2,3,6-Triacetoxy-acetophenon | 18477-46-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,3,6-Triacetoxy-acetophenon
• CAS: 18477-46-8
• 化学式: C₁₄H₁₄O₇
• 分子量: 294.261
• InChiKey: JOMKVLNEGFQPSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.67
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  95.97
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  2,3,6-Triacetoxy-acetophenon 在 甲醇 、 硫酸 作用下， 生成 1-(3-acetoxy-2,6-dihydroxy-phenyl)-ethanone
  参考文献：
  名称：

  How to eliminate illusions in quantified reasoning

  摘要：

  The mental model theory postulates that reasoners build models of situations described in premises. These models normally make explicit only what is true according to the premises. The theory has an unexpected consequence. It predicts the existence of illusions in inferences: Certain inferences should have compelling but erroneous conclusions. Previous studies have corroborated the existence of such illusions. The present study reports the first effective antidote to them. For example, most people incorrectly answer "yes" to the following problem: Only one of the following statements is true.../At least some of the plastic beads are not red./None of the plastic beads are red./Is it possible that none of the red beads are plastic In two experiments, we progressively eliminated this fallacy and others by using instructions designed to overcome the bias toward truth. The difference between the illusory and the control problems disappeared when the participants were instructed to work out both the case in which the first premise was true and the second premise was false and the case in which the second premise was true and the first premise was false.

  DOI：

  10.3758/bf03209353
• 作为产物：
  描述：

  2,5-二羟基苯乙酮 在 硫酸 、 silver(l) oxide 作用下， 生成 2,3,6-Triacetoxy-acetophenon
  参考文献：
  名称：

  How to eliminate illusions in quantified reasoning

  摘要：

  The mental model theory postulates that reasoners build models of situations described in premises. These models normally make explicit only what is true according to the premises. The theory has an unexpected consequence. It predicts the existence of illusions in inferences: Certain inferences should have compelling but erroneous conclusions. Previous studies have corroborated the existence of such illusions. The present study reports the first effective antidote to them. For example, most people incorrectly answer "yes" to the following problem: Only one of the following statements is true.../At least some of the plastic beads are not red./None of the plastic beads are red./Is it possible that none of the red beads are plastic In two experiments, we progressively eliminated this fallacy and others by using instructions designed to overcome the bias toward truth. The difference between the illusory and the control problems disappeared when the participants were instructed to work out both the case in which the first premise was true and the second premise was false and the case in which the second premise was true and the first premise was false.

  DOI：

  10.3758/bf03209353

文献信息

• Thiele acetylation of substituted benzoquinones
  作者：H. S. Wilgus、J. W. Gates,Jr

  DOI：10.1139/v67-314

  日期：1967.9.1

  The treatment of substituted quinones with acetic anhydride under acid catalysis gives substituted triacetoxybenzenes. Previous work on this reaction is summarized, and the reaction has been extended to include quinones having electron-withdrawing groups, and two quinones which had previously been reported as inactive.

  用醋酸酐在酸催化下处理取代醌可得到取代三乙酰氧基苯。对这种反应的先前研究进行了总结，并将该反应扩展到包括具有电子吸引基团的醌，以及之前被报道为不活跃的两种醌。
• Nakazawa, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1939, vol. 59, p. 297,301;dtsch.Ref.S.107,109
  作者：Nakazawa

  DOI：——

  日期：——
• How to eliminate illusions in quantified reasoning
  作者：Yingrui Yang、P. N. Johnson-Laird

  DOI：10.3758/bf03209353

  日期：2000.11

  The mental model theory postulates that reasoners build models of situations described in premises. These models normally make explicit only what is true according to the premises. The theory has an unexpected consequence. It predicts the existence of illusions in inferences: Certain inferences should have compelling but erroneous conclusions. Previous studies have corroborated the existence of such illusions. The present study reports the first effective antidote to them. For example, most people incorrectly answer "yes" to the following problem: Only one of the following statements is true.../At least some of the plastic beads are not red./None of the plastic beads are red./Is it possible that none of the red beads are plastic In two experiments, we progressively eliminated this fallacy and others by using instructions designed to overcome the bias toward truth. The difference between the illusory and the control problems disappeared when the participants were instructed to work out both the case in which the first premise was true and the second premise was false and the case in which the second premise was true and the first premise was false.