chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) | 179930-28-0

• 英文名称: chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
• 英文别名: chloro(nitrosyl)((tetra-meso-p-tolyl)porphyrinato)ruthenium(II)；Ru(5,10,15,20-tetra(p-tolyl)porphyrinate)(NO)Cl；(tetratolylporphyrinato dianion)Ru(NO)Cl；(TTP)Ru(NO)Cl
• CAS: 179930-28-0
• 化学式: C₄₈H₃₆ClN₅ORu
• 分子量: 835.37
• InChiKey: ZZUZFZNNJATZIR-KDTBAHQYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) 以 四氢呋喃 为溶剂， 生成 (5,10,15,20-tetra-p-tolylporphyrinato)dimethylruthenium
  参考文献：
  名称：

  The first structurally characterized organometallic nitrosyl porphyrin: structure of [Ru(ttp)(NO)(C6H4F-p)](ttp =meso-tetratolylporphyrinato dianion)

  摘要：

  [Ru(ttp)(NO)Cl]与芳基或烷基格氏试剂反应生成[Ru(ttp)(NO)R](R = C6H4F-p, Me)；[Ru(ttp)(NO)Me]中的Ru–C键通过SO2进行插入反应，而[Ru(ttp)(NO)(C6H4F-p)]的结构通过X射线晶体学得以确定。

  DOI：

  10.1039/cc9960002283
• 作为产物：
  描述：

  (carbonyl-κC)(methanol-κO)(5,10,15,20-tetra-p-tolylporphyrinato-κ(4)N)ruthenium(II) 在 DBU 作用下， 以 二氯甲烷 为溶剂， 生成 chloride(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
  参考文献：
  名称：

  Synthesis and Axial Ligand Substitution Chemistry of Ru(TTP)(NO)X. Structures of Ru(TTP)(NO)X (X = ONO, OH)

  摘要：

  New complexes of the family Ru(TTP)(NO)X, where TTP = tetra-p-tolylporphyrinato dianion, and X = OMe, Cl, OH, SH, S-p-tolyl, O2CH, ONO, ONO2, N-3, or NCS, have been prepared by a variety of high-yield metathesis techniques from Ru(TTP)(CO)(MeOH). New complexes have been characterized by IR, NMR, and UV spectroscopies as well as by cyclic voltammetry, elemental analysis, and, in two cases, by X-ray crystallography. The two complexes which have been characterized by single-crystal X-ray diffraction, the hydroxide and nitrite complexes 6 and 10 both crystallize in the monoclinic space group P2(1)/n and have Z = 6, with two independent metalloporphyrins in the unit cell, one (ordered) lying on a general position and the other (disordered) with the ruthenium on an inversion center. Acid labilization of the methoxide results in facile substitution kinetics at room temperature and with the exception of the sulfhydryl complex, L = SH, the resulting complexes are air stable and thermally robust species. For example, the formate derivative cannot be decarboxylated thermally or photolytically to give a hydride complex, and the azido complex does not eliminate dinitrogen under similar conditions to give a nitrido complex.

  DOI：

  10.1021/ic980182m

文献信息

• Disproportionation reaction of NO2/N2O4 with a Ru(ii) porphyrin
  作者：Yanlong Kang、Grigory V. Zyryanov、Dmitry M. Rudkevich

  DOI：10.1039/b307959g

  日期：——

  A Ru(II) porphyrin rapidly reacts with NO2/N2O4 with the formation of a stable Ru(II) nitrosyl nitrato complex.

  一种 Ru（II）卟啉与 NO2/N2O4 快速反应，形成稳定的 Ru（II）亚硝基硝基络合物。
• Synthesis, structure and ligand exchange reactions of Ru(TTP)(NO)(OMe)
  作者：D. Scott Bohle、Patricia A. Goodson、Bryan D. Smith

  DOI：10.1016/0277-5387(96)00090-3

  日期：1996.6

  A facile, novel preparation of the useful synthon Ru(TTP)(NO)(OMe) is reported and it has been characterized by a range of techniques, including single crystal X-ray diffraction. Subsequent methoxide substitution reactions led to the preparation in high yield and purity of a wide variety of new complexes including a mercaptide complex which is the first reported analogue of the diamagnetic nitrosyl

  报道了一种有用的合成子Ru（TTP）（NO）（OMe）的简便，新颖的制备方法，并已通过包括单晶X射线衍射在内的多种技术进行了表征。随后的甲醇取代反应导致高产率和高纯度的各种新配合物的制备，包括硫醇配合物，该硫醇配合物是P-450单加氧酶的反磁性亚硝酰基加合物的第一个报道类似物。
• Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)
  作者：Nan Xu、Jonghyuk Lee、Douglas R. Powell、George B. Richter-Addo

  DOI：10.1016/j.ica.2004.06.031

  日期：2005.6

  A new high-yield preparative route to (por)Ru(NO)Cl compounds (por=porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the Ru-N-O linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered. (c) 2004 Elsevier B.V. All rights reserved.
• Synthesis and Characterization of Isostructural Metalloporphyrin Chalconitrosyl Complexes Ru(TTP)(NE)Cl (E = O, S) and a Remarkable Thionitrosyl/Nitrite → Nitrosyl/Thiazate Transformation
  作者：D. Scott Bohle、Chen-Hsiung Hung、Annie K. Powell、Bryan D. Smith、Sigrid Wocadlo

  DOI：10.1021/ic9614576

  日期：1997.5.1

  When Ru(TP)(NS)Cl is treated with silver nitrite, the product is not the expected halide metathesis product but a N-bound thiazate complex.
• Heterobimetallic nitrido-bridged Ru(II)NOs(VIII) and Ru(II)NOs(VI) complexes containing ruthenium porphyrins
  作者：Wa-Hung Leung、Joyce L.C. Chim、Willetta Lai、Leo Lam、Wing-Tak Wong、Wing Hang Chan、Chi-Hung Yeung

  DOI：10.1016/s0020-1693(99)00096-1

  日期：1999.6

  Treatment of Ru(por)(NO)(OTf) (por=dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin H-2(OEP) or 5,10,15,20-tetra(p-tolyl)porphyrin H-2(TTP), OTf=triflate) with [(NBu4)-Bu-n][OsO3N] afforded the nitrido-bridged Ru(II)-Os(VIII) complexes [(por)(NO)RuNOsO3] (por=OEP (3) or TTP (4)). The structure of 3 has been established by X-ray crystallography. The Ru-N(O), Ru-N(Os and Os-N distances in 3 are 1.83(2, 2.03(1) and 1.79(1) Angstrom, respectively; the Ru-N-O and Ru-N-Os angles are 153(1) and 138.4(8)degrees, respectively. Reaction of Ru(por)(NO)(OTf) with [(NBu4)-Bu-n]OsNL2] (H2L = 3,4-toluenedithiol) gave the nitrido-bridged Ru(II)-Os(VI) complexes (por)(NO)RuNOsL2 (por = OEP (5), TTP (6)). Treatment of Ru(OEP)(NO)(OTf) with ReN(Et(2)dtc)(2) (Et(2)dtc = N,N-diethyldithiocarbamate) afforded the Ru(IT)-Re(V) complex (OEP)(NO)RuNRe(Et(2)dtc)(2)(OTf) (7). Complexes 3 and 4 exhibit porphyrin-centered oxidation along with Os(VIII)-Os(VIT) and Ru(II)-Ru(I) reductions. Complexes 5 and 6 exhibit Os(VII)-Os(VI) and porphyrin ring oxidation along with Ru(II)-Ru(I) reduction. (C) 1999 Elsevier Science S.A. All rights reserved.