蒽-1,5-二甲酸 | 41694-83-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 蒽-1,5-二甲酸
• 英文名称: anthracene-1,5-dicarboxylic acid
• 英文别名: 1,5-anthracenedicarboxylic acid；Anthracen-1,5-dicarbonsaeure；1,5-Dicarboxyanthracen
• CAS: 41694-83-1
• 化学式: C₁₆H₁₀O₄
• 分子量: 266.253
• InChiKey: WYNLDQIVFWSFIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2917399090

反应信息

• 作为反应物：
  描述：

  蒽-1,5-二甲酸 在 lithium aluminium tetrahydride 、 四甲基乙二胺 、 叔丁基锂 、 sodium methylate 、 sodium hydride 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 为溶剂， 反应 15.5h， 生成 1,5-bis{[dimethyl(methoxymethyl)silyl]methyl}anthracene
  参考文献：
  名称：

  Intramolecular Behaviors of Anthryldicarbenic Systems:  Dibenzo[b,f]pentalene and 1H,5H-Dicyclobuta[de,kl]anthracene

  摘要：

  9,10-Bis[methoxy(trimethylsilyl)methyl]anthracenes (24), synthesized from 9,10-dilithioanthracene (26) and bromomethoxytrimethylsilylmethane (27, 2 equiv), decompose (550-650 degreesC/10(-3) mmHg) carbenically to dibenzo[b,f]pentalene (28, > 48%). 9,10-Anthryldicarbenes 39 or their equivalents convert to pentalene 28 rather than di-peri-cyclobutanthracenes 30 and 31, benzobiphenylene 32, or extended rearrangement products 33-38. Formation of 28 from 24 raises questions with respect to the behavior of 1,3,4,6-cycloheptatetraenyl-1-carbenes 49, 2,4,5,7-cyclooctatetraenylidene 51, 2,5,7-cyclooetatriene-1,4-diylidene 52, 1,2,4,5,7-cyclooetapentaene 53, and bicyclo[4.1.0]heptatrienyl-1-carbenes 54 and to carbon-skeleton and hydrogen rearrangements of anthryldicarbenes 39 and/or their equivalents at various temperatures. 1,5-Bis [methoxy(trimethylsilyl)methyl] anthracenes (25), prepared from 1,5-diiodoanthracene (63) and methoxytrimethylsilylmethylzinc bromide (57,2 equiv) as catalyzed by PdCl2(PPh3)(2), yield the di-peri-carbenic reaction product 1H,5H-dicyclobuta[de,kl]-anthracene (30, > 40%) on pyrolysis at 550-650 degreesC/10(-3) mmHg. Proof of structure and various aspects of the mechanisms of formation of 30 are discussed.

  DOI：

  10.1021/jo010404p
• 作为产物：
  描述：

  1,5-dicyano-9,10-anthraquinone 在 ammonium hydroxide 、 硫酸 、 锌 作用下， 生成 蒽-1,5-二甲酸
  参考文献：
  名称：

  光学活性三萜烯，V. 2,7-二取代三萜烯的合成、光学分辨率和绝对构型。

  摘要：

  保留 C2 对称轴的 2,7-Dicarboxytriptycene 由 1,5-二氯蒽醌合成。三苯乙烯的光学拆分提供了 (+)- 和 (-)- 对映异构体。(+)-2,7-dicarboxytriptycene 的绝对构型通过化学相关确定为 1R,6R 与具有 1R,6S 构型的 (+)-2-methoxy-7-methoxycarbonyltriptycene 经化学转化和 X 射线结构确认使用 Bijvoet 方法进行分析。以(+)-2,7-二羧基三烯为原料，制备了一系列具有1R,6R构型的2,7-二取代三烯。

  DOI：

  10.1246/bcsj.46.605

文献信息

• Optically Active Triptycenes, V. Synthesis, Optical Resolution and Absolute Configuration of 2,7-Disubstituted Triptycenes.
  作者：Masaaki Kuritani、Yoshiteru Sakata、Fumio Ogura、Masazumi Nakagawa

  DOI：10.1246/bcsj.46.605

  日期：1973.2

  retaining C2-axis of symmetry was synthesized from 1,5-dichloroanthraquinone. Optical resolution of the triptycene afforded (+)- and (−)-enantiomers. The absolute configuration of (+)-2,7-dicarboxytriptycene was determined as 1R,6R by chemical correlation with (+)-2-methoxy-7-methoxycarbonyltriptycene which has 1R,6S configuration as confirmed by chemical transformation and X-ray structure analysis using

  保留 C2 对称轴的 2,7-Dicarboxytriptycene 由 1,5-二氯蒽醌合成。三苯乙烯的光学拆分提供了 (+)- 和 (-)- 对映异构体。(+)-2,7-dicarboxytriptycene 的绝对构型通过化学相关确定为 1R,6R 与具有 1R,6S 构型的 (+)-2-methoxy-7-methoxycarbonyltriptycene 经化学转化和 X 射线结构确认使用 Bijvoet 方法进行分析。以(+)-2,7-二羧基三烯为原料，制备了一系列具有1R,6R构型的2,7-二取代三烯。
• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Optical activity of C2 symmetrical 9,10-dihydro-9,10-ethanoanthracenes
  作者：S. Hagishita、K. Kuriyama

  DOI：10.1016/0040-4020(72)88028-1

  日期：1972.1

  Optically active C2-symmetrical 9,10-dihydro-9,10-ethanoanthracene (DEA) derivatives have been prepared and their absolute configurations determined by kinetic resolution of phenylmethylcarbinol with optically active DEA-11,12-dicarboxylic acid chloride, spectroscopic studies and chemical correlations. The rotational strengths for the α- and the p-band regions calculated from the dipole-velocity procedure

  制备了旋光的C 2对称的9,10-二氢-9,10-乙基蒽（DEA）衍生物，并通过用旋光的DEA-11,12-二羧酸氯化物动力学拆分苯基甲基甲醇确定了它们的绝对构型，并进行了光谱研究和化学相关性。α-和p的旋转强度由π-SCF近似中的偶极速度过程计算出的带区，而不是点偶极激子处理，与实验吻合良好。尽管旋转强度主要是由局部激励的耦合产生的，但在某些情况下，电荷转移构型会导致A和B组合的跃迁能顺序在励磁构型中发生反转。这是基于激子近似的实验结果和计算结果之间不一致的最重要因素，其中假定两个发色团之间没有电子交换。
• Studies on Chemiluminescent Compounds. I. Syntheses of Acylsubstituted Anthracene Derivatives and Their Chemiluminescence
  作者：Toshiyuki Hiramatsu、Toshiaki Harada、Teizo Yamaji

  DOI：10.1246/bcsj.54.985

  日期：1981.4

  New anthracene derivatives with a –COCH– group, such as 1,5-dipropionylanthracene, 1,8-dipropionylanthracene, 1,5-di-isobutyrylanthracene, 1,8-diisobutyrylanthracene, 1,5-bis[3-(methoxycarbonyl)propionyl]anthracene, 1,8-bis[3-(methoxycarbonyl)propionyl] anthracene, 1,5-bis(cyclohexylcarbonyl) anthracene, 3,7-diisopropyl-1,5-diisobutyrylanthracene, and 5-dimethylamino-4-isobutyryl-1-methoxyanthracene

  具有-COCH-基团的新型蒽衍生物，例如1,5-二丙酰基蒽、1,8-二丙酰基蒽、1,5-二异丁酰基蒽、1,8-二异丁酰基蒽、1,5-双[3-(甲氧基羰基)丙酰基]蒽、1,8-双[3-(甲氧基羰基)丙酰基]蒽、1,5-双(环己基羰基)蒽、3,7-二异丙基-1,5-二异丁酰基蒽和5-二甲氨基-4-异丁酰基-1 -甲氧基蒽（10）已被合成。通过在碱性溶液中的空气氧化研究了它们的直接化学发光。已发现化学发光的性质不仅受与羰基相邻的 C-H 键类别的影响，还受芳环系统、溶剂和添加剂的电子性质的影响。10 表现出最长的化学发光。
• Reactive polymer-supporting porous film for battery seperator and use thereof
  申请人：Uetani Yoshihiro

  公开号：US20060257727A1

  公开（公告）日：2006-11-16

  The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a polycarboxylic acid. The reactive polymer-supporting porous film for use as a battery separator has a separator and electrodes sufficiently bonded to each other and low inner resistance so that it is suitably used for production of battery excellent in high rate performance. Further, the invention provides a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and the electrodes together.

  本发明提供一种反应性聚合物支持多孔膜，用于作为电池隔膜，包括多孔基底膜和部分交联的反应性聚合物支持在多孔基底膜上，所述部分交联的反应性聚合物是通过交联性聚合物与多羧酸反应而得到的，所述交联性聚合物在分子中至少具有3-氧杂环基团和环氧基团中的一种反应性基团。作为电池隔膜使用的反应性聚合物支持多孔膜，具有足够紧密结合的隔膜和电极以及低内阻，因此适用于生产高速性能优异的电池。此外，本发明还提供一种电池的制造方法，其中包括将电极/反应性聚合物支持多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解液，从而将多孔膜和电极粘合在一起。