10-(dibenzo[b,d]thiophen-4-yl)-9-(naphthalene-2-yl)anthracene | 1361453-04-4

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 10-(dibenzo[b,d]thiophen-4-yl)-9-(naphthalene-2-yl)anthracene
• 英文别名: 4-(10-(naphthalen-2-yl)anthracen-9-yl)dibenzothiophene；4-(10-Naphthalen-2-ylanthracen-9-yl)dibenzothiophene
• CAS: 1361453-04-4
• 化学式: C₃₆H₂₂S
• 分子量: 486.637
• InChiKey: QIPWECBKEBEFIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  37
• 可旋转键数：
  2
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-溴-10-(2-萘基)蒽 、 二苯并噻吩-4-硼酸 在 bis-triphenylphosphine-palladium(II) chloride 、 potassium carbonate 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以85%的产率得到10-(dibenzo[b,d]thiophen-4-yl)-9-(naphthalene-2-yl)anthracene
  参考文献：
  名称：

  New blue host materials based on anthracene-containing dibenzothiophene

  摘要：

  A series of novel host blue-emitting materials based on anthracene have been synthesized and investigated in which, a pi-electron-rich dibenzothiophene moiety was introduced as a side group to fine adjust the HOMO/LUMO levels of the anthracene and enhance the ability of hole-transport and electron-injection. These materials exhibit good film-forming capabilities, and display strong blue fluorescence in solution. To explore the electroluminescent properties of these materials, sky blue devices of 2-TNATA (60 nm)/NPB (10 nm)/Host: BUBD-1 (40 nm)/Alq(3) (15 nm)/LiF (1 nm)/Al (150 nm) were fabricated. For the device with 9, 10-bis(dibenzothiophen-4-yl)anthracene as the host, an electroluminescence efficiency of 13.14 cd/A and 6.76 lm/W at 20 mA/cm(2) and 6.09 V were achieved, with Commission Internationale d'Eclairage (CIEx,y) color coordinates of (x = 0.15, y = 0.30). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2011.01.002

文献信息

• COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200270283A1

  公开（公告）日：2020-08-27

  Provided is a compound represented by Formula 1 and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1.

  提供的是由公式1表示的化合物以及包括该化合物的有机发光设备。所述有机发光设备包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，所述有机层包括发射层和由公式1表示的化合物。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND POLYCYCLIC COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20210143336A1

  公开（公告）日：2021-05-13

  An organic electroluminescence device of an embodiment includes a first electrode, a second electrode, and an emission layer disposed between the first electrode and the second electrode, and the emission layer includes a polycyclic compound represented by Formula 1. The organic electroluminescence device may exhibit high luminous efficiency and/or service life characteristics:

  本实施例的一种有机电致发光装置包括第一电极、第二电极以及位于第一电极和第二电极之间的发光层，发光层包括由公式1表示的多环化合物。该有机电致发光装置可能展现出高发光效率和/或使用寿命特性。
• MATERIAL FOR AN ORGANIC ELECTROLUMINESCENT DEVICE AND ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160285006A1

  公开（公告）日：2016-09-29

  Embodiments of the present disclosure are directed toward a material for an organic electroluminescent device realizing a low driving voltage and high emission efficiency, and an organic electroluminescent device using the same. The material for an organic electroluminescent device is represented by Formula 1: In Formula 1, X is selected from O, N or S, Y and Z are each independently selected from CAr 5 Ar 6 or SiAr 7 Ar 8 , Ar 1 to Ar 8 are each independently selected from a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, a substituted or unsubstituted heteroaryl group having 5 to 30 carbon atoms for forming a ring, a silyl group, a halogen atom, deuterium, and hydrogen, and l to n are each independently an integer selected from 0 to 4.

  本公开的实施例涉及一种用于实现低驱动电压和高发射效率的有机电致发光器件的材料，以及使用该材料的有机电致发光器件。用于有机电致发光器件的材料由化学式1表示： 在化学式1中，X从O、N或S中选择，Y和Z分别从CAr 5 Ar 6 或SiAr 7 Ar 8 中独立选择，Ar 1 至Ar 8 分别从具有1至30个碳原子的取代或未取代烷基基团、用于形成环的具有6至30个碳原子的取代或未取代芳基基团、用于形成环的具有5至30个碳原子的取代或未取代杂环芳基基团、硅基基团、卤素原子、氘和氢中独立选择，l至n分别是从0到4中独立选择的整数。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND FUSED POLYCYCLIC COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20210391540A1

  公开（公告）日：2021-12-16

  An organic electroluminescence device of an embodiment includes a first electrode facing a second electrode, and a plurality of organic layers between the first electrode and the second electrode, wherein at least one organic layer among the plurality of organic layers includes a fused polycyclic compound represented by Formula 1 below, thereby showing improved emission efficiency.

  本实施例的有机电致发光装置包括面向第二电极的第一电极，以及位于第一电极和第二电极之间的多个有机层，其中多个有机层中至少一个有机层包括如以下公式1所示的融合多环化合物，从而显示提高了的发射效率。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE ORGANOMETALLIC COMPOUND, AND ORGANIC LIGHT-EMITTING APPARATUS INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20190058137A1

  公开（公告）日：2019-02-21

  Provided are an organometallic compound, an organic light-emitting device including the organometallic compound, and an organic light-emitting apparatus including the organic light-emitting device. Organic light-emitting devices including the organometallic compound may have a low driving voltage, high efficiency, and high luminance, thereby implementing high-quality organic light-emitting devices and organic light-emitting apparatuses.

  提供了一种有机金属化合物，包括该有机金属化合物的有机发光器件，以及包括该有机发光器件的有机发光装置。包括该有机金属化合物的有机发光器件可能具有低驱动电压、高效率和高亮度，从而实现高质量的有机发光器件和有机发光装置。