bis(benzonitrile)copper(II) dichloride | 16482-46-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(benzonitrile)copper(II) dichloride
• CAS: 16482-46-5
• 化学式: C₁₄H₁₀Cl₂CuN₂
• 分子量: 340.699
• InChiKey: DUVXIKLRLPPNIU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  正丁基锂 、 2H-1,3-dithiepin 、 bis(benzonitrile)copper(II) dichloride 、 四乙基溴化铵 在 二硫化碳 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以75%的产率得到tetraethylammonium copper(II) 1,3-dithiepin-2-carbodithiolate
  参考文献：
  名称：

  Syntheses and characterization of the palladium(II) and copper(II) complexes of the new 1,1-dithiolate ligand, 1,3-dithiepin-2-carbodithiolate

  摘要：

  The synthesis of a new 1,1-dithiolate ligand, 1,3-dithiepin-2-carbodithiolate (L2-), has been accomplished from the reaction of carbon disulfide with the lithium salt of 1,3-dithiepin. Copper(II) and palladium(II) complexes of the formula ML2(2-) were isolated as the tetraethylammonium salts. Proton nuclear magnetic resonance spectra of the free ligand and the palladium salt suggest a good deal of 'Huckel' aromatic character in the seven membered dithiepin ring. Electron spin resonance spin Hamiltonian parameters obtained from frozen glass samples of the copper(II) complex suggest a highly delocalized four membered chelate ring. Taken together, these data suggest the dithiepin ring is a strong pi-acceptor in these complexes.

  DOI：

  10.1016/s0020-1693(00)85440-7