申请人:SOLVAY SOLEXIS S.p.A.
公开号:US20140228531A1
公开(公告)日:2014-08-14
The invention pertains to a method for making a fluoropolymer comprising an aqueous emulsion polymerization of one or more fluorinated monomers wherein said aqueous emulsion polymerization is carried out in the presence of at least one cyclic fluorocompound of the following formula (I):
wherein X
1
, X
2
, X
3
, equal or different from each other are independently selected among H, F, and C
1-6
(per)fluoroalkyl groups, optionally comprising one or more catenary or non-catenary oxygen atoms; L represents a bond or a divalent group; R
F
is a divalent fluorinated C
1-3
bridging group; Y is a hydrophilic function selected among anionic functionalities, cationic functionalities and non-ionic functionalities.
该发明涉及一种制备氟聚合物的方法,包括一种水乳液聚合的方法,其中所述水乳液聚合是在至少一种具有以下式(I)的环状氟化合物存在下进行的:其中X1、X2、X3相互独立且可相同或不同地选择自H、F和C1-6(per)氟烷基团,可选地包括一个或多个环链或非环链氧原子;L代表键或二价基团;RF是二价氟化的C1-3桥联基团;Y是在阴离子功能团、阳离子功能团和非离子功能团中选择的亲水功能。