吩恶噻 10,10-二氧化物 | 950-47-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 中文名称: 吩恶噻 10,10-二氧化物
• 中文别名: 吩恶噻10,10-二氧化物
• 英文名称: phenoxathiin S,S-dioxide
• 英文别名: phenoxathiin 10,10-dioxide；Phenoxathiin, 10,10-dioxide；phenoxathiine 10,10-dioxide
• CAS: 950-47-0
• 化学式: C₁₂H₈O₃S
• 分子量: 232.26
• InChiKey: XJLRCPYQIPAQCA-UHFFFAOYSA-N

物化性质

• 熔点：
  144 °C
• 沸点：
  413.4±15.0 °C(Predicted)
• 密度：
  1.418±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  吩恶噻 10,10-二氧化物 在 palladium dihydroxide 正丁基锂 、 高氯酸 、 氢气 、 溶剂黄146 作用下， 反应 0.75h， 生成 1-乙基吩恶噻10,10-二氧化物
  参考文献：
  名称：

  Selective Inhibitors of Monoamine Oxidase (MAO). 5. 1-Substituted Phenoxathiin Inhibitors Containing No Nitrogen That Inhibit MAO A by Binding It to a Hydrophobic Site

  摘要：

  It is believed that a monoamine oxidase (MAO) inhibitor specific for MAO A, which is reversibly bound to this enzyme and displaceable:by tyramine, will be an antidepressant which will not cause a rise in blood pressure when tyramine-containing foods are ingested. Some linear tricyclic compounds with a larger and a smaller group forming the central ring and with a lipophilic group ortho to the larger group (here mostly the SO2 function of phenoxathiin 10, -10-dioxide) are reported to have the sought properties. Potency appears to require short length and relatively small cross section for the substituent. The 1-ethyl (13), 1-vinyl (22), 1-trifluoromethyl (27), and 1-iodo (76) phenoxathiin dioxides had the best profiles. Structure-activity relationships, syntheses, and a possible rationale for the selectivity of these compounds and related tricyclics are given. Compound 13 was selected for further development. A summary of pharmacological data for 13 is given.

  DOI：

  10.1021/jm970862j
• 作为产物：
  描述：

  phenoxatellurine 在 铬酸 、 sulfur 作用下， 生成 吩恶噻 10,10-二氧化物
  参考文献：
  名称：

  Drew, Journal of the Chemical Society, 1928, p. 512,519, 521

  摘要：

  DOI：

文献信息

• Tetradentate platinum and palladium complex emitters containing phenyl-pyrazole and its analogues
  申请人：ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

  公开号：US10020455B2

  公开（公告）日：2018-07-10

  A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula 1 or Formula II, where M is platinum or palladium.

  根据您的要求，翻译结果如下： 一个磷光发射器或延迟荧光和磷光发射器，由公式1或公式II表示，其中M是铂或钯。
• Tetradentate Platinum And Palladium Complex Emitters Containing Phenyl-Pyrazole And Its Analogues
  申请人：Li Jian

  公开号：US20150194616A1

  公开（公告）日：2015-07-09

  A phosphorescent emitter or delayed fluorescent and phosphorescent emitters represented by Formula 1 or Formula II, where M is platiunum or palladium.

  一个磷光发射器或延迟荧光和磷光发射器，由公式1或公式II表示，其中M是铂或钯。
• ORGANIC MIXTURE AND APPLICATION THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200317646A1

  公开（公告）日：2020-10-08

  The present invention relates to an organic mixture and an application thereof in organic electronic devices. The organic mixture comprises a spirofluorene organic compound containing a fused heterocyclic ring and an aromatic fused heterocyclic organic compound containing an electron-donating group. A combination of the two materials may be used as a host material of a phosphorescent organic light-emitting diode (OLED), which may use the energy of excitons and balance the charge transport to the greatest extent and which may effectively reduce the concentration of excitons and the operating voltage of a corresponding device, thereby effectively improving the efficiency and service life of the related electronic device in order to provide an effective solution for improving the overall performance of an organic electronic device.

  本发明涉及一种有机混合物及其在有机电子器件中的应用。该有机混合物包括含有螺环异芳烃环的螺芴有机化合物和含有供电子给体基团的芳香融合杂环有机化合物。这两种材料的组合可用作磷光有机发光二极管（OLED）的主体材料，该二极管可以利用激子的能量并最大程度地平衡电荷传输，从而有效降低激子的浓度和相应器件的工作电压，从而有效提高相关电子器件的效率和使用寿命，为改善有机电子器件的整体性能提供有效解决方案。
• Green Oxidations. Manganese(II) Sulfate Aided Oxidations of Organic Compounds by Potassium Permanganate
  作者：Ahmad Shaabani、Abbas Rahmati、Masoumeh Sharifi、Jafar Mogimi Rad、Behnaz Aghaaliakbari、Elham Farhangi、Donald G. Lee

  DOI：10.1007/s00706-007-0667-5

  日期：2007.7

  The oxidation of arenes and sulfides by potassium permanganate was accomplished in good yields under solvent free and heterogeneous conditions when manganese(II) sulfate is used as a solid support. After extraction of the organic products, the inorganic products can be reoxidized to permanganate. This result is important because it provides an approach to oxidation reactions that is, in theory, infinitely

  当使用硫酸锰（II）作为固体载体时，在无溶剂和非均质条件下，高锰酸钾可以很好地完成芳烃和硫化物的氧化反应。提取有机产物后，可以将无机产物再氧化为高锰酸盐。该结果很重要，因为它提供了一种理论上无限可持续的氧化反应方法。
• Selectivity switch in the aerobic oxygenation of sulfides photocatalysed by visible-light-responsive decavanadate
  作者：Chifeng Li、Noritaka Mizuno、Kei Murata、Kazuyuki Ishii、Tomoyoshi Suenobu、Kazuya Yamaguchi、Kosuke Suzuki

  DOI：10.1039/d0gc01500h

  日期：——

  following mechanistic steps for this photocatalytic system: the aerobic oxygenation of sulfides to form the corresponding sulfoxides initiated by a visible-light-induced photoredox reaction of V10. As for the formation of sulfones, MEK-derived peroxide species as the co-catalysts are probably involved in the oxygenation of sulfoxides to sulfones. The selectivity switch of the V10-photocatalysed reaction

  纳米尺寸的金属氧化物是用于可见光响应的光催化剂发展的有前途的物种，该光催化剂用于有机官能团的选择性转化。在本文中，我们报告在使用O 2（1 atm）作为绿色氧化剂实现的硫化物的产品选择性氧化中，十钒酸盐（[V 10 O 28 ] 6−，V10）表现为一种有效的可见光响应型光催化剂。。特别是，我们发现V10的可见光响应光催化显示出显着的活性，可利用O 2氧化结构多样的硫化物以形成相应的砜在甲乙酮（MEK）中。此外，通过简单地将水添加到反应混合物中，硫化物氧化的产物选择性可以显着地转变为亚砜的产生，而不会伴随光催化活性的损失。基于实验证据，我们推断出该光催化系统的以下机械步骤：硫化物的需氧氧化形成相应的亚砜，该可见光由V10的可见光诱导的光氧化还原反应引发。至于砜的形成，MEK衍生的过氧化物作为助催化剂可能涉及将亚砜氧化成砜。V10的选择性开关加水引起的β-光催化反应最有可能通过抑制MEK衍生的过氧化物物质的形成而实现。