甲基3-(二丁基氨基)-2-甲基丙酸酯 | 71735-20-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 甲基3-(二丁基氨基)-2-甲基丙酸酯
• 中文别名: 甲基3-(二丁基氨基)-2-甲基丙酸盐
• 英文名称: methyl 3-(dibutylamino)-2-methylpropionate
• 英文别名: Methyl β-(di-n-butylamino)-isobutyrat；methyl 3-(dibutylamino)-2-methylpropanoate
• CAS: 71735-20-1
• 化学式: C₁₃H₂₇NO₂
• mdl: MFCD12193179
• 分子量: 229.363
• InChiKey: JWMZBTCOXOGERJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.923
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲基3-(二丁基氨基)-2-甲基丙酸酯 、 phenylmagnesium bromide 以 乙醚 为溶剂， 生成 1.1-Diphenyl-2-methyl-3-(di-n-butylamino)propanol
  参考文献：
  名称：

  中枢神经系统制剂。1.二苯基叔氨基丙醇的合成。

  摘要：

  DOI：

  10.1021/jm00293a018
• 作为产物：
  描述：

  二正丁胺 、 甲基丙烯酸甲酯 在 四氯化硅 作用下， 生成 甲基3-(二丁基氨基)-2-甲基丙酸酯
  参考文献：
  名称：

  四氯化硅在无溶剂条件下催化胺与共轭烯烃的氮杂-迈克尔加成

  摘要：

  报道了在无溶剂条件下，在催化量的四氯化硅存在下，芳香族和脂肪族胺与 α,β-不饱和羰基化合物的有效且非常简单的共轭加成。芳基和烷基胺与不同的迈克尔受体反应得到相应的迈克尔加合物，催化剂简单，产率好到极好。

  DOI：

  10.1055/s-0029-1219195

文献信息

• SURFACE-COATING MATERIAL, COATED FILM, AND HYDROPHILIC/OIL-REPELLENT MATERIAL
  申请人：Mitsubishi Materials Corporation

  公开号：EP3176236A1

  公开（公告）日：2017-06-07

  There is provided a surface-coating material for forming a hydrophilic/oil-repellent layer on at least a part of the surface of a substrate, and the surface-coating material includes one or more fluorine-based compounds represented by the following formulas (1) to (4), a binder, and a solvent.

  提供了一种表面涂层材料，用于在基材表面的至少一部分形成亲水/憎油层，该表面涂层材料包括一种或多种由以下式子（1）至（4）表示的氟基化合物、粘合剂和溶剂。
• HYDROPHILIC OIL REPELLENT AGENT AND METHOD FOR MANUFACTURING SAME, AND SURFACE COVERING MATERIAL, COATING FILM, RESIN COMPOSITION, OIL-WATER SEPARATION FILTER MEDIUM, AND POROUS BODY
  申请人：Mitsubishi Materials Corporation

  公开号：EP3176237A1

  公开（公告）日：2017-06-07

  The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.

  亲水驱油剂包括一种或多种含氮氟基化合物。含氮氟基化合物分子中包括从阴离子型亲水赋予基团、阳离子型亲水赋予基团和两性型亲水赋予基团组成的组中选出的任意一个亲水赋予基团。
• Hydrophilic oil repellent and production method of same, surface coating material, coating film, resin composition, oil-water separation filter material, and porous body
  申请人：MITSUBISHI MATERIALS CORPORATION

  公开号：US10208210B2

  公开（公告）日：2019-02-19

  The hydrophilic oil repellent includes one or more types of nitrogen-containing fluorine-based compounds. The nitrogen-containing fluorine-based compound includes any one hydrophilicity imparting group selected from the group consisting of anion type hydrophilicity imparting groups, cation type hydrophilicity imparting groups, and amphoteric type hydrophilicity imparting groups in the molecule.

  亲水驱油剂包括一种或多种含氮氟基化合物。含氮氟基化合物分子中包括从阴离子型亲水赋予基团、阳离子型亲水赋予基团和两性型亲水赋予基团组成的组中选出的任意一个亲水赋予基团。
• Surface coating material, coating film, and hydrophilic oil repellent member
  申请人：MITSUBISHI MATERIALS CORPORATION

  公开号：US10364360B2

  公开（公告）日：2019-07-30

  A surface coating material is provided for forming a hydrophilic oil repellent layer on at least a part of the surface of a substrate, and the surface coating material includes one or more fluorine-based compounds represented by the following formulas (1) to (4), a binder, and a solvent.

  提供了一种表面涂层材料，用于在基材表面的至少一部分形成亲水性憎油层，该表面涂层材料包括一种或多种由以下式子（1）至（4）表示的氟基化合物、粘合剂和溶剂。
• Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts
  作者：Kelin Li、Peter N. Horton、Michael B. Hursthouse、King Kuok (Mimi) Hii

  DOI：10.1016/s0022-328x(02)02138-1

  日期：2003.1

  A series of cationic (diphosphine)palladium(II) complexes have been prepared and fully characterized, including two crystal structures. These complexes were evaluated as catalysts for the hydroamination of acyclic alkenes. The reactivity of the catalysts is dependent on the nature of the diphosphine ligand and the substituents on the amine and alkene substrates. (C) 2002 Elsevier Science B.V. All rights reserved.