(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C5H11) | 183063-41-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C5H11)
• 英文别名: (tetratolylporphyrinato dianion)Ru(NO)(O-i-C5H11)；(TTP)Ru(NO)(i-O-C5H11)
• CAS: 183063-41-4
• 化学式: C₅₃H₄₇N₅O₂Ru
• 分子量: 887.058
• InChiKey: OTOVZRZZBAABAU-KDTBAHQYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C5H11) 、 三氯化硼 以 二氯甲烷 为溶剂， 生成 chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
  参考文献：
  名称：

  Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)

  摘要：

  A new high-yield preparative route to (por)Ru(NO)Cl compounds (por=porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the Ru-N-O linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.031
• 作为产物：
  描述：

  carbonyl(meso-tetrakis(4-tolyl)porphyrinato)ruthenium(II) 、 亚硝酸异戊酯 以 二氯甲烷 为溶剂， 以58%的产率得到(5,10,15,20-tetra-p-tolylporphyrinato)Ru(NO)(O-i-C5H11)
  参考文献：
  名称：

  Activation of Thionitrites and Isoamyl Nitrite by Group 8 Metalloporphyrins and the Subsequent Generation of Nitrosyl Thiolates and Alkoxides of Ruthenium and Osmium Porphyrins

  摘要：

  Ruthenium and osmium porphyrins of the form (por)M(CO) (per = octaelhylporphyrinato diction (OEP), tetratolylporphyrinato dianion (TTP)) react with thionitrites (RSNO) and isoamyl nitrite (RONO) to give the (por)(NO)(SR) and (por)M(NO)(OR) addition products. Reaction of S-nitroso-N-acetyl-L-cysteine methyl ester with (TPP)Fe(THF)(2) (TPP tetraphenylporphyrinato dianion) gives (TPP)Fe(NO) in high yield. The related reaction of isoamyl nitrite with [(TPP)Fe(THF)(2)](+) gives the nitrosyl alcohol product [(TPP)Fe(NO)(HO-i-C5H11)](+). The solid stare structures of (OEP)Ru(NO)(NACysMe-S) (NACysMe = N-acetyl-L-cysteinate methyl ester), (TTP)Os(NO)(S-i-C5H11), and [(TPP)Fe(NO)(HO-i-C5H11)](+) have been determined by X-ray diffraction.

  DOI：

  10.1021/ic970282c