2-[(1,1,1',1'-tetramethyl-5',6,6'-tripyridin-2-yloxy-3,3'-spirobi[2H-indene]-5-yl)oxy]pyridine | 1190746-34-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-[(1,1,1',1'-tetramethyl-5',6,6'-tripyridin-2-yloxy-3,3'-spirobi[2H-indene]-5-yl)oxy]pyridine
• CAS: 1190746-34-9
• 化学式: C₄₁H₃₆N₄O₄
• 分子量: 648.761
• InChiKey: IVNKZFZEEQGRPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  49
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  88.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-溴吡啶 、 5,5',6,6'-四羟基-3,3,3',3'-四甲基-1,1'-螺旋联吲哚 在 potassium carbonate 作用下， 以 环丁砜 、 甲苯 为溶剂， 反应 48.75h， 以46%的产率得到2-[(1,1,1',1'-tetramethyl-5',6,6'-tripyridin-2-yloxy-3,3'-spirobi[2H-indene]-5-yl)oxy]pyridine
  参考文献：
  名称：

  New three- and four-armed flexible bridging ligands for use in metallosupramolecular chemistry: syntheses and X-ray structures

  摘要：

  Preparations are described of twelve new tritopic and tetratopic ligands by coupling of two phenolic precursors with a range of heterocyclic units. X-ray crystal structures of four representative examples revealed the conformations in the solid state with the nitrogen donor atoms separated by distances ranging from 10.9 to 18.2 angstrom. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.07.068

文献信息

• COMPOUND COMPRISING PHENYL PYRIDINE UNITS
  申请人：Ye Qing

  公开号：US20090289547A1

  公开（公告）日：2009-11-26

  Organic compounds of formula I may be used in optoelectronic devices wherein R 1 is, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; R2 is, independently at each occurrence, a C 1 -C 20 aliphatic radical, a C 3 -C 20 aromatic radical, or a C 3 -C 20 cycloaliphatic radical; a is, independently at each occurrence, an integer ranging from 0-4; b is, independently at each occurrence, an integer ranging from 0-3; Ar 1 is a direct bond or heteroaryl, aryl, or alkyl or cycloalkyl; Ar 2 is heteroaryl, aryl, or alkyl or cycloalkyl; c is 0, 1 or 2; and n is an integer ranging from 2-4.

  化学式I的有机化合物可用于光电子器件，其中R1在每次出现时独立地是C1-C20脂肪基、C3-C20芳香基或C3-C20环脂肪基；R2在每次出现时独立地是C1-C20脂肪基、C3-C20芳香基或C3-C20环脂肪基；a在每次出现时独立地是0-4之间的整数；b在每次出现时独立地是0-3之间的整数；Ar1是直接键或杂环芳基、芳基、烷基或环烷基；Ar2是杂环芳基、芳基、烷基或环烷基；c为0、1或2；n是2-4之间的整数。
• US8039125B2
  申请人：——

  公开号：US8039125B2

  公开（公告）日：2011-10-18
• US8053095B2
  申请人：——

  公开号：US8053095B2

  公开（公告）日：2011-11-08
• US8062768B2
  申请人：——

  公开号：US8062768B2

  公开（公告）日：2011-11-22
• New three- and four-armed flexible bridging ligands for use in metallosupramolecular chemistry: syntheses and X-ray structures
  作者：Justine R.A. Cottam、Peter J. Steel

  DOI：10.1016/j.tet.2009.07.068

  日期：2009.9

  Preparations are described of twelve new tritopic and tetratopic ligands by coupling of two phenolic precursors with a range of heterocyclic units. X-ray crystal structures of four representative examples revealed the conformations in the solid state with the nitrogen donor atoms separated by distances ranging from 10.9 to 18.2 angstrom. (C) 2009 Elsevier Ltd. All rights reserved.