trans-Perfluoro-1-tert-butyl-4-methyl-1,3-pentadiene | 133586-52-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: trans-Perfluoro-1-tert-butyl-4-methyl-1,3-pentadiene
• 英文别名: (4E)-1,1,1,3,4,5,7,7,7-nonafluoro-2,6,6-tris(trifluoromethyl)hepta-2,4-diene
• CAS: 133586-52-4
• 化学式: C₁₀F₁₈
• 分子量: 462.081
• InChiKey: IBYUYFSEMYHGEP-DUXPYHPUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.16
• 重原子数：
  28.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  全氟异丁烯 、 三甲基(1,2,2-三氟乙烯基)硅烷 在 cesium fluoride 作用下， 以 乙腈 为溶剂， 反应 4.0h， 生成 Perfluoro-1,1,3-trimethyl-3-sec-butyl-1,2-propadiene 、 trans-Perfluoro-1-tert-butyl-4-methyl-1,3-pentadiene
  参考文献：
  名称：

  Transfer of an organofluorine fragment from CF2=CFSi(CH3)3 and CFCl2Si(CH3)3 to unsaturated perfluorinated compounds catalyzed by cesium fluoride

  摘要：

  A study was carried out on the reaction of 1,1,2-trifluorovinylsilane and fluorodichloromethylsilane in the presence of CsF with perfluoro-2-methyl-2-pentene, perfluoro-5-aza-4-nonene, and perfluoroisobutylene. These silanes are capable of transferring a fluorine-containing fragment to unsaturated organofluorine compounds.

  DOI：

  10.1007/bf01184539

文献信息

• PETROV, V. A.;SHEVCHENKO, N. V.;GRINEVSKAYA, V. K.;PARNES, Z. N.;BARDIN, +, IZV. AN CCCP. CEP. XIM.,(1990) N2, S. 2826-2831
  作者：PETROV, V. A.、SHEVCHENKO, N. V.、GRINEVSKAYA, V. K.、PARNES, Z. N.、BARDIN, +

  DOI：——

  日期：——
• Transfer of an organofluorine fragment from CF2=CFSi(CH3)3 and CFCl2Si(CH3)3 to unsaturated perfluorinated compounds catalyzed by cesium fluoride
  作者：V. A. Petrov、N. V. Shevchenko、V. K. Grinevskaya、Z. N. Parnes、V. V. Bardin、G. G. Furin、L. S. German、M. E. Vol'pin

  DOI：10.1007/bf01184539

  日期：1990.12

  A study was carried out on the reaction of 1,1,2-trifluorovinylsilane and fluorodichloromethylsilane in the presence of CsF with perfluoro-2-methyl-2-pentene, perfluoro-5-aza-4-nonene, and perfluoroisobutylene. These silanes are capable of transferring a fluorine-containing fragment to unsaturated organofluorine compounds.