Zn(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate)) | 15319-29-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Zn(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate))
• 英文别名: (N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine)zinc(II)；[N,N'-bis(3-methoxysalicylidene)ethane-1,2-diamine]zinc(II)
• CAS: 15319-29-6
• 化学式: C₁₈H₁₈N₂O₄Zn
• 分子量: 391.742
• InChiKey: RYKSXLYPPNIRME-BYCVLTJGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate)) 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Audebert, P.; Capdevielle, P.; Maumy, M., New Journal of Chemistry, 1992, vol. 16, p. 697 - 704

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-bis(3-methoxysalicylidene)ethylenediamine 、 zinc(II) acetate dihydrate 以 四氢呋喃 、 甲醇 为溶剂， 生成 Zn(6,6'-{[ethane-1,2-diylbis(azanylylidene)]bis(methanylylidene)}bis(2-methoxyphenolate))
  参考文献：
  名称：

  Effective enhancement of near-infrared emission by carbazole modification in the Zn–Nd bimetallic Schiff-base complexes

  摘要：

  With ZnL1 or ZnL2 from the simple Salen-type Schiff-base ligand H2L1 (H2L1 N,N'-bis(3-methoxysalicylidene)-ethylene-1,2-diamine) or the carbazole-modified Salen-type Schiff-base ligand H2L2 (H2L2 N,N'-bis(3-methoxy-5-{2-[4-(N-carbazyl)-phenyl]-ethynyl}-ethylene-1,2-diamine) as the precursor, two series of four bimetallic ZnLn complexes (Ln=Nd(1 or 3), Ln=Gd (2 or 4) are obtained, respectively. The photophysical properties results showed that the sensitization from the excited state ((LC)-L-1 and (LC)-L-3) of the ligand H2L1 or H2L2 and the effective energy transfer of Zn2+-Schiff-base (ZnL1 or ZnL2) to the Nd3+ ion for the NIR luminescence were realized, respectively. Especially through the cabarzole modification, the improved NIR luminescence of the ZnNd complex 3 was observed due to the realization of the energy level's match of the excited state of the chromophore to the Nd3+ ion's exciting state. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.02.010

文献信息

• Photoluminescence of Zinc Complexes: Easily Tunable Optical Properties by Variation of the Bridge Between the Imido Groups of Schiff Base Ligands
  作者：Frédéric Dumur、Emmanuel Contal、Guillaume Wantz、Didier Gigmes

  DOI：10.1002/ejic.201402422

  日期：2014.9

  derived from salicylaldehyde and 2-hydroxy-1-naphthaldehyde were designed and investigated. The combination of five nonconjugated flexible spacers and five conjugated rigid spacers with four salicylaldehyde derivatives provided a series of forty complexes. The series of blue to red photoluminescent complexes was investigated by UV/Vis absorption and luminescence spectroscopy in solution and in the solid

  设计并研究了一系列衍生自水杨醛和 2-羟基-1-萘醛的对称四齿席夫碱配体的有机金属螯合物。五个非共轭柔性间隔物和五个共轭刚性间隔物与四种水杨醛衍生物的组合提供了一系列四十种复合物。通过溶液和固态中的紫外/可见吸收和发光光谱以及循环伏安法研究了一系列蓝色到红色光致发光复合物。配体支架中桥的性质被确定为影响所研究的锌 (II) 配合物的吸收和发射颜色的主要参数。
• Heterobinuclear Zn–Ln and Ni–Ln Complexes with Schiff‐Base and Carbacylamidophosphate Ligands: Synthesis, Crystal Structures, and Catalytic Activity
  作者：Oleksiy V. Amirkhanov、Olesia V. Moroz、Kateryna O. Znovjyak、Tetiana Yu. Sliva、Larysa V. Penkova、Tetyana Yushchenko、Lukasz Szyrwiel、Irina S. Konovalova、Viktoriya V. Dyakonenko、Oleg V. Shishkin、Vladimir M. Amirkhanov

  DOI：10.1002/ejic.201402224

  日期：2014.8

  reaction of Salen-like ZnII and NiII precursors with carbacylamidophosphate lanthanide moieties yields six new types of 3d–4f compounds. The complexes were characterized by means of 1H, 31P NMR and IR spectroscopy, elemental analysis, ESI mass spectrometry, and X-ray diffraction analysis. Depending on the Schiff base ligands, the NiII ion adopts either a square-planar or an octahedral geometry, whereas

  Salen 样 ZnII 和 NiII 前体与碳酰氨基磷酸镧系元素的反应产生了六种新型 3d-4f 化合物。通过 1H、31P NMR 和 IR 光谱、元素分析、ESI 质谱和 X 射线衍射分析对配合物进行了表征。取决于席夫碱配体，NiII 离子采用方形平面或八面体几何形状，而 ZnII 离子具有四方锥体几何形状。镧系元素的配位数为九或十。研究了一些异双金属 Zn-Ln 和 Ni-Ln 配位化合物在 2-（羟丙基）-对硝基苯基磷酸酯的分子内水解降解反应中的水解活性。
• Heterobimetallic Zn(II)−Ln(III) Phenylene-Bridged Schiff Base Complexes, Computational Studies, and Evidence for Singlet Energy Transfer as the Main Pathway in the Sensitization of Near-Infrared Nd³⁺ Luminescence
  作者：Wing-Kit Lo、Wai-Kwok Wong、Wai-Yeung Wong、Jianping Guo、Kai-Tai Yeung、Yuen-Kit Cheng、Xiaoping Yang、Richard A. Jones

  DOI：10.1021/ic0610177

  日期：2006.11.1

  formula [Zn(mu-L1)Ln(NO3)3(S)n] [Ln = La (1), Nd (2), Gd (3), Er (4), Yb (5); S = H(2)O, EtOH; n = 1, 2; H2L1 = N,N'-bis(3-methoxysalicylidene)phenylene-1,2-diamine] and [Zn(mu-L2)Ln(NO3)3(H2O)n] [Ln = La (6), Nd (7), Gd (8), Er (9), Yb (10); n = 1, 2; H(2)L(2) = N,N'-bis(3-methoxy-5-p-tolylsalicylidene)phenylene-1,2-diamine] were synthesized and characterized. Complexes 1, 2, 4, and 7 were structurally

  一系列通式为[Zn（mu-L1）Ln（NO3）3（S）n]的3d-4f杂双金属亚苯基桥席夫碱配合物[Ln = La（1），Nd（2），Gd（3 ），Er（4），Yb（5）；S = H（2）O，乙醇; n = 1，2；H2L1 = N，N'-双（3-甲氧基水杨基亚苯基）亚苯基1,2-二胺]和[Zn（mu-L2）Ln（ ）3（H2O）n] [Ln = La（6），Nd（7 ），Gd（8），Er（9），Yb（10）；n = 1，2；合成并表征了H（2）L（2）= N，N'-双（3-甲氧基-5-对甲苯基亚水基）亚苯基-1，2-二胺]。配合物1、2、4和7在结构上通过X射线晶体学表征。在室温下，在CH（3）CN中，钕（III）（2和7）和（III）（5和10）配合物除了在UV-vis区域中以配体为中心的发射外，还显示出它们的复合物。在近红外（NIR）区域中的镧系元素（III）离子发射。测量了由锌
• Synthesis and near-infrared luminescence of 3d-4f bi-metallic Schiff base complexes
  作者：Wai-Kwok Wong、Hongze Liang、Wai-Yeung Wong、Zongwei Cai、King-Fai Li、Kok-Wai Cheah

  DOI：10.1039/b104175b

  日期：2002.3.11

  The reaction of the zinc(II) Schiff base complex ZnL [H2L=N,N′-bis(3-methoxysalicylidene)ethylene-1,2-diamine] with one equivalent of Ln(NO3)3·xH2O (Ln=Nd, Ho, Er or Yb) gives the neutral 3d-4f bi-metallic Schiff base complexes [Zn(NO3)(μ-L)Ln(NO3)2(H2O)], which in solution exhibit emission corresponding to the Ln(III) ions (Ln=Nd, Er and Yb) in the near-infrared region.

  锌（II）席夫碱配合物ZnL [H 2 L =N，N'-双（3-甲氧基水杨基）乙烯-1,2-二胺]与一当量的Ln（NO 3）3 · x H 2 O（Ln = Nd，Ho，Er或Yb）等效得到中性的3d-4f双金属希夫碱配合物[Zn（NO 3）（μ-L）Ln（NO 3）2（H 2 O）]，其在溶液中的发射与附近的Ln（III）离子（Ln = Nd，Er和Yb）相对应-红外区域。
• The Zn2Dy2 single-molecule magnet constructed by salen-type ligand and hydroximic acid
  作者：Chu-Meng Wang、Zhuo Wu、Peng Chen、Yong-Mei Tian、Wen-Bin Sun

  DOI：10.1016/j.molstruc.2021.131231

  日期：2021.12