菲-2,7-二胺 | 62245-46-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 菲-2,7-二胺
• 英文名称: 2,7-diaminophenanthrene
• 英文别名: 2,7-Phenanthrenediamine；phenanthrene-2,7-diamine
• CAS: 62245-46-9
• 化学式: C₁₄H₁₂N₂
• 分子量: 208.263
• InChiKey: QJZDTUSIYGXUJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  菲-2,7-二胺 在 盐酸 、 sodium azide 、 水 、 sodium nitrite 作用下， 生成 2,7-diazidophenanthrene
  参考文献：
  名称：

  Effects of Additional Linkers in Biphenyl-4,4‘-dinitrene on the Low-Lying Singlet−Triplet Energy Gap and Zero-Field Splitting

  摘要：

  Perturbation effects of additional linkers on the spin-spin coupling in biphenyl-4,4'-dinitrene (1) were examined by introducing a linking group between 2- and 2'-positions of 1. Five different doubly linked systems showed triplet ESR spectra corresponding to quinonoid dinitrenes. Curie law analyses suggested that all those tripler states were thermally excited triplet states. In addition, the singlet-tripler energy gaps, which were determined by the Curie law analyses, were well, correlated with their corresponding zero-field-splitting (zfs) D values. The result could be explained by the stability of dinitrene character which is estimated from the resonance energy of the intervening pi-system. Our semiempirical molecular orbital calculations supported the experimental correlation between the singlet-triplet energy gap and the zfs D value.

  DOI：

  10.1021/jp9629710
• 作为产物：
  描述：

  二苯基-2,2-二甲醛 在 palladium on activated charcoal 硫酸 、 一水合肼 、 potassium nitrate 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 生成 菲-2,7-二胺
  参考文献：
  名称：

  Bochenkov,V.N., Journal of Organic Chemistry USSR (English Translation), 1976, vol. 12, p. 2355 - 2357

  摘要：

  DOI：

文献信息

• [EN] ORGANOMETALLIC COMPLEX AND ORGANIC LIGHT-EMITTING ELEMENT USING THE COMPLEX<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE UTILISANT LEDIT COMPLEXE
  申请人：CANON KK

  公开号：WO2014112657A1

  公开（公告）日：2014-07-24

  Provided is an organic light-emitting element having high light-emitting efficiency and a long element lifetime, the organic light-emitting element including an anode, a cathode, and an organic compound layer placed between the anode and the cathode, in which: the organic compound layer includes an emission layer; the emission layer includes a host and a guest; the host is an aromatic hydrocarbon compound; the guest is an iridium complex of a specific structure; and a content of the host is 50 wt% or more with reference to the total amount of the constituent materials for the emission layer.

  提供的是一种具有高发光效率和长寿命的有机发光元件，该有机发光元件包括阳极、阴极和放置在阳极和阴极之间的有机化合物层，其中：有机化合物层包括发射层；发射层包括主体和客体；主体是芳香烃类化合物；客体是具有特定结构的铱配合物；主体的含量相对于发射层的组分材料总量为50重量％或更多。
• AROMATIC AMINE DERIVATIVES AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20070029927A1

  公开（公告）日：2007-02-08

  An aromatic amine derivative with a specific structure and an organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. The organic electroluminescence device which exhibits an enhanced current efficiency of light emission and emits blue light with a prolonged lifetime is realized.

  一种具有特定结构的芳香胺衍生物和一种有机电致发光器件，该器件至少包括一个有机薄膜层，其中包括夹在由阳极和阴极组成的一对电极之间的发光层，其中至少一个有机薄膜层包括该芳香胺衍生物单独或作为其混合组分。实现了一种具有增强的发光电流效率并且发出蓝光并具有延长寿命的有机电致发光器件。
• [EN] NOVEL m-TERPHENYL COMPOUND AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME<br/>[FR] NOUVEAU COMPOSÉ M-TERPHÉNYLE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE CONTENANT
  申请人：CANON KK

  公开号：WO2011132624A1

  公开（公告）日：2011-10-27

  An organic light emitting device which includes a m-terphenyl compound having a high T1 energy is provided. In addition, a novel m-terphenyl compound is provided.

  提供了一种具有高T1能量的m-terphenyl化合物的有机发光器件。此外，还提供了一种新型的m-terphenyl化合物。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE MAKING USE OF THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1914222A1

  公开（公告）日：2008-04-23

  An aromatic amine derivative with a specific structure snd an organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. The organic electroluminescence device which exhibits an enhanced current efficiency of light emission and emits blue light with a prolonged lifetime is realized.

  一种具有特殊结构的芳香族胺衍生物和一种有机电致发光器件，该器件包括至少一个有机薄膜层，该薄膜层由夹在一对由阳极和阴极组成的电极之间的发光层组成，其中至少一个有机薄膜层由芳香族胺衍生物单独或作为其混合物成分组成。这种有机电致发光器件的发光电流效率得到了提高，并能发出寿命更长的蓝光。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：EP3010068A1

  公开（公告）日：2016-04-20

  An organic light-emitting device includes: a first electrode; a second electrode disposed opposite to the first electrode; an emission layer between the first electrode and the second electrode; and a hole transport region between the first electrode and the emission layer, wherein the emission layer includes an organometallic compound of Formula 1 as represented in the specification, and the hole transport region includes a first compound of Formula 2A or Formula 2B as represented in the specification.

  一种有机发光器件包括：第一电极；与第一电极相对设置的第二电极；位于第一电极和第二电极之间的发射层；以及位于第一电极和发射层之间的空穴传输区域，其中发射层包括如说明书所示的式 1 的有机金属化合物，空穴传输区域包括如说明书所示的式 2A 或式 2B 的第一种化合物。