4,5-Difluoro-4-methyl-2,2-bis(trifluoromethyl)-1,3-dioxolane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,5-Difluoro-4-methyl-2,2-bis(trifluoromethyl)-1,3-dioxolane
• 英文别名: 4,5-difluoro-4-methyl-2,2-bis(trifluoromethyl)-1,3-dioxolane
• 化学式: C₆H₄F₈O₂
• 分子量: 260.08
• InChiKey: SRIYJWFYWTZSHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  10

文献信息

• Method for producing fluorine-containing compound having iodine atom content reduced
  申请人：AGC Inc.

  公开号：US10604461B2

  公开（公告）日：2020-03-31

  The purpose of the present invention is to obtain a fluorine-containing compound which is easily stabilized without irradiation of ultraviolet light, by efficiently converting a C—I bond in an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to a C—H bond. A method for producing a fluorine-containing compound having an iodine atom content reduced than the following iodine-containing compound, which comprises subjecting an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to deiodinating treatment in the presence of an organic peroxide and a hydrogen-containing compound having a group represented by —CHR1—CHR2—CHR3— (wherein R1, R2 and R3 are each independently a hydrogen atom or an alkyl group).

  本发明的目的是通过有效地将具有-CFRf-I（其中Rf为氟原子或全氟烷基）所代表基团的含碘化合物中的C-I键转化为C-H键，获得一种无需紫外线照射即可轻松稳定的含氟化合物。一种生产碘原子含量低于下述含碘化合物的含氟化合物的方法，该方法包括在有机过氧化物和具有-CHR1-CHR2-CHR3-(其中R1、R2和R3各自独立地为氢原子或烷基)基团的含氢化合物存在下，对具有-CFRf-I(其中Rf为氟原子或全氟烷基)基团的含碘化合物进行脱碘处理。
• METHOD FOR PRODUCING FLUORINE-CONTAINING COMPOUND HAVING IODINE ATOM CONTENT REDUCED
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US20180222828A1

  公开（公告）日：2018-08-09

  The purpose of the present invention is to obtain a fluorine-containing compound which is easily stabilized without irradiation of ultraviolet light, by efficiently converting a C—I bond in an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to a C—H bond. A method for producing a fluorine-containing compound having an iodine atom content reduced than the following iodine-containing compound, which comprises subjecting an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to deiodinating treatment in the presence of an organic peroxide and a hydrogen-containing compound having a group represented by —CHR 1 —CHR 2 —CHR 3 — (wherein R 1 , R 2 and R 3 are each independently a hydrogen atom or an alkyl group).