9,10-bis(mercaptomethyl)anthracene | 59045-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis(mercaptomethyl)anthracene
• 英文别名: 9,10-anthracenedimethanedithiol；9,10-anthracenedimethanethiol；9,10-dithiamethyl-anthracene；9,10-Anthracendimethanthiol；9,10-bis-mercaptomethyl-anthracene；9,10-Bis-mercaptomethyl-anthracen；[10-(sulfanylmethyl)anthracen-9-yl]methanethiol
• CAS: 59045-59-9
• 化学式: C₁₆H₁₄S₂
• 分子量: 270.419
• InChiKey: QULSCWWJJFURRB-UHFFFAOYSA-N

物化性质

• 熔点：
  145 °C
• 沸点：
  490.1±25.0 °C(Predicted)
• 密度：
  1.238±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis(mercaptomethyl)anthracene 在 乙醇 、 sodium 、 亚磷酸三乙酯 作用下， 以 苯 为溶剂， 生成 <2.2>(9,10)anthracenoparacyclophane
  参考文献：
  名称：

  Ferguson, James; Puza, Miroslav; Robbins, Raymond J., Australian Journal of Chemistry, 1989, vol. 42, # 12, p. 2215 - 2223

  摘要：

  DOI：
• 作为产物：
  描述：

  9,10-二(氯甲基)蒽 在 硫脲 、 lithium aluminium tetrahydride 作用下， 以 乙醇 、 四氢呋喃 为溶剂， 反应 2.0h， 以85%的产率得到9,10-bis(mercaptomethyl)anthracene
  参考文献：
  名称：

  The synthesis and complexation studies of thia-anthracene receptors

  摘要：

  Systematic studies towards the formation of thia-anthracene receptors were performed. Anthracene podand 3 consisting of two anthryl groups connected by the SCH2CH2CH2S spacer group was prepared in 99% yield. The complexation properties of this compound were investigated using UV-VIS and fluorescence titration techniques. Addition of silver salts into a solution of the fluorophore strongly modifies the absorption and fluorescence spectra and the association constants were found to be K-1 = 2 x 10(5) and K-2 = 8 x 10(4) M-1 for the 1:1 and 1:2 complexes, respectively. Addition of metal ions, as Cu2+, Zn2+, Cd2+, Hg2+, Ni2+, and Co2+, did not lead to any change in the photophysical properties of compound 3. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00654-7

文献信息

• [EN] COSMETIC PROCESS FOR ATTENUATING WRINKLES<br/>[FR] PROCÉDÉ COSMÉTIQUE POUR ATTÉNUER LES RIDES
  申请人：OREAL

  公开号：WO2016050788A1

  公开（公告）日：2016-04-07

  The invention relates to a cosmetic process for wrinkled skin, comprising either the topical application to the skin of an extemporaneous mixture of a cosmetic composition comprising a polysaccharide polymer grafted with (meth)acrylate groups and of a crosslinking thiol compound having one or more thiol groups; or the sequential application to the skin of a cosmetic composition comprising a polysaccharide polymer grafted with (meth)acrylate groups, followed by the application of a crosslinking thiol compound having one or more thiol groups, or of a cosmetic composition containing same. The invention also relates to the use of the mixture of said grafted polysaccharide polymer and of said crosslinking thiol as a skin tensioning agent. The invention also relates to a cosmetic composition obtained by mixing a cosmetic composition comprising said grafted polysaccharide polymer and said crosslinking thiol. The invention relates to a kit comprising a first cosmetic composition comprising said grafted polysaccharide polymer and a second composition comprising said crosslinking thiol, the first and second compositions each been packaged in a distinct packaging assembly.

  该发明涉及一种用于皱纹皮肤的化妆过程，包括以下两种方式：要么将一种化妆组合物涂抹在皮肤上，该组合物包括一种聚糖聚合物，其与（甲基）丙烯酸酯基团进行嫁接，以及一种具有一个或多个硫醇基团的交联硫醇化合物的现场混合物；要么将一种包括聚糖聚合物，其与（甲基）丙烯酸酯基团进行嫁接的化妆组合物顺序涂抹在皮肤上，然后涂抹一种具有一个或多个硫醇基团的交联硫醇化合物，或者含有该化合物的化妆组合物。该发明还涉及将所述嫁接聚糖聚合物和所述交联硫醇的混合物用作皮肤紧致剂。该发明还涉及通过混合包括所述嫁接聚糖聚合物和所述交联硫醇的化妆组合物而获得的化妆组合物。该发明涉及一种套装，包括第一化妆组合物，其中包括所述嫁接聚糖聚合物，以及第二组成物，其中包括所述交联硫醇，第一和第二组成物分别被包装在不同的包装组件中。
• SYNTHESIS OF CYCLOPHANES FROM A SELF-ASSEMBLY REACTION
  申请人：University of Oregon

  公开号：US20160137598A1

  公开（公告）日：2016-05-19

  Disclosed herein is a novel method for preparing cyclophanes, comprising forming a disulfide cyclophane by contacting a linker moiety which includes two or more thiol groups, with a metal salt and an oxidant. The disulfide cyclophane is then desulfurized to form a thiacyclophane comprising thioether bridges. This thiacyclophane optionally may be further desulfurized to form an unsaturated hydrocarbon cyclophane, which can then be reduced to form a saturated hydrocarbon cyclophane. The various cyclophanes can be synthesized in a ring form, such as a dimer, trimer or tetramer etc., or they can be synthesized in a tetrahedral or larger structure. Also disclosed are novel cyclophanes formed by the disclosed method.

  本文揭示了一种制备环戊烷的新方法，包括通过将含有两个或更多硫醚基团的连接剂与金属盐和氧化剂接触来形成二硫化环戊烷。然后对二硫化环戊烷进行脱硫作用，形成含有硫醚桥的硫代环戊烷。这种硫代环戊烷可以选择性地进一步脱硫，形成不饱和碳氢化合物环戊烷，然后可以还原为饱和碳氢化合物环戊烷。这些不同的环戊烷可以以环形形式合成，如二聚体、三聚体或四聚体等，或者它们可以以四面体或更大的结构合成。此外，还披露了通过上述方法形成的新型环戊烷。
• CHROMENE COMPOUND, CURABLE COMPOSITION COMPRISING THE COMPOUND, AND OPTICAL ARTICLE INCLUDING A CURED BODY OF THE CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20200190106A1

  公开（公告）日：2020-06-18

  A chromene compound having at least one indenonaphthopyran moiety which has a group forming a spiro ring together with the 13-position carbon atom and further an oligomer chain group selected from a polyalkylene oxide oligomer chain group having at least three recurring units and a polyester oligomer chain group having at least three recurring units, represented by the following formula and having reduced matrix dependence: wherein R 1 and R 2 are each a group which may have an oligomer chain group, the ring Z bonded to the 13-position carbon atom of the chromene compound is a Spiro ring group, and R 3 and R 4 are each an aryl group or heteroaryl group which may have an oligomer chain group. Preferably, the chromene compound has at least one oligomer chain group in the molecule.

  具有至少一个印苯并萘吡喃基团的色酮化合物，其中该基团与13位碳原子形成螺环，并且进一步具有从至少三个重复单元中选择的聚烷氧基寡聚物链基团和聚酯寡聚物链基团中的一个寡聚物链基团，由下式表示并具有降低的矩阵依赖性： 其中R1和R2是各自可能具有寡聚物链基团的基团，与色酮化合物的13位碳原子键合的环Z是螺环基团，而R3和R4是各自可能具有寡聚物链基团的芳基或杂环基团。最好，该色酮化合物在分子中至少具有一个寡聚物链基团。
• METAL COMPOUND, POLYMERIZABLE COMPOSITION CONTAINING THE SAME, RESIN, METHOD FOR PRODUCING THE RESIN, AND USE OF THE RESIN
  申请人：Murakami Masakazu

  公开号：US20110136977A1

  公开（公告）日：2011-06-09

  Disclosed is a metal compound represented by the following formula (0): in the formula (0), A represents a thietane ring, or a monovalent group containing a thiol group; B represents a divalent group containing a heteroatom; R 2 represents a divalent organic group; n represents the valence of M; p represents an integer of 1 ton; M represents a lanthanoid atom or a barium (Ba) atom when A is a thietane ring, and represents a lanthanoid atom when A is a monovalent group containing a thiol group; or more than Y represents a monovalent inorganic or organic group; when n−p is not less than 2, a plurality of Y's each independently represent a monovalent inorganic or organic group; and when n−p is not less than 2, the plurality of Y's may be bonded with each other to form a ring containing M.

  揭示了一种由以下公式（0）表示的金属化合物： 在公式（0）中，A表示噻吩环或含有硫醇基的一价基团；B表示含有杂原子的二价基团；R2表示二价有机基团；n表示M的价；p表示1到n的整数；当A是噻吩环时，M表示镧系元素或钡（Ba）原子，当A是含有硫醇基的一价基团时，M表示镧系元素；Y表示一价无机或有机基团，当n-p不小于2时，多个Y可以各自独立地表示一价无机或有机基团；当n-p不小于2时，多个Y可以彼此连接形成含有M的环。
• Chiroptical properties of dithia[3.3]cyclophanes composed of anthracene and pyridine/pyridinium moieties: A combined experimental and theoretical study
  作者：Akinori Shimizu、Keisuke Nagasaki、Yoshihisa Inoue、Tadashi Mori

  DOI：10.1002/chir.22740

  日期：2017.11

  dominated by the local transitions of anthracene. Nevertheless, the CD spectra of 1 and 1‐H+ were well reproduced by theoretical calculations to allow us an unambiguous absolute configuration determination of the first high‐performance liquid chromatography (HPLC) elute (from Chiralcel IB column) as Sp. The transannular interactions between the anthracene and pyridine/pyridinium units were examined by UV‐vis

  通过实验和理论研究了中性和质子化[3.3]蒽吡啶并吡啶鎓（1和1 H +）的圆二色性（CD）。引入具有延长的共轭的蒽部分影响了环烷结构，其弯曲角与母体[3.3]吡啶并烷的弯曲角相比明显减小。在观察到的效果棉花（CES）1个乙b频带两者1和1-H +是相当强的，显然bisignate，然而，事实并非是简单的激子对联而是由多个转换。相反，CE在1 L a中要弱得多乐队区域。与母体吡啶吡啶相比，质子化后的光谱变化不那么显着，主要由蒽的局部跃迁控制。然而，1和1 H +的CD谱通过理论计算得到了很好的再现，从而使我们能够明确地确定第一个高效液相色谱（HPLC）洗脱液（来自Chiralcel IB柱）的S p绝对构型。通过紫外可见光谱和荧光光谱检查了蒽与吡啶/吡啶鎓单元之间的跨环相互作用，揭示了低能区的电荷转移（CT）带，特别是对于1 H +。尽管有可比的CT相互作用，但蒽吡啶基吡啶在CT波段的CE