diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine | 1347752-56-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine
• 英文别名: hexaiminohexaazatrinaphthalene；DPH；5,6,11,12,17,18-hexaazatrinaphthylene-2,3,8,9,14,15-hexaamine；Diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine；3,10,13,20,23,30-hexazaheptacyclo[20.8.0.02,11.04,9.012,21.014,19.024,29]triaconta-1(30),2,4(9),5,7,10,12,14(19),15,17,20,22,24(29),25,27-pentadecaene-6,7,16,17,26,27-hexamine
• CAS: 1347752-56-0
• 化学式: C₂₄H₁₈N₁₂
• 分子量: 474.487
• InChiKey: FUDKFMJAXUPHBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.1
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  234
• 氢给体数：
  6
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  1-溴十一烷 、 diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine 以 水 为溶剂， 反应 0.5h， 以78%的产率得到2,3,8,9,14,15-hexaundecyldiquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine
  参考文献：
  名称：

  基于胺衍生的六氮杂萘并萘的新型有机胶凝剂†

  摘要：

  新型C 3-对称杂芳族六氮杂萘萘（HATNA）胶凝剂被芳香族和脂族侧基侧基对称取代。这些π共轭结构中的一些诱导自组装，形成能够以低wt％凝胶化不同极性的溶剂的纤维，如通过光谱学和显微镜技术所证明的。

  DOI：

  10.1039/c1ob05811h
• 作为产物：
  描述：

  邻苯二胺 在 吡啶 、 硫酸 、 palladium on activated charcoal 、 氢气 、 硝酸 、 溶剂黄146 作用下， 以 乙酸乙酯 为溶剂， 20.0~100.0 ℃ 、500.01 kPa 条件下， 反应 69.5h， 生成 diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine
  参考文献：
  名称：

  Diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine(DPH) 단량체 및 이를 이용한 촉매 복합체

  摘要：

  本发明提供了一种催化剂复合物，该复合物由diquinoxalino [2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine（DPH）单体和上述单体与hexaketocyclohexane octahydrate反应制成，可以提供催化活性良好，稳定性优异且可大规模生产的催化剂复合物。

  公开号：

  KR101793453B1

文献信息

• <i>In Vitro</i> Activities of Hexaazatrinaphthylenes against Leishmania spp
  作者：Atteneri López-Arencibia、Daniel García-Velázquez、Carmen M. Martín-Navarro、Ines Sifaoui、María Reyes-Batlle、Jacob Lorenzo-Morales、Ángel Gutiérrez-Ravelo、José E. Piñero

  DOI：10.1128/aac.00226-15

  日期：2015.5

  cytotoxicity assay was carried out to in order to evaluate the possible toxic effects of these compounds. Moreover, different assays were performed to determine the type of cell death induced after incubation with these compounds. The obtained results highlight the potential use of hexaazatrinaphthylene derivatives against Leishmania species, and further studies should be undertaken to establish them as novel

  在这项研究中描述了一组新型的化合物，六氮杂萘并菲衍生物对两种利什曼原虫的体外活性。这些化合物对寄生虫的增殖表现出显着的剂量依赖性抑制作用，对前鞭毛体阶段的抑制浓度（IC（50）s）为50％，范围为1.23至25.05μM，对细胞内的变形虫，抑制浓度为0.5至0.7μM。另外，进行了细胞毒性试验以评估这些化合物可能的毒性作用。此外，进行了不同的测定以确定与这些化合物一起温育后诱导的细胞死亡的类型。所得结果突出了六氮杂萘并菲衍生物对利什曼原虫物种的潜在用途，
• Tuning Electron Delocalization of Redox‐Active Porous Aromatic Framework for Low‐Temperature Aqueous Zn–K Hybrid Batteries with Air Self‐Chargeability
  作者：Junhao Wang、Xupeng Zhang、Zhaoli Liu、Jie Yu、Heng-Guo Wang、Xing-Long Wu、Fengchao Cui、Guangshan Zhu

  DOI：10.1002/anie.202401559

  日期：——

  Air self‐charging aqueous batteries promise to integrate energy harvesting technology and battery systems, potentially overcoming a heavy reliance on energy and the spatiotemporal environment. However, the exploitation of multifunctional air self‐charging battery systems using promising cathode materials and suitable charge carriers remains challenging. Herein, for the first time, we developed low‐temperature self‐charging aqueous Zn‐K hybrid ion batteries (AZKHBs) using a fully conjugated hexaazanonaphthalene (HATN)‐based porous aromatic framework as the cathode material, exhibiting redox chemistry using K+ as charge carriers, and regulating Zn‐ion solvation chemistry to guide uniform Zn plating/stripping. The unique AZKHBs exhibit the exceptional electrochemical properties in all‐climate. Most importantly, the large potential difference causes the AZKHBs discharged cathode to be oxidized using oxygen, thereby initiating a self‐charging process in the absence of an external power source. Impressively, the air self‐charging AZKHBs can achieve a maximum voltage of 1.15 V, an impressive discharge capacity (466.3 mA h g‐1), and exceptional self‐charging performance even at –40 °C. Therefore, the development of self‐charging AZKHBs offers a solution to the limitations imposed by the absence of a power grid in harsh environments or remote areas.
• Novel organogelators based on amine-derived hexaazatrinaphthylene
  作者：Daniel García Velázquez、Alejandro González Orive、Alberto Hernández Creus、Rafael Luque、Ángel Gutiérrez Ravelo

  DOI：10.1039/c1ob05811h

  日期：——

  Novel C3-symmetrical heteroaromatic hexaazatrinaphthylene (HATNA) gelators symmetrically end-substituted with pendant aromatic and aliphatic amines were synthesized. Some of these π-conjugated structures induce self-assembly, forming fibers able to gelate solvents of different polarity at low wt% as demonstrated by spectroscopic and microscopic techniques.

  新型C 3-对称杂芳族六氮杂萘萘（HATNA）胶凝剂被芳香族和脂族侧基侧基对称取代。这些π共轭结构中的一些诱导自组装，形成能够以低wt％凝胶化不同极性的溶剂的纤维，如通过光谱学和显微镜技术所证明的。
• Diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine(DPH) 단량체 및 이를 이용한 촉매 복합체
  申请人：UNIST(ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY) 울산과학기술원(120150812047) Corp. No ▼ 230171-0011595BRN ▼620-82-06236

  公开号：KR101793453B1

  公开（公告）日：2017-11-20

  본 발명은 diquinoxalino[2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine(DPH) 단량체와 상기 단량체와 hexaketocyclohexane octahydrate를 반응시켜 제조되는 촉매 복합체를 제공하여 촉매 활성이 좋고, 안정성이 우수하면서도 대량생산이 가능한 촉매 복합체를 제공할 수 있다.

  本发明提供了一种催化剂复合物，该复合物由diquinoxalino [2,3-a:2',3'-c]phenazine-2,3,8,9,14,15-hexaamine（DPH）单体和上述单体与hexaketocyclohexane octahydrate反应制成，可以提供催化活性良好，稳定性优异且可大规模生产的催化剂复合物。