1,3-bis(3-methyl-4-hydroxyphenyl)adamantane | 582311-10-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,3-bis(3-methyl-4-hydroxyphenyl)adamantane
• 英文别名: 1,3-bis(4-hydroxy-3-methylphenyl)adamantane；4-[3-(4-hydroxy-3-methylphenyl)-1-adamantyl]-2-methylphenol
• CAS: 582311-10-2
• 化学式: C₂₄H₂₈O₂
• 分子量: 348.485
• InChiKey: QFEOUZVEDVLPTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-bis(3-methyl-4-hydroxyphenyl)adamantane 、 乌洛托品 在 三氟乙酸 作用下， 反应 26.0h， 生成 1,3-bis(3-formyl-5-methyl-4-hydroxyphenyl)adamantane
  参考文献：
  名称：

  1,3-Bis(3-Formyl-4-Hydroxyphenyl)Adamantanes and Polynuclear Polyphenols Derived Therefrom

  摘要：

  一种新的1,3-双(3-甲醛基-4-羟基苯基)金刚烷，可作为金刚烷双酚衍生物的中间体材料或用于光敏感抗蚀材料、环氧树脂和其他合成树脂、热敏感记录材料等，具有优异的性能，如耐热性和机械强度。可以通过一个工业过程轻松获得这种材料，产率高，纯度高，方法是通过将1,3-双(4-羟基苯基)金刚烷与六亚甲基四胺或其他物质在酸的存在下发生反应，然后用酸水解得到的席夫碱。同时还提供了一种可能源自相同材料的新的多核多酚。

  公开号：

  US20080242896A1
• 作为产物：
  描述：

  1,3-金刚烷二醇 、 邻甲酚 在 sodium hydroxide 、 磷酸 、 对甲苯磺酸一水合物 作用下， 以 氮气 、 水 、 甲苯 为溶剂， 生成 1,3-bis(3-methyl-4-hydroxyphenyl)adamantane
  参考文献：
  名称：

  Hydroxyphenyl adamantanes and process for the production of the same

  摘要：

  羟基苯基重氮烷类化合物由通式（1）表示： 1 其中R为烷基、环烷基或苯基；m为0或整数1或2；l为0或1；当l为1时，取代羟基苯基的1和3位的羟基在对位上共同存在；n为0或整数1、2或3；当l为0时，n为整数1、2或3。

  公开号：

  US20030187307A1

文献信息

• METHOD FOR PRODUCING BISCHLOROFORMATE COMPOUND, POLYCARBONATE OLIGOMER HAVING SMALL NUMBER OF MONOMERS AND SOLUTION CONTAINING BISCHLOROFMATE COMPOUND
  申请人：Hikosaka Takaaki

  公开号：US20120101292A1

  公开（公告）日：2012-04-26

  A dihydric phenol compound represented by the following formula (2), a phosgene compound, and an aliphatic tertiary amine are mixed together using a hydrophobic organic solvent to produce bischloroformate that is represented by the following formula (1) and has an average number of repeating units (n) of 1.99 or less. In the formulae (1) and (2), Ar is a divalent aromatic group.

  使用疏水性有机溶剂混合以下化学式（2）表示的二元酚化合物、光气化合物和脂肪族三级胺，以产生以下化学式（1）表示的双氯甲酸酯，其平均重复单元数（n）为1.99或更少。在化学式（1）和（2）中，Ar是二价芳香族基。
• ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1985617A1

  公开（公告）日：2008-10-29

  To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions. An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Yrepresentsagrouprepresented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16-m) and p and q are each an integer of 1 to 5.

  为提供一种金刚烷衍生物、一种具有金刚烷骨架的化合物、含有它们的组合物，可提供具有优异光学性能（如透明度和耐光性）、长期耐热性和电特性（如介电常数）的固化产品以及使用这些组合物的光电子元件。该金刚烷衍生物由通式（I）表示，具有金刚烷骨架的化合物由通式（VII）或（VIII）表示，含有它们的组合物以及使用树脂组合物的光电子元件。在公式中，W代表氢原子，X代表由通式（II）表示的基团，Y代表由公式（V）或（VI）表示的基团，R1代表甲基基团或乙基基团，R2代表含有O或S的C1至C10烃基团，m为2至4的整数，k为0至（16-m）的整数，p和q均为1至5的整数。
• 1,3-BIS(HYDROXYPHENYL)-5-ETHYLADAMANTANE COMPOUND AND METHOD FOR PRODUCTION THEREOF, AND AROMATIC POLYCARBONATE RESIN AND METHOD FOR PRODUCTION THEREOF
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160244389A1

  公开（公告）日：2016-08-25

  The present invention can provide a 1,3-bis(hydroxyphenyl)-5-ethyladamantane compound represented by Formula (1) below and a method for producing the same, as well as an aromatic polycarbonate resin comprising said compound and a method for producing the same. (wherein, R represents an alkyl group with a carbon number of 1-6, a cycloalkyl group with a carbon number of 3-6, or a phenyl group, and n represents an integer of 0-2).

  本发明提供了一种由下式（1）表示的1,3-双（羟基苯基）-5-乙基金刚烷化合物及其制备方法，以及包含所述化合物的芳香族聚碳酸酯树脂及其制备方法。（其中，R代表碳数为1-6的烷基，碳数为3-6的环烷基或苯基，n代表0-2的整数）。
• Adamantane derivative, composition comprising the derivative, and optical and electronic member using the composition
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US07960483B2

  公开（公告）日：2011-06-14

  An adamantane derivative of formula (I), a compound of formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X is bonded to a bridge-head adamantane carbon and represents, for example, a group of represented by the general formula (II), Y represents a group of formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16−m) and p and q are each an integer of 1 to 5.

  公式（I）的一种金刚烷衍生物，公式（VII）或（VIII）的化合物，包含它们的组合物，以及使用树脂组合物的光电元件。在公式中，W代表例如氢原子，X与桥头金刚烷碳键合，并代表例如由通式（II）表示的基团，Y代表公式（V）或（VI）的基团，R1代表甲基基团或乙基基团，R2代表可能含有O或S的C1至C10烃基团，m为2至4的整数，k为0至（16-m）的整数，p和q分别为1至5的整数。
• POLYCARBONATE POLYMER, COATING LIQUID, AND ELECTROPHOTOGRAPHIC PHOTOSENSITIVE BODY
  申请人：Hikosaka Takaaki

  公开号：US20100233603A1

  公开（公告）日：2010-09-16

  A polycarbonate polymer includes: a monomer unit represented by a formula (1A) below; and a monomer unit represented by a formula (2). A haze of a solution that is obtained by dissolving the polycarbonate polymer in THF (tetrahydrofuran) at a concentration of 10 mass % is 5% or less (according to JIS K7105, optical path length of 10 mm). In the formula (1A), R and R′ each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 12 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms; n1 is an integer in a range of 2 to 4; and n2 is an integer in a range of 25 to 220; and in the formula (2), Ar represents a divalent aromatic group.

  一种聚碳酸酯聚合物包括：由以下式（1A）表示的单体单位；和由式（2）表示的单体单位。将聚碳酸酯聚合物以10质量％的浓度在THF（四氢呋喃）中溶解得到的溶液的浑浊度小于或等于5％（根据JIS K7105，光程为10毫米）。在式（1A）中，R和R'各自独立表示氢原子，卤素原子，具有1到12个碳原子的烷基或具有6到12个碳原子的取代或未取代芳基基团；n1是2到4之间的整数；n2是25到220之间的整数；在式（2）中，Ar表示二价芳香基团。