methyl [(6-formyl-3-pyridinyl)oxy]acetate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: methyl [(6-formyl-3-pyridinyl)oxy]acetate
• 英文别名: Methyl 2-(6-formylpyridin-3-yl)oxyacetate
• 化学式: C₉H₉NO₄
• 分子量: 195.175
• InChiKey: BDZYHKACCPSHOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  65.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  methyl [(6-formyl-3-pyridinyl)oxy]acetate 生成 2-[(5Z)-5-[[5-(2-methoxy-2-oxoethoxy)pyridin-2-yl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid
  参考文献：
  名称：

  MIDZUTA, MURATA IURATA MAKOTO;NARUTO, SYUNSUKEH;FUDZIYA, TAKEHKADZU;KADOG+

  摘要：

  DOI：
• 作为产物：
  描述：

  5-羟基-2-吡啶甲醇 在 manganese(IV) oxide 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 异丙醇 为溶剂， 反应 26.0h， 生成 methyl [(6-formyl-3-pyridinyl)oxy]acetate
  参考文献：
  名称：

  Electronic absorption and emission properties of bishydrazone [2 × 2] metallosupramolecular grid-type architectures

  摘要：

  Several ditopic ligands containing two tridentate bishydrazone coordination subunits and their Zn(II) and Cd(II) [2 x 2] grid-type complexes were prepared and their photoluminescent properties studied. A special attention was devoted to the influence of the orientation of the hydrazone group N-N=in the core of the ligands and their complexes. Its reversal from [pyridine=N-N-pyrimidine] (L1) to [pyridinee-N-N=pyrimidine] (L2) has a strong impact on the observed absorption and emission behaviour of particular ligands (L1 and L2) as well as of their [2 x 2] grid assemblies. The further lateral functionalization of the ligands led to different emission quantum yields of the resulting grids, while their emission and absorption spectra varied very little. The simplest derivative L1 turned out to have the best performance with, for its Zn(II) complex, relatively high quantum yield 60%.

  DOI：

  10.1016/j.ica.2019.05.017

文献信息

• MIDZUTA, MURATA IURATA MAKOTO;NARUTO, SYUNSUKEH;FUDZIYA, TAKEHKADZU;KADOG+
  作者：MIDZUTA, MURATA IURATA MAKOTO、NARUTO, SYUNSUKEH、FUDZIYA, TAKEHKADZU、KADOG+

  DOI：——

  日期：——
• Electronic absorption and emission properties of bishydrazone [2 × 2] metallosupramolecular grid-type architectures
  作者：Jan Holub、Antonio Santoro、Jean-Marie Lehn

  DOI：10.1016/j.ica.2019.05.017

  日期：2019.8

  Several ditopic ligands containing two tridentate bishydrazone coordination subunits and their Zn(II) and Cd(II) [2 x 2] grid-type complexes were prepared and their photoluminescent properties studied. A special attention was devoted to the influence of the orientation of the hydrazone group N-N=in the core of the ligands and their complexes. Its reversal from [pyridine=N-N-pyrimidine] (L1) to [pyridinee-N-N=pyrimidine] (L2) has a strong impact on the observed absorption and emission behaviour of particular ligands (L1 and L2) as well as of their [2 x 2] grid assemblies. The further lateral functionalization of the ligands led to different emission quantum yields of the resulting grids, while their emission and absorption spectra varied very little. The simplest derivative L1 turned out to have the best performance with, for its Zn(II) complex, relatively high quantum yield 60%.