丙烯酰二甲基牛磺酸铵/乙烯甲酰胺共聚物 | 58374-69-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: 丙烯酰二甲基牛磺酸铵/乙烯甲酰胺共聚物
• 中文别名: 2-甲基-2-[(1-氧代-2-丙烯基)氨基]-1-丙磺酸一钠盐
• 英文名称: 2-acrylamido-2-methyl-1-propanesulfonic acid, ammonium salt
• 英文别名: ammonium acryloyldimethyltaurate；azanium;N-(2-methyl-1-sulfopropan-2-yl)prop-2-enimidate
• CAS: 58374-69-9
• 化学式: C₇H₁₃NO₄S*H₃N
• 分子量: 224.281
• InChiKey: BQMNFPBUAQPINY-UHFFFAOYSA-N

物化性质

• 沸点：
  66.3-283.9℃ at 101.325kPa
• 密度：
  1.16 at 19℃
• LogP：
  -2.8 at 24℃ and pH6.9-7.79
• 表面张力：
  52.9mN/m at 1g/L and 20℃
• 解离常数：
  2.4 at 20℃

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  95.7
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-丙烯酰胺基-2-甲基丙磺酸 在 氨 作用下， 以 叔丁醇 为溶剂， 生成 丙烯酰二甲基牛磺酸铵/乙烯甲酰胺共聚物
  参考文献：
  名称：

  Oxidation dyeing composition for keratinous fibres on amphiphilic polymers of at least an ethylenically unsaturated monomer with sulphonic group and comprising a hydrophobic part

  摘要：

  本发明涉及一种用于角蛋白纤维的氧化染色组合物，特别是用于人类角蛋白纤维，更特别是用于头发，所述组合物包括至少一种适用于染色的介质中的氧化染色剂，以及至少一种含有至少一种具有磺酸基的乙烯基不饱和单体的两亲性聚合物，其在自由形式或部分或完全中和的形式下进一步至少具有一个疏水部分。本发明还涉及使用所述组合物的染色方法和装置。

  公开号：

  US20050086745A1

文献信息

• NOVEL POWDERED POLYMER, PREPARATION METHOD THEREOF AND USE OF SAME AS A THICKENER
  申请人：Braun Olivier

  公开号：US20120172457A1

  公开（公告）日：2012-07-05

  Disclosed is a branched or crosslinked anionic polyelectrolyte of at least one monomer having a partially- or totally-salified strong acid function, with at least one neutral monomer and at least one monomer having formula (I), wherein: R represents a linear or branched alkyl radical including between 8 and twenty carbon atoms, and n represents a number greater than or equal to 1 and less than or equal to twenty. Also described is the use thereof as a thickener in topical compositions.

  本发明涉及一种分支或交联的阴离子聚电解质，该聚电解质由至少一种具有部分或完全盐化的强酸功能单体，至少一种中性单体和至少一种具有公式（I）的单体组成，其中：R表示包括8至20个碳原子的线性或支链烷基基团，n表示大于或等于1且小于或等于20的数字。还描述了其作为局部组成物中的增稠剂的用途。
• Polymerizable sulfonate ionic liquids and liquid polymers therefrom and methods of making same
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US08134024B2

  公开（公告）日：2012-03-13

  Disclosed is a new ionic liquid monomer salt and methods of is synthesis and polymerization. The ionic liquid monomer salt is prepared by mixing equimolar amounts of an amine, such as tris[2-(2-methoxyethoxy)-ethyl]amine and an acid functionalized polymerizable monomer, such as 2-acrylamido-2-methyl-1-propanesulfonic acid, which is stirred at ambient temperature until salt formation is complete. Also disclosed is a new ionic liquid polymer salts and method for making the same. The synthesis of 2-acrylamido-2-methyl-1-propanesulfonic acid-ammonium salt polymer is accomplished by adding 2,2′-azobisisobutyronitrile (AIBN) to the ionic liquid monomer salt and heating the homogeneous melt at 70° C. for 18 hr.

  本发明涉及一种新的离子液体单体盐及其合成和聚合方法。该离子液体单体盐是通过将胺（例如三[2-(2-甲氧基乙氧基)-乙基]胺）和酸官能化可聚合单体（例如2-丙烯酰胺基-2-甲基-1-丙磺酸）的等摩尔量混合，并在室温下搅拌直至盐形成完毕而制备的。本发明还涉及一种新的离子液体聚合物盐及其制备方法。通过将2,2'-偶氮丙二腈（AIBN）加入离子液体单体盐中，并在70℃下均匀熔融18小时，可以制备2-丙烯酰胺基-2-甲基-1-丙磺酸铵盐聚合物。
• An injection water viscosifier for enhanced oil recovery
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0094898A2

  公开（公告）日：1983-11-23

  High molecular weight N,N-dimethylacrylamide copolymers and terpolymers were synthesized. These polymers offer outstanding advantages as injection water viscosifiers in enhanced oil recovery processes including chemical, miscible, and steam or in processes requiring profile improvement through adsorption and/or gelation. They are very valuable in applications where high salinity is a problem since they are relatively insensitive to metal salts (such as those containing polyvalent ions, such as Ca++ and Mg++).

  合成了高分子量的 N,N-二甲基丙烯酰胺共聚物和三元共聚物。这些聚合物作为注水增粘剂在提高石油采收率工艺（包括化学、混溶和蒸汽）或需要通过吸附和/或凝胶化改善剖面的工艺中具有突出优势。这些聚合物对金属盐（如含有 Ca++ 和 Mg++ 等多价离子的金属盐）相对不敏感，因此在高盐度的应用中非常有价值。
• Thickeners having two ionic components and use thereof in aqueous compositions
  申请人：HENKEL CORPORATION (a Delaware corp.)

  公开号：EP0191184A2

  公开（公告）日：1986-08-20

  A thickener composition comprised of a polymer having as the major recurring structural unit an acryl-amidoal- kanesulfonic acid or derivative thereof and a polyvalent metal crosslinking agent is provided. The compositions are useful for thickening aqueous solutions within a specified range of pH. The thickener is effective even in aqueous compositions having high levels of electrolytes.

  本发明提供了一种增稠剂组合物，该组合物由具有丙烯酰-氨基醛-甲烷磺酸或其衍生物作为主要重复结构单元的聚合物和多价金属交联剂组成。 该组合物可用于增稠指定 pH 值范围内的水溶液。 即使在电解质含量较高的水溶液组合物中，该增稠剂也是有效的。
• Energy efficient high solids slurry stabilizers
  申请人：HENKEL CORPORATION (a Delaware corp.)

  公开号：EP0205744A2

  公开（公告）日：1986-12-30

  High solids slurry stabilizers are provided which are comprised of an acid-sensitive crosslinked polysaccharide and a water-soluble polymer having repeating units derived from an acrylamidoalkanesulfonic acid or the ammonium salt thereof, e.g. a homopolymer of 2-acrylamido-2-methylpropanesulfonic acid. The stabilizer compositions are effective in providing homogeneous stabilized aqueous slurries of finely divided solids, e.g. zircon flour, without the need for high energy mixing. The invention also provides methods for varying high solid slurries using such stabilizer compositions and high solid slurries comprised of such stabilizer compositions. The invention also provides for high solids slurries comprised of a water-soluble polymer having repeating units derived from the ammonium salt of an acrylamidoalkanesulfonic acid as the sole stabilizer and to methods of preparing such slurries.

  本发明提供的高固体浆料稳定剂由酸敏感交联多糖和水溶性聚合物组成，水溶性聚合物的重复单元来源于丙烯酰胺基烷磺酸或其铵盐，例如 2-丙烯酰胺基-2-甲基丙磺酸的均聚物。本发明的稳定剂组合物能有效地提供均匀稳定的细粒固体（如锆英石粉）水浆，而无需高能量混合。本发明还提供了使用此类稳定剂组合物和由此类稳定剂组合物组成的高固体淤浆的变化方法。本发明还提供了由具有源自丙烯酰胺基烷磺酸铵盐的重复单元的水溶性聚合物作为唯一稳定剂的高固体浆料，以及制备这种浆料的方法。