1,6-dimethoxydodecafluorohexane | 132182-96-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,6-dimethoxydodecafluorohexane
• 英文别名: 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-1,6-dimethoxyhexane
• CAS: 132182-96-8
• 化学式: C₈H₆F₁₂O₂
• 分子量: 362.115
• InChiKey: XCHCENKTLKDVFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  1,6-bis(fluorosulfato)perfluorhexane 、 硫酸二甲酯 在 cesium fluoride 作用下， 以 various solvent(s) 为溶剂， 反应 2.0h， 以69%的产率得到1,6-dimethoxydodecafluorohexane
  参考文献：
  名称：

  Fluoroaliphatic esters of fluorosulfonic acid. 2. Reaction of bis(fluorosulfato)perfluoroalkanes with cesium fluoride

  摘要：

  2,3-Bis(fluorosulfato) perfluoroalkanes split under the action of CsF in the absence of solvents, giving a mixture of alpha-fluorosulfatoperfluoro ketones, perfluoroalkene sulfates, and perfluoro alpha-diketones. The occurrence of these reactions in solutions results mainly in the formation of oxides of the corresponding fluoroolefins or products of their conversions. The reactions carried out are the first examples of nucleophilic substitution at a secondary carbon atom in a perfluorinated saturated chain.

  DOI：

  10.1007/bf00958252

文献信息

• ROGOVIK, V. M.;DELYAGINA, N. I.;MYSOV, E. I.;CHERSTKOV, V. F.;STERLIN, S.+, IZV. AN CCCP. CEP. XIM.,(1990) N, S. 2057-2063
  作者：ROGOVIK, V. M.、DELYAGINA, N. I.、MYSOV, E. I.、CHERSTKOV, V. F.、STERLIN, S.+

  DOI：——

  日期：——
• Fluoroaliphatic esters of fluorosulfonic acid. 2. Reaction of bis(fluorosulfato)perfluoroalkanes with cesium fluoride
  作者：V. M. Rogovik、N. I. Delyagina、E. I. Mysov、V. F. Cherstkov、S. R. Sterlin、L. S. German

  DOI：10.1007/bf00958252

  日期：1990.9

  2,3-Bis(fluorosulfato) perfluoroalkanes split under the action of CsF in the absence of solvents, giving a mixture of alpha-fluorosulfatoperfluoro ketones, perfluoroalkene sulfates, and perfluoro alpha-diketones. The occurrence of these reactions in solutions results mainly in the formation of oxides of the corresponding fluoroolefins or products of their conversions. The reactions carried out are the first examples of nucleophilic substitution at a secondary carbon atom in a perfluorinated saturated chain.