bis(trichloroethenyl)mercury | 10507-38-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: bis(trichloroethenyl)mercury
• 英文别名: bis(trichlorovinyl)mercury；bis-trichlorovinyl-mercury；Quecksilber-bis-trichloraethylenid；Bis-trichlorvinyl-quecksilber；Mercuritrichloraethylenid；Bis(trichlorovinyl)quecksilberchlorid；Mercury, bis(trichloroethenyl)-；bis(1,2,2-trichloroethenyl)mercury
• CAS: 10507-38-7
• 化学式: C₄Cl₆Hg
• 分子量: 461.352
• InChiKey: RIPLALIEIHZWKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.75
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  bis(trichloroethenyl)mercury 在 C₂H₄(P(C₆H₅)2)2 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Bell, N. A.; Nowell, I. W.; Reynolds, P. A., Journal of Organometallic Chemistry, 1980, vol. 193, p. 147 - 154

  摘要：

  DOI：
• 作为产物：
  描述：

  三氯乙烯 、 alkaline earth salt of/the/ methylsulfuric acid 在 alkali 作用下， 生成 bis(trichloroethenyl)mercury
  参考文献：
  名称：

  Fitz Gibbon, Journal of the Chemical Society, 1938, p. 1220,1221

  摘要：

  DOI：

文献信息

• Hofmann,K.A.; Kirmreuther, Chemische Berichte, 1908, vol. 41, p. 314
  作者：Hofmann,K.A.、Kirmreuther

  DOI：——

  日期：——
• Reactions of trichlorovinylmercurials with potential non-chelating bidentate ligands. Crystal structures of [(C2Cl3)2Hg (4,4′-bipyridyl)] (1), [C2Cl3Hg(2-pyridyl thiolate)] (12) and polymeric HgBr2(2,2′-dipyridyl disulfide) (10)
  作者：Norman A. Bell、Thomas Gelbrich、Michael B. Hursthouse、Mark E. Light、Annette Wilson

  DOI：10.1016/s0277-5387(00)00554-4

  日期：2000.12

  Reactions of C2Cl3HgX (X = C2Cl3, Cl, Br) with the potential bidentate ligands, bis(diphenylphosphino)methane, 2,4'-bipyridyl, 4,4'-bipyridyl and 2,2'-dipyridyl disulfide(PySSPy), in a 2:1 molar ratio have been studied and the thermal and infrared spectral characteristics of the products have been examined. Complexes were isolated for (C2Cl3)(2)Hg and C2Cl3HgCl in all cases apart from between (C2Cl3)(2)Hg and the diphosphine. The diphosphine and 2,2'-dipyridyl disulfide formed 1:1 complexes (7, 6) with C2Cl3HgCl, whereas with (C2Cl3)(2)Hg the latter ligand formed [(C2Cl3)(2)Hg}(2)(PySSPy)] (3) which on standing formed C2Cl3HgSPy (12). 4,4'-Bipyridyl and 2,4'-bipyridyl differed in the stoichiometry of the isolated complexes. (C2Cl3)(2)Hg formed 1:1 complexes (1, 2) with both ligands whereas C2Cl3HgCl formed a 1:1 complex (4) with the former ligand but a 1:2 complex (5) with the latter. All four ligands caused disproportionation of C2Cl3HgBr with resulting isolation of the mercury(II) bromide complexes (8-11). The structure of [(C2Cl3)(2)Hg (4,4'-bipyridyl)] (1) shows that only one nitrogen is weakly coordinated to mercury so that C-Hg-C is approximately linear in the monomeric structure but there are four intramolecular chlorines closer to mercury than the sum of the van der Waals radii. The C-Hg-S angle in [C2Cl3Hg(2-pyridyl thiolate)] (12) is only slightly distorted from linearity due to secondary bonding to nitrogen. There are two weak intramolecular contacts between mercury and chlorine and two intermolecular mercury-sulfur contacts to form pairs of molecules which form double chains along the b axis. [HgBr2(2,2'-dipyridyl disulfide)] (10) is polymeric and contains four-coordinate mercury with the ligand bridging between mercury atoms via coordination to nitrogen. (C) 2000 Elsevier Science B.V. All rights reserved.
• A 199Hg NMR study of redistribution reactions involving bis(trichloroethenyl)mercury
  作者：Paul Peringer、Peter-Paul Winkler

  DOI：10.1016/s0020-1693(00)88606-5

  日期：1981.1
• GB427979
  申请人：——

  公开号：——

  公开（公告）日：——
• CROSS, R. J.;GEMMILL, J., J. CHEM. RES. MICROFICHE, 1984, N 2, 30-31
  作者：CROSS, R. J.、GEMMILL, J.

  DOI：——

  日期：——