8BuOCO caprylic acid | 4753-32-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 8BuOCO caprylic acid
• 英文别名: 9-butoxy-9-oxononanoic acid
• CAS: 4753-32-6
• 化学式: C₁₃H₂₄O₄
• 分子量: 244.331
• InChiKey: JWZCRVPRCUVVHF-UHFFFAOYSA-N

物化性质

• 沸点：
  164-167 °C(Press: 7 Torr)
• 密度：
  1.012±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  8BuOCO caprylic acid 在 吡啶 、 草酰氯 作用下， 反应 50.0h， 生成 1-O-butyl 9-O-[3,5-dimethoxy-2-[2-(4-methoxyphenyl)acetyl]phenyl] nonanedioate
  参考文献：
  名称：

  A Facile Synthesis of 2-Substituted Isoflavones for Immunoassay: Assembly of the Isoflavonoid Skeleton By Means of a Novel Cyclisation Reaction

  摘要：

  DOI：

  10.1055/s-1998-2221
• 作为产物：
  描述：

  壬二酸 、 正丁醇 生成 8BuOCO caprylic acid
  参考文献：
  名称：

  Freidlin,G.N. et al., Journal of Organic Chemistry USSR (English Translation), 1965, vol. 1, p. 1385 - 1387

  摘要：

  DOI：

文献信息

• Selective monoetherification and monoesterificatton of diols and diacids under phase-transfer conditions
  作者：Jaime de la Zerda、Gabriela Barak、Yoel Sasson

  DOI：10.1016/0040-4020(89)80151-6

  日期：1989.1

  Research on the selectivity of etherlfication reactions of diols and esterification reactions of diacids by alkyl halides under phase-transfer catalysis has shown that under such conditions, selectivity of monoetherification increases in the order prim < sec < tert diols, though overall yield of monoether decreases from sec to tert diols. Monoesterification of diacids was accomplished with a high degree

  对相转移催化二醇的醚化反应的选择性和烷基卤化物对二酸的酯化反应的选择性的研究表明，在这种条件下，尽管单醚的总收率从秒至叔二醇。二酸的单酯化以高度选择性完成。发现二醇和二酸的最佳提取通常对应于约5个碳的链长。这可能意味着由于其空间构象，通过内部溶剂化，在催化剂和要反应的阴离子之间形成的络合物对于某些碳长度是稳定的。
• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• Foamable thermoplastic composition containing volatile blowing agent and expandable microspheres
  申请人：Riken Technos Corporation

  公开号：EP1275688A1

  公开（公告）日：2003-01-15

  It is an object of the present invention to provide a foamable thermoplastic elastomer composition which gives the stable foam. The present invention provides a foamable thermoplastic elastomer composition which contains:(a) 10 to 90 parts by weight of one of an olefin-based resin and rubber having a melting or softening point of 140°C or lower,(b) 9 to 85 parts by weight of heat-expandable microcapsules expanding at 120 to 300°C,(c) 1 to 50 parts by weight of a volatile composition, wherein the components (a) to (c) total 100 parts by weight, and another invention provides a foamable thermoplastic elastomer composition which contains :the above said (a) to (c) and (d) 50 to 99 parts by weight of a thermoplastic resin, wherein the components (a) to (d) total 100 parts by weight, and also provides a method of producing the above foamable thermoplastic elastomer composition in two stages.

  本发明的目的是提供一种能产生稳定泡沫的可发泡热塑性弹性体组合物。 本发明提供了一种可发泡热塑性弹性体组合物，它含有：(a) 10 至 90 份（按重量计）熔点或软化点为 140℃或更低的烯烃基树脂和橡胶中的一种，(b) 9 至 85 份（按重量计）在 120 至 300℃下膨胀的可热膨胀微胶囊，(c) 1 至 50 份（按重量计）挥发性组合物，其中(a)至(c)组分的总重量为 100 份，另一项发明提供了一种可发泡热塑性弹性体组合物，它含有：上述(a)至(c)和(d) 50 至 99 份（按重量计）热塑性树脂，其中(a)至(d)组分的总重量为 100 份（按重量计），还提供了一种分两个阶段生产上述可发泡热塑性弹性体组合物的方法。
• Aliphatic esters and polymer compositions containing them
  申请人：Novamont S.p.A.

  公开号：US10144813B2

  公开（公告）日：2018-12-04

  This invention relates to a family of aliphatic esters having the following general structure: R1—O—C(O)—R4—C(O)-[—O—R2—O—C(O)—R5—C(O)-]m—O—R3 in which: R1 is selected from one or more of the groups consisting of H, linear and branched saturated and unsaturated alkyl residues of the C1-C24 type, and polyol residues esterified with C1-C24 monocarboxylic acids; R2 comprises —CH2—C(CH3)2—CH2— and C2-C8 alkylene groups, and comprises at least 50% in moles of the said —CH2—C(CH3)2—CH2— groups; R3 is selected from one or more of the groups consisting of H, linear and branched saturated and unsaturated alkyl residues of the C1-C24 type, and polyol residues esterified with C1-C24 monocarboxylic acids; R4 and R5 comprise one or more C2-C22 alkylenes and comprise at least 50% in moles of C7 alkylenes; m lies between 1 and 20; at least one of R1 and/or R3 comprise polyol residues esterified with at least one C1-C24 monocarboxylic acid selected from the group consisting of stearic acid, palmitic acid, 9-ketostearic acid, 10-ketostearic acid and mixtures thereof. These esters are particularly suitable for use as plasticizers for various types of polymers such as for example vinyl polymers of the polyvinyl chloride (PVC) type, thermoplastic elastomers, and hydroxy acid polyesters, for example polyesters of lactic acid.

  本发明涉及具有以下一般结构的脂肪族酯家族： R1-O-C(O)-R4-C(O)-[-O-R2-O-C(O)-R5-C(O)-]m-O-R3 其中 R1 选自 H、C1-C24 型直链和支链饱和和不饱和烷基残基以及与 C1-C24 单羧酸酯化的多元醇残基组成的一个或多个基团； R2 包括-CH2-C(CH3)2- -和 C2-C8 亚烷基，且上述- -C( )2- -基团的摩尔数至少占 50%； R3 选自 H、C1-C24 型直链和支链饱和及不饱和烷基残基以及与 C1-C24 单羧酸酯化的多元醇残基组成的一个或多个基团； R4 和 R5 由一个或多个 C2-C22 烷基组成，且 C7 烷基的摩尔数至少占 50%； m 介于 1 和 20 之间； R1 和/或 R3 中至少有一个包含与至少一种 C1-C24 单羧酸酯化的多元醇残基，该 C1-C24 单羧酸选自硬脂酸、棕榈酸、9-酮硬脂酸、10-酮硬脂酸及其混合物组成的组。 这些酯类特别适合用作各类聚合物的增塑剂，例如聚氯乙烯（PVC）类乙烯基聚合物、热塑性弹性体和羟基酸聚酯（例如乳酸聚酯）。