2-(4-tert-butylphenyl)-5-(4-vinylphenyl)-[1,3,4]-oxadiazole | 253878-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-tert-butylphenyl)-5-(4-vinylphenyl)-[1,3,4]-oxadiazole
• 英文别名: 2-(4-Tert-butylphenyl)-5-(4-vinylphenyl)-1,3,4-oxadiazole；2-(4-tert-butylphenyl)-5-(4-ethenylphenyl)-1,3,4-oxadiazole
• CAS: 253878-38-5
• 化学式: C₂₀H₂₀N₂O
• 分子量: 304.392
• InChiKey: QIABKSAHMWPSQL-UHFFFAOYSA-N

物化性质

• 沸点：
  442.4±48.0 °C(Predicted)
• 密度：
  1.079±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-溴-1,8-萘二甲酸酐 、 2-(4-tert-butylphenyl)-5-(4-vinylphenyl)-[1,3,4]-oxadiazole 在 potassium phosphate 、 palladium diacetate 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以74%的产率得到
  参考文献：
  名称：

  萘酰亚胺-若丹明染料的合成和聚集诱导的发射增强

  摘要：

  设计并合成了一系列具有不同末端结构的萘二甲亚胺-罗丹明染料L 1-4。罗丹明用作萘二甲酰亚胺的庞大刚性取代基，以增强AIE性能。所有的萘二甲亚胺-若丹明染料均表现出明显的聚集诱导的发射增强。观察到固态的强荧光发射，发射峰的范围为549至608 nm。在高f W混合溶液中，荧光强度随含水量的增加而增强，这可归因于两种聚集诱导的形态。制备了AIE染料掺杂的二氧化硅纳米粒子（Si-NPs），并在纯水中表现出良好的溶解性。另外，染料L 1和L 2表现出对Hg 2+离子的选择性识别，并成功应用于活细胞中的生物图像。研究了从萘二甲酰亚胺部分到若丹明部分的分子内荧光共振能量转移机理。

  DOI：

  10.1016/j.jphotochem.2016.06.020
• 作为产物：
  描述：

  对溴苯甲酰肼 在 吡啶 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 甲苯 为溶剂， 反应 86.5h， 生成 2-(4-tert-butylphenyl)-5-(4-vinylphenyl)-[1,3,4]-oxadiazole
  参考文献：
  名称：

  EMISSIVE COMPOUNDS FOR ORGANIC LIGHT-EMITTING DIODES

  摘要：

  本文披露了包含可选择取代的(2-苯基吡啶基-N,C2′)(2,4-戊二酮基)Pt(II)的化合物。一些实施例提供了一种发光装置，包括：阳极层；阴极层；以及位于阳极层和阴极层之间并与之电连接的发光层，其中该发光层包括本文披露的化合物。

  公开号：

  US20130087772A1

文献信息

• Degenerate nonlinear absorption and optical power limiting properties of asymmetrically substituted stilbenoid chromophoresElectronic supplementary information (ESI) available: Experimental details. See http://www.rsc.org/suppdata/jm/b3/b313185h/
  作者：Tzu-Chau Lin、Guang S. He、Paras N. Prasad、Loon-Seng Tan

  DOI：10.1039/b313185h

  日期：——

  Two-photon absorption (2PA) spectra (650–1000 nm) of a series of model chromophores were measured via a newly developed nonlinear absorption spectral technique based on a single and powerful femtosecond white-light continuum beam. The experimental results suggested that when either an electron-donor or an electron-acceptor was attached to a trans-stilbene at a para-position, an enhancement in molecular two-photon absorptivity was observed in both cases, particularly in the 650–800 nm region. However, the push–pull chromophores with both the donor and acceptor groups showed larger overall two-photon absorption cross-sections within the studied spectral region as compared to their mono-substituted analogues. The combined results of the solvent effect and the 1H-NMR studies indicated that stronger acceptors produce a more efficient intramolecular charge transfer character upon excitation, leading to increased molecular two-photon responses in this model-compound set. A fairly good 2PA based optical power limiting behavior from one of the model chromophores is also demonstrated.

  通过一种基于单个强飞秒白光连续波束的新型非线性吸收光谱技术，测定了系列模型染料在650-1000 nm范围内的双光子吸收（2PA）光谱。实验结果表明，当电子供体或电子受体分别连接到反式-均二苯代乙烯的邻位时，两种情况下都观察到分子双光子吸收性的增强，尤其是在650-800 nm区域。然而，与单取代的类似物相比，同时含有供体和受体基团的推-拉型染料在整个研究光谱范围内表现出更大的双光子吸收截面。溶剂效应和1H-NMR研究的联合结果表明，更强的受体在激发时产生更有效的分子内电荷转移特性，导致该模型化合物系列中的分子双光子响应增强。其中一种模型染料的相当好的2PA基光学功率限制行为也被展示。
• Enhanced two-photon absorption of novel four-branched chromophore via vibronic coupling
  作者：Deqiang Wang、Xiaomei Wang、Qingguo He、Maoyi Zhou、Wenwen Rui、Xutang Tao、Fenglian Bai、Minhua Jiang

  DOI：10.1016/j.tetlet.2008.07.116

  日期：2008.10

  A novel four-branched chromophore TOZ-4 with starburst linker was synthesized and showed two-photon absorption cross-section (δ) as large as 5254 GM, which was principally resulted from vibronic coupling enhancement.

  合成了一种新型的带有星爆连接基团的四支发色团TOZ-4，其显示出大至5254 GM的双光子吸收截面（δ），这主要是由于振动耦合的增强。
• A field-dependent organic LED consisting of two new high Tg blue light emitting organic layers: a possibility of attainment of a white light sourceElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/jm/b2/b209949g/
  作者：Soon Wook Cha、Jung-Il Jin

  DOI：10.1039/b209949g

  日期：2003.2.20

  Two new blue light emitting trimeric compounds of the Y-shape type having high glass transition temperatures were synthesized and EL behavior of LED devices consisting of bilayers of the two compounds was studied. One of the compounds is of hole-transporting type containing carbazole moieties, whereas the other is of electron-transporting type bearing phenyloxadiazole moieties. The bilayer LED devices exhibit a strong field-dependence and emit white light (simultaneous light-emittance in blue, green and red regions), at high applied electric fields. Increased interfacial formation of exciplexes at stronger external fields appears to be responsible for this field-dependence.

  合成了两种新的Y形蓝光发射三聚体化合物，它们具有较高的玻璃转变温度，并研究了由这两种化合物双层组成的LED器件的电致发光行为。其中一种化合物为输送孔穴的类型，含有咔唑基团，而另一种则为输送电子的类型，具有苯基噁二唑基团。在高施加电场下，双层LED器件表现出强烈的场依赖性，并发出白光（在蓝色、绿色和红色区域同时发光）。在更强的外部电场下，界面处激发态复合物的增生似乎是这种场依赖性的原因。
• Degenerate two-/three-photon absorption and optical power-limiting properties in femtosecond regime of a multi-branched chromophore
  作者：Tzu-Chau Lin、Guang S. He、Qingdong Zheng、Paras N. Prasad

  DOI：10.1039/b603119f

  日期：——

  The degenerate two- and three-photon absorption properties of a multi-branched chromophore were investigated in the femtosecond regime utilizing white-light continuum and nonlinear transmission techniques. The experimental results show that the studied multi-branched structure exhibits relatively strong and broad two- and three-photon absorption bands in the near infra-red (IR) region. It is demonstrated that a highly conjugated molecular structure based on a symmetrically substituted skeleton would possess promoted molecular nonlinear absorptivities within the studied spectral region. Both two- and three-photon absorption-based optical power-limiting properties in the femtosecond time domain of this model compound were also characterized. The results indicate that a multi-chromophoric structure with expanded π-conjugation could be an effective multi-photon absorber and might be used as a single-component material system for quick-responsive and broadband optical-suppressing related applications, especially when under ultrashort laser pulses.

  利用白光连续和非线性透射技术研究了一种多支链发色团在飞秒级的退化双光子和三光子吸收特性。实验结果表明，所研究的多支链结构在近红外（IR）区域表现出相对较强和较宽的双光子和三光子吸收带。实验证明，基于对称取代骨架的高共轭分子结构在所研究的光谱区域内具有更高的分子非线性吸收率。研究还对该模型化合物在飞秒时域内基于双光子和三光子吸收的光功率限制特性进行了表征。研究结果表明，具有扩展π共轭的多色素结构是一种有效的多光子吸收体，可作为单组分材料系统用于快速响应和宽带光抑制相关应用，尤其是在超短激光脉冲下。
• 一种噁二唑三苯胺-氟硼二吡咯红光化合物 OPA-BODIPY及其制备方法和应用
  申请人：东南大学

  公开号：CN106496260B

  公开（公告）日：2018-03-23

  本发明公开了一种噁二唑三苯胺‑氟硼二吡咯红光化合物OPA‑BODIPY。本发明还公开了该噁二唑三苯胺‑氟硼二吡咯红光化合物OPA‑BODIPY的制备方法及其应用。本发明的新型化合物OPA‑BODIPY是包含2,5‑二苯基噁二唑、三苯胺及1,3,5,7‑四甲基氟硼二吡咯3种复合荧光基团的树形红光染料，固态及水溶液中发射红色荧光，具有优良的聚集诱导荧光增强性能。可作为性能优异的红光染料，在近红外荧光成像、荧光传感器、生物荧光分析、荧光标记等领域具有广泛应用。