgang

  公开号：US20080063678A1

  公开（公告）日：2008-03-13

  The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R 1 to R 5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds I and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula I and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula I and/or at least one agriculturally acceptable salt thereof. a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula I

  本发明涉及2-氰基-3-(卤)烷氧基苯磺酰胺化合物I，其中变量Alk和R1至R5如权利要求1所定义，以及/或其在农业上有用的盐。此外，本发明还涉及使用化合物I和/或其盐来对抗动物害虫；包含至少一种通式I化合物和/或至少一种I的农业有用盐及至少一种惰性液体和/或固体农业上可接受的载体的农业组合物，其具有杀虫作用，如有需要，还包括至少一种表面活性剂；以及一种对抗动物害虫的方法，其中将至少一种2-氰基-3-(卤)烷氧基苯磺酰胺化合物I的杀虫有效量与动物害虫、它们的栖息地、繁殖地、食物供应、植物、种子、土壤、区域、材料或环境接触，或者接触需要保护免受动物攻击或侵害的材料、植物、种子、土壤、表面或空间。本发明还涉及一种保护种子免受土壤昆虫和由此产生的植物根和茎免受土壤和叶面昆虫的方法，其中在播种前和/或发芽前将种子与通式I的2-氰基-3-(卤)烷氧基苯磺酰胺化合物接触。
• NOVEL 2-CYANO-3(HALO)ALKOXY-BENZENESULFONAMIDE COMPOUNDS FOR COMBATING ANIMAL PESTS
  申请人：Deyn Wolfgang von

  公开号：US20080306297A1

  公开（公告）日：2008-12-11

  Novel 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds for combating animal pests The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R 1 to R 5 are as defined in claim 1 , and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds I and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula I and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula I and/or at least one agriculturally acceptable salt thereof. a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxybenzenesulfonamide compound of the general formula I

  本发明涉及2-氰基-3-(卤代)烷氧基苯磺酰胺化合物I，其中变量Alk和R1至R5如权利要求1所定义，和/或其在农业上有用的盐。此外，本发明还涉及使用化合物I和/或其盐来对抗动物害虫的方法；包括至少一种通式I化合物和/或至少一种I的农业上有用的盐以及至少一种惰性液体和/或固体农业上可接受的载体的农业组合物，以产生杀虫作用，如果需要，还包括至少一种表面活性剂；以及一种对抗动物害虫的方法，其中将至少一种2-氰基-3-(卤代)烷氧基苯磺酰胺化合物I或其农业上可接受的盐以杀虫有效量接触动物害虫、它们的栖息地、繁殖地、食物供应、植物、种子、土壤、区域、材料或动物害虫生长或可能生长的环境以及需要保护免受动物攻击或侵染的材料、植物、种子、土壤、表面或空间。还涉及一种使用2-氰基-3-(卤代)烷氧基苯磺酰胺通式I化合物的方法，用于保护种子免受土壤昆虫和由此产生的植物根和茎免受土壤和叶面昆虫的侵害，在播种前和/或发芽前将种子与通式I的2-氰基-3-(卤代)烷氧基苯磺酰胺化合物接触。
• 2-cyano-3(halo)alkoxy-benzenesulfonamide compounds for combating animal pests
  申请人：BASF Aktiengesellschaft

  公开号：US07544637B2

  公开（公告）日：2009-06-09

  The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts. Moreover, the present invention relates to the use of compounds I and/or their salts for combating animal pests; agricultural compositions comprising such an amount of at least one compound of the general formula I and/or at least one agriculturally useful salt of I and at least one inert liquid and/or solid agronomically acceptable carrier that it has a pesticidal action and, if desired, at least one surfactant; and a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the formula I and/or at least one agriculturally acceptable salt thereof. a method for the for the protection of seeds from soil insects and of the resulting plant's roots and shoots from soil and foliar insects comprising contacting the seeds before sowing and/or after pregermination with a 2-cyano-3-(halo)alkoxy-benzenesulfonamide compound of the general formula I

  本发明涉及2-氰基-3-(卤)烷氧基苯磺酰胺化合物I，其中变量Alk和R1至R5如权利要求1所定义，和/或它们的农业有用盐。此外，本发明涉及利用化合物I和/或其盐来对抗动物害虫的用途；包含至少一种通式I的化合物和/或至少一种I的农业有用盐以及至少一种惰性液体和/或固体农学上可接受的载体的农业组合物，其具有杀虫作用，并且如果需要，至少一种表面活性剂；以及一种对抗动物害虫的方法，包括用至少一种2-氰基-3-(卤)烷氧基苯磺酰胺化合物I和/或其农业上可接受的盐的杀虫有效量接触动物害虫、它们的栖息地、繁殖场、食物供应、植物、种子、土壤、区域、材料或动物害虫正在生长或可能生长的环境，或需要保护免受动物攻击或侵染的材料、植物、种子、土壤、表面或空间。一种用于保护种子免受土壤昆虫和由此产生的植物根和茎免受土壤和叶面昆虫的方法，包括在播种前和/或发芽前将种子接触2-氰基-3-(卤)烷氧基苯磺酰胺化合物I。
• Chemical compounds
  申请人：Maienfisch Peter

  公开号：US08524896B2

  公开（公告）日：2013-09-03

  A compound of the formula (I) where, for example, W, X and Y are each CH; R1 and R6 together with the adjacent nitrogen forms a 3 to 10-membered saturated ring, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms and/or heteroatom groups as ring members, independently of one another, selected from the group consisting of sulfur, CO, SO, SO2 and N—R7 and/or the ring may carry 1, 2 or 3 radicals, independently of one another, each selected, for example, from the group consisting of halogen, cyano, nitro, amino, and C1-C6-alkyl. R2 is, for example, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and R7 is for example, R10C(═O), C1-C6 alkyl or C1-C6-haloalkyl; and/or salts thereof; and their use as pesticidal agents.

  化合物的式子（I），其中，例如，W、X和Y均为CH；R1和R6与相邻的氮形成一个3到10个成员的饱和环，其中该环可以包含除氮和碳环成员之外的1、2或3个杂原子和/或杂原子基作为环成员，独立于彼此，从所述群组中选出，所述群组由硫、CO、SO、SO2和N-R7组成，和/或该环可以携带1、2或3个基团，独立于彼此，每个基团例如从卤素、氰基、硝基、氨基和C1-C6烷基中选出。例如，R2是卤素、C1-C6烷基、C1-C6卤代烷基、C1-C6烷氧基、C1-C6卤代烷氧基或C1-C6-烷氧基-C1-C6-烷氧基，R7例如为R10C（═O）、C1-C6烷基或C1-C6卤代烷基；以及它们的盐；以及它们作为杀虫剂的用途。
• CHEMICAL COMPOUNDS
  申请人：Pitterna Thomas

  公开号：US20100311582A1

  公开（公告）日：2010-12-09

  A compound of the formula (I) where, for example, W, X and Y are each CH; R 1 and R 6 , independently of each other, are for example, selected from the group consisting of H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C3-C8-cycloalkyl, R 7 C(═O), and a ring system; provided that at least one of R 1 and R 6 is a —C2-C6-alkenylthio-C1-C6-alkyl, —C1-C6-alkoxy-C(═O)NRx-C1-C6-alkyl, —partially or fully unsaturated ring system containing in at least one ring in the ring system at least one hetero atom selected from N, O and S, which ring system is bound (i.e. through the N bonded to R 1 and R 6 in formula I) either directly or via a a C1-C6-alkylene group to the remainder of the compound, —partially or fully unsaturated ring system containing a ring that is bound to the remainder of the compound (i.e. through the N bonded to R 1 and R 6 in formula I) via a C1-C6-alkylene group, which group contains at least one hetero atom and/or heteroatom group selected from N, O, S, SO, SO 2 , and C(=0), —a ring system having a 5- to 14-membered bicylic ring which may be unsubstituted or be substituted with 1, 2 or 3, independently of one another, radicals selected from halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy and C1-C6-haloalkoxy, or —(C3-C8-cyloalkyl)thio-C1-C6-alkyl; R 2 is, for example, H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and/or salts thereof; and their use as pesticidal agents.

  化合物的公式（I），其中，例如，W、X和Y都是CH；R1和R6彼此独立，例如，从H、C1-C6-烷基、C2-C6-烯基、C2-C6-炔基、C1-C6-烷氧基、C3-C8-环烷基、R7C（═O）和环系组成的群中选择；前提是R1和R6中至少有一个是-C2-C6-烯基硫基-C1-C6-烷基，-C1-C6-烷氧基-C（═O）NRx-C1-C6-烷基，部分或完全不饱和的环系，其中在环系中至少有一个环中含有N、O和S中选择的至少一个杂原子，该环系通过式I中与R1和R6结合的N直接或通过C1-C6-烷基链与化合物的其余部分结合，部分或完全不饱和的环系，其中有一个环通过C1-C6-烷基链与化合物的其余部分结合，该链含有至少一个N、O、S、SO、SO2和C（=0）中选择的杂原子和/或杂原子基，具有5-至14-成员的双环环系，可以是未取代的或被1、2或3个彼此独立的基团（选择自卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基和C1-C6-卤代烷氧基）取代的；R2，例如，是H、卤素、C1-C6-烷基、C1-C6-卤代烷基、C1-C6-烷氧基、C1-C6-卤代烷氧基或C1-C6-烷氧基-C1-C6-烷氧基，和/或其盐；以及它们作为杀虫剂的用途。