N-[4-[[4-(benzhydrylideneamino)phenyl]methyl]phenyl]-1,1-diphenylmethanimine | 1027164-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-[[4-(benzhydrylideneamino)phenyl]methyl]phenyl]-1,1-diphenylmethanimine
• CAS: 1027164-62-0
• 化学式: C₃₉H₃₀N₂
• 分子量: 526.681
• InChiKey: KPLHPTZESDMGTD-UHFFFAOYSA-N

物化性质

• 沸点：
  655.1±55.0 °C(Predicted)
• 密度：
  1.05±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  41
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-[4-[[4-(benzhydrylideneamino)phenyl]methyl]phenyl]-1,1-diphenylmethanimine 在 potassium permanganate 、 四丁基溴化铵 作用下， 以 苯 为溶剂， 反应 32.0h， 以85%的产率得到DPA dendron G2
  参考文献：
  名称：

  Efficient Synthesis of Poly(phenylazomethine) Dendrons Allowing Access to Higher Generation Dendrimers

  摘要：

  We have developed a novel synthetic method of phenylazomethine dendrons that uses 4,4'-methylenedianiline instead of 4,4'-diaminobenzophenone to synthesize the precursor of the phenylazomethine dendron and then oxidized the precursor to the next-generation dendron. For this method, the productivity of the dendrons has been significantly increased. Furthermore, as the synthesis of high-generation dendrons becomes easier, synthesis of DPA G5 was achieved.

  DOI：

  10.1021/ol049656d
• 作为产物：
  描述：

  二苯甲酮 、 4,4'-二氨基二苯甲烷 在 三乙烯二胺 、 四氯化钛 作用下， 以 氯苯 为溶剂， 反应 24.0h， 以85%的产率得到N-[4-[[4-(benzhydrylideneamino)phenyl]methyl]phenyl]-1,1-diphenylmethanimine
  参考文献：
  名称：

  Efficient Synthesis of Poly(phenylazomethine) Dendrons Allowing Access to Higher Generation Dendrimers

  摘要：

  We have developed a novel synthetic method of phenylazomethine dendrons that uses 4,4'-methylenedianiline instead of 4,4'-diaminobenzophenone to synthesize the precursor of the phenylazomethine dendron and then oxidized the precursor to the next-generation dendron. For this method, the productivity of the dendrons has been significantly increased. Furthermore, as the synthesis of high-generation dendrons becomes easier, synthesis of DPA G5 was achieved.

  DOI：

  10.1021/ol049656d

文献信息

• Efficient Synthesis of Poly(phenylazomethine) Dendrons Allowing Access to Higher Generation Dendrimers
  作者：Kensaku Takanashi、Hiroshi Chiba、Masayoshi Higuchi、Kimihisa Yamamoto

  DOI：10.1021/ol049656d

  日期：2004.5.1

  We have developed a novel synthetic method of phenylazomethine dendrons that uses 4,4'-methylenedianiline instead of 4,4'-diaminobenzophenone to synthesize the precursor of the phenylazomethine dendron and then oxidized the precursor to the next-generation dendron. For this method, the productivity of the dendrons has been significantly increased. Furthermore, as the synthesis of high-generation dendrons becomes easier, synthesis of DPA G5 was achieved.