Perfluoro(3-propoxypropionyl) fluoride | 356-61-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: Perfluoro(3-propoxypropionyl) fluoride
• 英文别名: tetrafluoro-3-(heptafluoro-propoxy)-propionyl fluoride；Tetrafluor-3-(heptafluor-propoxy)-propionylfluorid；perfluoro (3-(n-propoxy)propionyl fluoride)；CF3CF2CF2Ocf2CF2cof；2,2,3,3-tetrafluoro-3-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl fluoride
• CAS: 356-61-6
• 化学式: C₆F₁₂O₂
• 分子量: 332.046
• InChiKey: RSRKJNROIOOTCO-UHFFFAOYSA-N

物化性质

• 沸点：
  59 °C
• 密度：
  1.688±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  Perfluoro(3-propoxypropionyl) fluoride 在 sodium hydroxide 、 硫酸 作用下， 生成 tetrafluoro-3-(heptafluoro-propoxy)-propionic acid methyl ester
  参考文献：
  名称：

  Fluorocarbon acids and derivatives

  摘要：

  公开号：

  US02713593A1
• 作为产物：
  描述：

  3-丙氧基丙酰氯 在 氢氟酸 作用下， 生成 Perfluoro(3-propoxypropionyl) fluoride
  参考文献：
  名称：

  Fluorocarbon acids and derivatives

  摘要：

  公开号：

  US02713593A1

文献信息

• CARBOXYLIC ACID ESTER/CARBAMATE COMPOUND WITH POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND MANUFACTURING METHOD THEREFOR
  申请人：UNIMATEC CO., LTD.

  公开号：US20160185714A1

  公开（公告）日：2016-06-30

  Provided are a fluorine-containing monomer soluble in a hydrocarbon-based solvent as well as excellent in water and oil repellence, and a manufacturing method therefor. The fluorine-containing monomer is a carboxylic acid ester/carbamate compound having a polymerizable functional group and a fluorine atom group, and represented by the following general formula: C a F 2a+1 O—(C b F 2b O) c —C 2 F 4 COO—Z—(CONHR) d . The method for manufacturing the carboxylic acid ester/carbamate compound is comprised of the steps of making an isocyanate compound having a polymerizable functional group react with an alcohol such as a polyalkylene glycol, a cycloalkane dimethanol, or a polyhydric alcohol to produce a hydroxycarbamate, and subsequently making the resulting hydroxycarbamate react with a perfluoropolyether carboxylic acid halide.

  提供了一种可溶于烃基溶剂且具有优异的水和油抗性的含氟单体及其制造方法。该含氟单体是一种具有可聚合官能团和氟原子团的羧酸酯/氨基甲酸酯化合物，由以下通式表示：CaF2a+1O—(CbF2bO)c—C2F4COO—Z—(CONHR)d。制造羧酸酯/氨基甲酸酯化合物的方法包括以下步骤：使具有可聚合官能团的异氰酸酯化合物与醇反应，例如聚烷基醚、环烷基二甲醇或多元醇，生成羟基氨甲酸酯，然后使所得的羟基氨甲酸酯与全氟聚醚羧酸卤化物反应。
• Synthesis of new nitrogen-containing perfluoroalkyl iodides
  作者：Haruhiko Fukaya、Eiji Hayashi、Yoshio Hayakawa、Takashi Abe

  DOI：10.1016/s0022-1139(97)00011-0

  日期：1997.7

  perfluoropiperidino- and perfluoropropoxy-subs perfluoroalkyl iodides were synthesized directly by the reaction of the corresponding perfluoroacyl fluorides with lithium iodide in high yield. Under controlled reaction conditions, it was possible to synthesize either iodo-perfluoroacyl fluorides or perfluoroalkylidene diiodides by the reaction of perfluoro(alkanedioyl) difluorides with lithium iodide. Perfluoro(

  通过相应的全氟酰基氟与碘化锂的高产率直接合成全氟（二甲基氨基）-，全氟（二乙基氨基）-，全氟（1-吡咯烷基）-，全氟吗啉代-，全氟哌啶子基和全氟丙氧基-亚砜全氟烷基碘。在受控的反应条件下，可以通过全氟（链烷二酰基）二氟化物与碘化锂的反应来合成碘-全氟酰基氟或全氟亚烷基二碘化物。全氟（α-烷基氨基取代的烷基）碘化物可能是太阳泵浦激光器介质的良好候选者。
• Process for producing a fluorine-containing compound by liquid phase fluorination
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20030204099A1

  公开（公告）日：2003-10-30

  The invention provides a process for producing a fluorine-containing compound from an inexpensive material. Namely, Compound I such as R A CH 2 OH is reacted with Compound II such as XCOR B to form Compound III such as R A CH 2 OCOR B , followed by fluorination in a liquid phase to form Compound IV such as R AF CF 2 OCOR BF , which is converted to Compound V such as R AF COF and/or Compound VI such as R BF COF. R A is an alkyl group or the like, R B is a perhalogenoalkyl group or the like, R AF and R BF are fluorinated R A and R B , and X is halogen.

  本发明提供了一种从廉价材料制备含氟化合物的方法。即，将化合物I，如RACH2OH，与化合物II，如XCORB，反应形成化合物III，如RACH2OCORB，然后在液相中进行氟化反应形成化合物IV，如RAFCF2OCORBF，然后将其转化为化合物V，如RAFCOF和/或化合物VI，如RBFCOF。其中，RA是烷基或类似物，RB是全氟烷基或类似物，RAF和RBF是氟化的RA和RB，X是卤素。
• Process for producing a fluorine containing compound by liquid phase fluorination
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20020022752A1

  公开（公告）日：2002-02-21

  The invention provides a process for producing a fluorine-containing compound from an inexpensive material. Namely, Compound I such as R A CH 2 OH is reacted with Compound II such as XCOR B to form Compound III such as R A CH 2 OCOR B , followed by fluorination in a liquid phase to form Compound IV such as R AF CF 2 OCOR BF , which is converted to Compound V such as R AF COF and/or Compound VI such as R BF COF. R A is an alkyl group or the like, R B is a perhalogenoalkyl group or the like, R AF and R BF are fluorinated R A and R B , and X is halogen.

  本发明提供了一种从廉价材料制备含氟化合物的方法。具体而言，化合物I（例如RACH2OH）与化合物II（例如XCORB）反应，形成化合物III（例如RACH2OCORB），随后在液相中进行氟化反应，形成化合物IV（例如RAFCF2OCORBF），然后将其转化为化合物V（例如RAFCOF）和/或化合物VI（例如RBFCOF）。RA是烷基或类似物，RB是全氟烷基或类似物，RAF和RBF是氟化的RA和RB，X是卤素。
• Gubanov, V. A.; Zevakin, I. A.; Gurari, V. E., Journal of Organic Chemistry USSR (English Translation), 1981, p. 1409 - 1412
  作者：Gubanov, V. A.、Zevakin, I. A.、Gurari, V. E.、Tumanova, A. V.、Dolgopol'skii, I. M.、et al.

  DOI：——

  日期：——