3-氯-丙酸丁酯 | 27387-79-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 3-氯-丙酸丁酯
• 英文名称: 3-chloro-propionic acid butyl ester
• 英文别名: 3-Chlor-propionsaeure-butylester；β-Chlor-propionsaeure-butylester；3-chloro-propanoic acid, butyl ester；butyl 3-chloropropionate；β-Chlorpropionsaeure-butylester；Butyl 3-chloropropanoate
• CAS: 27387-79-7
• 化学式: C₇H₁₃ClO₂
• 分子量: 164.632
• InChiKey: KRZKQEQBZXWCDJ-UHFFFAOYSA-N

物化性质

• 沸点：
  231.51°C (rough estimate)
• 密度：
  1.0370
• 保留指数：
  1083;1085;1086;1091;1092;1093;1097;1098;1094

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  3-氯-丙酸丁酯 在 sodium 作用下， 以 乙醚 为溶剂， 生成 α-Carbaethoxy-α-(β-carbbutoxy-aethyl)-β-methyllaevulinsaeure-aethylester
  参考文献：
  名称：

  Evstigneeva,R.P. et al., Journal of general chemistry of the USSR, 1961, vol. 31, # 2, p. 400 - 402

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烯酸丁酯 在 溶剂黄146 、 乙基二氯化磷 作用下， 生成 3-氯-丙酸丁酯
  参考文献：
  名称：

  Reaction of ethyldichloeophosphine with acrylic acid esters

  摘要：

  DOI：

  10.1007/bf00867241

文献信息

• Medical devices having conductive substrate and covalently bonded coating layer
  申请人：Richard E. Robert

  公开号：US20060013853A1

  公开（公告）日：2006-01-19

  The present invention provides a medical device comprising an electrically conductive substrate and a coating layer that covers at least a portion of the electrically conductive substrate, wherein the coating layer comprises a polymer that is made by a process that comprises (a) electrochemically linking a initiator to a surface of the electrically conductive substrate and (b) conducting a free radical polymerization reaction in the presence of one or more free radical polymerizable monomers.

  本发明提供了一种医疗设备，包括一个电导性基板和覆盖电导性基板至少部分的涂层层，其中涂层层包括通过以下过程制备的聚合物：(a) 电化学地将引发剂连接到电导性基板表面；(b) 在一个或多个自由基聚合单体的存在下进行自由基聚合反应。
• Polyhydroxyalkanoate having vinyl group, ester group, carboxyl group, and sulfonic group, and method of producing the same
  申请人：Kenmoku Takashi

  公开号：US20070073006A1

  公开（公告）日：2007-03-29

  To provide a novel polyhydroxyalkanoate having a reactive functional group in a molecule and a method of producing the same; and a novel polyhydroxyalkanoate having a new function obtained by chemically modifying the polyhydroxyalkanoate having a reactive functional group and a method of producing the same. By utilizing a vinyl group of a polyhydroxyalkanoate containing a unit having the vinyl group at a side chain thereof, a polyhydroxyalkanoate containing units having a carboxyl group, an amide group, and a sulfonic group in a molecule is induced.

  提供一种分子中具有反应性功能基团的新型聚羟基脂肪酸酯及其制备方法；以及通过化学修饰具有反应性功能基团的聚羟基脂肪酸酯获得的具有新功能的新型聚羟基脂肪酸酯及其制备方法。通过利用聚羟基脂肪酸酯中含有侧链上乙烯基的单元的乙烯基，诱导聚羟基脂肪酸酯中含有羧基、酰胺基和磺酸基的单元。
• Polyhydroxyalkanoic Acid Having Vinyl, Ester, Carboxyl or Sulfonic Acid Group and Producing Method Therefor
  申请人：Kenmoku Takashi

  公开号：US20080064828A1

  公开（公告）日：2008-03-13

  The invention is to provide a novel polyhydroxyalkanoate having a reactive function group within the molecule and a producing method therefor In a polyhydroxyalkanoate containing a unit having a vinyl group in a side chain, such vinyl group is utilized for deriving a polyhydroxyalkanoate comprising a carboxyl group or a unit having an amide group and a sulfonic acid group.

  本发明旨在提供一种新型聚羟基烷酸酯，其分子内具有反应性功能团，并提供其制备方法。在含有侧链中具有乙烯基团的聚羟基烷酸酯中，利用该乙烯基团来获得含有羧基或含有酰胺基和磺酸基的聚羟基烷酸酯。
• Charge control agent, toner, image forming method, and image forming apparatus
  申请人：Yano Tetsuya

  公开号：US20090202927A1

  公开（公告）日：2009-08-13

  To provide: a charge control agent having negative chargeability, which contributes to environmental conservation and the like to an increased degree, has high performance (high charge amount, quick rise-up of charge, excellent stability with time, and high environmental stability), and has improved dispersibility; a toner for developing an electrostatic charge image containing the charge control agent; and an image forming method and an image forming apparatus each using the toner for developing an electrostatic charge image. A charge control agent for controlling a charged state of powder, characterized by including one or more units each represented by the following chemical formula (1) in a molecule.

  提供：一种具有负电荷性能的充电控制剂，可更有效地促进环境保护等，具有高性能（高电荷量，快速电荷上升，优异的时间稳定性和高环境稳定性），并具有改善的分散性；一种包含充电控制剂的用于开发静电充电图像的色调剂；以及使用用于开发静电充电图像的色调剂的图像形成方法和图像形成设备。一种用于控制粉末的带电状态的充电控制剂，其特征在于分子中包含由以下化学式（1）表示的一个或多个单元。
• PROCESS FOR THE PREPARATION OF 1-ALKOXY-1-TRIMETHYLSILYLOXYCYCLOPROPANES
  申请人：IHARA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0900803A1

  公开（公告）日：1999-03-10

  The present invention provides a process for producing 1-alkoxy-1-trimethylsilyloxycyclopropane represented by the following general formula: by reacting microgranular metallic sodium dispersed in a hydrocarbon solvent, β-halogenocarboxylic acid ester represented by the following general formula: and chlorotrimethylsilane. According to the present invention, by using no ether compound solvent (the ether compound solvent has various problems in safety) and using microgranular metallic sodium dispersed in a hydrocarbon solvent, 1-alkoxy-1-trimethylsilyloxycyclopropane can be industrially produced simply (no special apparatus is required) at an advantageous cost at a yield at least equal to that obtained when an ether is used as solvent.

  本发明提供了一种生产通式如下的 1-烷氧基-1-三甲基硅氧基环丙烷的工艺： 将分散在烃类溶剂中的微颗粒金属钠、通式如下的 β-卤代羧酸酯和三甲基氯硅烷反应： 和氯三甲基硅烷。 根据本发明，通过不使用醚类化合物溶剂（醚类化合物溶剂在安全性方面存在各种问题）和使用分散在烃类溶剂中的微颗粒金属钠，可以简单地工业化生产 1-烷氧基-1-三甲基硅氧基环丙烷（不需要特殊装置），且成本低廉，产率至少与使用醚类溶剂时的产率相当。

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