4'-氨基磺酰基-4-联苯基羧酸 | 114879-31-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4'-氨基磺酰基-4-联苯基羧酸
• 英文名称: 4-sulfobiphenyl-4'-carboxylic acid
• 英文别名: 4'-sulfo-biphenyl-4-carboxylic acid；4'-Sulfo-biphenyl-carbonsaeure-(4)；4'-Sulfo-biphenyl-4-carbonsaeure；4-(4-sulfophenyl)benzoic Acid
• CAS: 114879-31-1
• 化学式: C₁₃H₁₀O₅S
• 分子量: 278.285
• InChiKey: PWULGFUNKQJPNG-UHFFFAOYSA-N

物化性质

• 密度：
  1.464±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4'-氨基磺酰基-4-联苯基羧酸 、 氢氧化钾 、 sodium hydroxide 以62%的产率得到
  参考文献：
  名称：

  ADOMENAS, P. V.;VOSILENE, E. S.;LABANAUSKAS, L. K.;PYATRAJTIS, YU. K., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 30,(1987) N 10, 115-117

  摘要：

  DOI：
• 作为产物：
  描述：

  4-溴茴香硫醚 在 四(三苯基膦)钯 N-甲基吡咯烷酮 、 air 、 sodium thiomethoxide 、 金 、 potassium carbonate 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 反应 72.0h， 生成 4'-氨基磺酰基-4-联苯基羧酸
  参考文献：
  名称：

  Deep UV Photopatterning of Biphenyl Thiol Self-Assembled Monolayer and its Physical Properties

  摘要：

  Aromatic thiol such as a 4'-mercapto-biphenyl-4-carboxylic acid was synthesized, and then the self-assembled monolayer (SAM) was fabricated on a gold substrate. The pattern formation of biphenyl thiol and alkanethiol SAMs was obtained by oxidation reaction due to the irradiation of deep UV light. The resulting positive pattern image and current-voltage (I-V) characteristics of biphenyl thiol and alkanethiols were investigated through the measurements of Atomic Force Microscope (AFM) and Scanning Tunneling Microscope (STM). In addition, cytochrome c protein was immobilized onto the patterned gold substrate by self-assembly technique and electrochemical activity was studied with a cyclic voltammetry.

  DOI：

  10.1080/15421400601027981

文献信息

• McCorkle, Iowa State College Journal of Science, 1939, vol. 14, p. 64
  作者：McCorkle

  DOI：——

  日期：——
• A Cu II coordination polymer based on incorporated carboxylate and sulfonate groups: Synthesis, crystal structure, and magnetic properties
  作者：Yinfeng Han、Zebao Zheng、Chang’an Wang、Jiafeng Sun、Xiaoyan Li、Jianping Zhang、Jing Xiao、Guofang He、Liqing Li

  DOI：10.1016/j.molstruc.2014.09.025

  日期：2015.1

  A Cu-II coordination polymer, [Cu(sbpc)(phen)(H2O)]center dot H2O 1, has been synthesized and characterized structurally and magnetically (H(2)sbpc = 4-sulfobiphenyl-4'-carboxylic acid, phen = 1,10-phenanthroline). Single-crystal structural analysis shows that 1 consists of dinuclear [Cu-2(CO2)(2)] units bridged via sbpc(2-) to afford a 1-D chain, which then extends into the 3-D coordination polymer supramolecular network by O-H...O hydrogen bonds and pi...pi interactions. Magnetic measurements indicate that complex 1 exhibits weak antiferromagnetic coupling. (C) 2014 Elsevier B.V. All rights reserved.
• Deep UV Photopatterning of Biphenyl Thiol Self-Assembled Monolayer and its Physical Properties
  作者：Se Young Oh、Hee Jeong Kim、Hyung Seok Choi

  DOI：10.1080/15421400601027981

  日期：2007.1.22

  Aromatic thiol such as a 4'-mercapto-biphenyl-4-carboxylic acid was synthesized, and then the self-assembled monolayer (SAM) was fabricated on a gold substrate. The pattern formation of biphenyl thiol and alkanethiol SAMs was obtained by oxidation reaction due to the irradiation of deep UV light. The resulting positive pattern image and current-voltage (I-V) characteristics of biphenyl thiol and alkanethiols were investigated through the measurements of Atomic Force Microscope (AFM) and Scanning Tunneling Microscope (STM). In addition, cytochrome c protein was immobilized onto the patterned gold substrate by self-assembly technique and electrochemical activity was studied with a cyclic voltammetry.
• ADOMENAS, P. V.;VOSILENE, E. S.;LABANAUSKAS, L. K.;PYATRAJTIS, YU. K., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 30,(1987) N 10, 115-117
  作者：ADOMENAS, P. V.、VOSILENE, E. S.、LABANAUSKAS, L. K.、PYATRAJTIS, YU. K.

  DOI：——

  日期：——