chlorine isocyanide | 75754-69-7

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: chlorine isocyanide
• 英文别名: chloroazaniumylidynemethane
• CAS: 75754-69-7
• 化学式: CClN
• 分子量: 61.4707
• InChiKey: VJONOHJOZKJOSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  氯化氰 以 gaseous matrix 为溶剂， 生成 dichlorocarbonitrile 、 carbon nitride 、 chlorine isocyanide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D3, 6.2.4.7.2, page 203 - 204

  摘要：

  DOI：

文献信息

• Spectroscopic Study of the Vacuum‐Ultraviolet Photolysis of Matrix‐Isolated HCN and Halogen Cyanides. Infrared Spectra of the Species CN and XNC
  作者：Dolphus E. Milligan、Marilyn E. Jacox

  DOI：10.1063/1.1711859

  日期：1967.7

  Vacuum-ultraviolet photolysis of HCN isolated in Ar and N2 matrices at 14°K is found to lead to the production of HNC in concentration sufficient for direct infrared observation of all three vibrational fundamentals. The spectrum of this species is found to be appreciably perturbed by the presence of N2. The force constants and thermodynamic properties of HNC have been revised to the values appropriate to this species in an environment free of perturbation by an adjacent N2 molecule. The free radical CN is also produced in these systems in concentration sufficient for direct observation not only of the B(2Σ+)—X(2Σ+) transition but also of the ground-state vibrational fundamental. Isotopic data supporting this identification are presented. Upon vacuum-ultraviolet photolysis of matrix-isolated FCN, two infrared absorptions appear which can be identified with the stretching fundamentals of the species FNC. In analogous experiments on the species ClCN and BrCN, infrared absorptions tentatively assigned to ClNC and BrNC have been observed.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D3, 6.2.4.7.2, page 203 - 204
  作者：

  DOI：——

  日期：——