[(pyridine)bis(diethyldithiocarbamato)zinc(II)]*pyridine | 872467-60-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [(pyridine)bis(diethyldithiocarbamato)zinc(II)]*pyridine
• CAS: 872467-60-2；215436-82-1
• 化学式: C₅H₅N*C₁₅H₂₅N₃S₄Zn
• 分子量: 520.139
• InChiKey: CBWKYHQTGUIAMC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(pyridine)bis(diethyldithiocarbamato)zinc(II)]*pyridine 以 neat (no solvent) 为溶剂， 生成 [(pyridine)bis(diethyldithiocarbamato)zinc(II)]
  参考文献：
  名称：

  Isomorphism of bis(diethyldithiocarbamato)zinc(II) adduct with pyridine, [Zn(Py)(EDtc)2]: hysteresis in the reaction of the adduct formation

  摘要：

  The structure of the polycrystalline adduct bis(diethyldithiocarbamato)-pyridine zinc(II) depends on the pathway of physicochemical conditions during the preparation procedure, as was revealed by solid state N-15 CP/MAS spectroscopy in good correlation with known single crystal X-ray diffraction structures of this adduct. Two isomorphs of the adduct, namely alpha-[Zn(Py)(S2CNEt2)(2)] and beta-[Zn(Py)(S2CNEt2)(2)], are the two molecules in the asymmetric unit of a single crystal (or polycrystalline) sample that can be obtained by recrystallization from toluene of the equimolar solution of the initial diethyldithiocarbamate zinc(II) complex and pyridine. The third isomorph, gamma-[Zn(Py)(S2CNEt2)(2)], can be obtained by recrystallization from pure pyridine of the diethyldithiocarbamate zinc(II) complex, or by its equimolar absorption of pyridine, or by desorption of pyridine from the clathrated adduct, [Zn(Py)(S2CNEt2)(2)]Py-.. Finally, the gamma-[Zn(Py)(S2CNEt2)(2)] isomorph recrystallizes from the melt into alpha/beta-isomorphs of the adduct. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)01274-3
• 作为产物：
  描述：

  吡啶 以 甲醇 为溶剂， 生成 [(pyridine)bis(diethyldithiocarbamato)zinc(II)]*pyridine
  参考文献：
  名称：

  Synthesis, Characterization and Thermal Studies of Bipyridine Metal Complexes Containing Different Substituted Dithiocarbamates

  摘要：

  Complexes of the type [Mpy(2)(dedtc)(2)], and [Mpy(2)(dpdtc)(2)], where M = Mn(II), Fe(II), Co(II), Ni( II), Cu(II), Zn(II), py = pyridine, dedtc = diethyldithiocarbamate and dpdtc = diphenyl-dithiocarbamate, have been synthesized and characterized by elemental analyses, magnetic susceptibility, TGA/DSC and IR in the solid-state, and electronic spectroscopy and conductivity measurement studies in solution. The dithiocarbamato moiety has been found to be symmetrically bonded to the metal. The complexes are proposed to have a distorted-octahedral structure. The ligand field parameters 10 Dq, B and beta have also been evaluated. The value of b indicates a considerable orbital overlap in the complexes. A two-stage decomposition pattern leading to the formation of respective metal sulfide as the end-product has been observed in all the complexes. Their molar conductance indicated them to be non-electrolyte in nitrobenzene.

  DOI：

  10.1081/sim-200066980