Sodium bis(2,6-dimethoxybenzoyl)phosphide | 1253120-31-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Sodium bis(2,6-dimethoxybenzoyl)phosphide
• 英文别名: Sodium;bis(2,6-dimethoxybenzoyl)phosphanide；sodium;bis(2,6-dimethoxybenzoyl)phosphanide
• CAS: 1253120-31-8
• 化学式: C₁₈H₁₈O₆P*Na
• 分子量: 384.301
• InChiKey: RCSFVTHOPUKCQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.65
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  Sodium bis(2,6-dimethoxybenzoyl)phosphide 、 3-溴丙胺氢溴酸盐 在 双氧水 作用下， 以 乙二醇二甲醚 、 乙醚 、 乙醇 为溶剂， 生成 (3-aminopropyl)-bis(2,6-dimethoxy-benzoyl)-phosphine oxide
  参考文献：
  名称：

  POLYMER-BOUND BISACYLPHOSPHINE OXIDES

  摘要：

  该发明涉及一种寡聚体或聚合物，其通过一个或多个双酰基膦氧基团取代，其特征在于所述的双酰基膦氧基团通过磷原子连接到寡聚体或聚合物骨架，可选地通过一个间隔基团连接；以及特定功能化的双酰基膦氧化物，适用于制备所述的聚合物或寡聚体。

  公开号：

  US20120142805A1
• 作为产物：
  描述：

  2,6-二甲氧基苯甲酰氯 以87%的产率得到Sodium bis(2,6-dimethoxybenzoyl)phosphide
  参考文献：
  名称：

  POLYMER NANOPARTICLES

  摘要：

  通过光诱导乳液聚合制备聚合物纳米粒子的方法包括制备乳液，该乳液包括至少一种表面活性剂、分散相和连续相。分散相包括至少一种可聚合单体，连续相包括水和至少一种光引发剂。至少一种可聚合单体通过将乳液暴露于具有波长的电磁辐射而聚合，以诱导至少一种光引发剂产生自由基。至少一种光引发剂从公式（I）中的至少一种化合物中选择。

  公开号：

  US20120115963A1

文献信息

• Polymer nanoparticles
  申请人：ETH ZUERICH

  公开号：US10023675B2

  公开（公告）日：2018-07-17

  A process for the preparation of a polymer nanoparticle by a photoinduced emulsion polymerization includes preparing an emulsion comprising at least one surfactant, a dispersed phase and a continuous phase. The dispersed phase comprises at least one polymerizable monomer and the continuous phase comprises water and at least one photoinitiator. The at least one polymerizable monomer is polymerized by exposing the emulsion to an electromagnetic radiation having a wavelength so as to induce a generation of radicals from the at least one photoinitiator. The at least one photoinitiator is selected from at least one compound of formula (I)

  通过光诱导乳液聚合法制备聚合物纳米粒子的工艺包括制备包含至少一种表面活性剂、分散相和连续相的乳液。分散相包括至少一种可聚合单体，连续相包括水和至少一种光引发剂。至少一种可聚合单体是通过将乳液暴露在电磁辐射下而聚合的，电磁辐射的波长可诱导至少一种光引发剂产生自由基。至少一种光引发剂选自至少一种式 (I) 的化合物
• BISACYLPHOSPHANES AND THEIR USE AS PHOTOINITIATORS; PROCESS FOR PREPARING ACYLPHOSPHANES
  申请人：BASF SE

  公开号：EP1814891B1

  公开（公告）日：2011-01-26
• Process for Preparing Acylphosphanes and Derivatives Thereof
  申请人：Murer Peter

  公开号：US20080004464A1

  公开（公告）日：2008-01-03

  The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C 1 -C 18 alkyl or C 2 -C 18 alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 2 -C 18 alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R 1 ; the process comprises the steps a) contacting e.g. elemental phosphorous [P]∞, P(Hal) 3 with a reducing metal optionally in the presence of a catalyst or an activator in a solvent to obtain metal phosphides Me 3 P or Me′ 3 P 2 , wherein Me is an alkali metal and Me′ is an earth alkali metal or to obtain metal polyphosphides b) optionally adding a proton source, optionally in the presence of a catalyst or an activator to obtain metal dihydrogen phosphides MePH 2 ; c) subsequent acylation reaction with m acid halides of formula III or m carboxylic acid esters of formula IV or, in case that in formula I m=1, with one carboxylic ester of formula IV followed by one acid halide of formula III or vice versa, wherein R is the residue of an alcohol and R 2 is as defined above; d) alkylation reaction subsequent reaction with an electrophilic agent R 1 Hal or other electrophilic agents to obtain the compounds of formula I. An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides, which are used as photoinitiators.
• US7687657B2
  申请人：——

  公开号：US7687657B2

  公开（公告）日：2010-03-30
• US8883872B2
  申请人：——

  公开号：US8883872B2

  公开（公告）日：2014-11-11