syn-7-Methoxynorbornene | 86137-04-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: syn-7-Methoxynorbornene
• 英文别名: 7-Methoxybicyclo[2.2.1]hept-2-ene
• CAS: 86137-04-4
• 化学式: C₈H₁₂O
• 分子量: 124.183
• InChiKey: RELKQDGGKGDNGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  syn-7-Methoxynorbornene 、 烯丙基硼酸频哪醇酯 在 [Mo(CHCMe₂Ph)(adamantylimido)((OC₆H(Me)2C(CH₃)3)2)] 作用下， 以 苯 为溶剂， 生成 2-[3-(2-methoxy-3-vinylcyclopentyl)allyl]-4,4,5,5-tetramethyl[1,3,2]dioxaborolane 、 2-[3-(2-methoxy-3-vinylcyclopentyl)allyl]-4,4,5,5-tetramethyl[1,3,2]dioxaborolane
  参考文献：
  名称：

  对映体纯的金刚烷亚氨基钼亚烷基络合物。一种用于对映选择性烯烃复分解的有效新催化剂

  摘要：

  制备了带有烷基亚氨基配体的对映异构纯 Mo 基复合物，并通过 NMR 光谱和 X 射线分析对其进行表征。Mo配合物4是唯一报道的手性烷基亚氨基催化剂；所有以前的手性配合物都是芳基亚氨基体系。这些研究表明，手性 Mo 催化剂仅作为顺式异构体存在，并且它在不对称烯烃复分解中提供了独特的反应性和选择性。

  DOI：

  10.1021/ja021204d

文献信息

• Polymerizable Fluorine-Containing Compound
  申请人：ISONO Yoshimi

  公开号：US20110098500A1

  公开（公告）日：2011-04-28

  A polymerizable fluorine-containing compound represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 2 represents an acid-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 2 , R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a resist composition capable of forming a pattern that is transparent to exposure light and superior in rectangularity.

  一种可聚合的含氟化合物，其化学式为（1），其中R1表示可聚合的双键含有基团，R2表示酸敏感保护基团，R3表示氟原子或含氟烷基团，W表示二价连接基团。该化合物可以提供一种含氟聚合物化合物，其重均分子量为1,000-1,000,000，并包含由式（2）表示的重复单元，其中R2、R3和W如上所述，R4、R5和R6中的每一个独立地表示氢原子、氟原子或一价有机基团，至少两个R4、R5和R6可以结合形成一个环。该聚合物化合物可以提供一种抗蚀剂组合物，能够形成透明的曝光光线图案，并具有优异的矩形度。
• Fluorine-Containing Compound, Fluorine-Containing Polymer, Postive-Type Resist Composition, And Patterning Process Using Same
  申请人：ISONO Yoshimi

  公开号：US20080311507A1

  公开（公告）日：2008-12-18

  Disclosed is a fluorine-containing compound represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 2 represents an acid-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 2 , R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a resist composition capable of forming a pattern that is transparent to exposure light and superior in rectangularity.

  本发明涉及一种含氟化合物，其化学式为（1），其中R1代表可聚合的双键含基团，R2代表酸易保护基，R3代表氟原子或含氟烷基团，W代表双价连结基团。该化合物可提供一种含氟聚合物化合物，其重均分子量为1,000-1,000,000，并含有由式（2）所表示的重复单元，其中R2、R3和W如上所定义，R4、R5和R6中的每一个独立地代表氢原子、氟原子或一价有机基团，其中至少两个R4、R5和R6可以组成环。该聚合物化合物可提供一种抗蚀剂组合物，能够形成对曝光光线透明且在矩形度方面优越的图案。
• Positive-Type Resist Composition
  申请人：ISONO Yoshimi

  公开号：US20090061353A1

  公开（公告）日：2009-03-05

  Disclosed is a fluorine-containing polymer compound containing first and second repeating units respectively represented by formulas (a-1) and (a-2), wherein R 3 represents a fluorine atom or fluorine-containing alkyl group, each of W and W 1 independently represents a bivalent linking group, R 2 represents an acid-labile protecting group, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, and at least two of R 4 , R 5 , R 6 and W or W 1 may be combined to form a cyclic structure in formula (a-1) or (a-2). This polymer compound has a weight-average molecular weight of 1,000 to 1,000,000 and can provide a resist composition capable of forming a pattern with no swelling and no pattern falling down.

  本发明涉及一种含氟聚合物化合物，其中包含第一和第二重复单元，分别由式（a-1）和（a-2）表示，其中R3表示氟原子或含氟烷基，W和W1各自表示双价连接基团，R2表示酸敏保护基团，R4、R5和R6各自表示氢原子、氟原子或单价有机基团，且式（a-1）或（a-2）中至少两个R4、R5、R6和W或W1可组成环状结构。该聚合物化合物具有1,000至1,000,000的重均分子量，并可提供一种抗膨胀和无图案脱落的光刻胶组合物。
• Stereodirecting effect of a substrate methoxy substituent on the addition of singlet methylene to a double bond
  作者：Terry A. Young、Colleen O'Rourke、Nathan B. Gray、Brian D. Lewis、Curt A. Dvorak、Kan Shuh Kuen、JoAnn P. DeLuca

  DOI：10.1021/jo00075a016

  日期：1993.11

  The stereodirecting effects of substrate methoxy, hydroxy, methylthio, and methyl substituents were examined in the addition of 1:CH2 to the double bonds of substrates 1a-d. The carbene, generated by photolysis of CH2N2, inserted into the C-H bonds of solvent and substrate, added to the substrate double bond to give products 2a-d, and attacked the oxygen or sulfur atom of substrates 1a-c to produce ylide intermediates which underwent 2,3-sigmatropic rearrangement to give products 3a-c. A preference for addition syn to the methoxy group of substrate 1a was observed when the reaction was run in pentane solution (syn-2a/anti-2a, 1.14 +/- 0.02), while a preference for formation of anti-2a was observed in diethyl ether solution (syn-2a/anti-2a, 0.92 +/- 0.03). A preference for 1:CH2 addition anti to the substrate substituent was observed for substrates 1b-d in both pentane and ether solution. The effect of the methoxy substituent was also examined in the addition of 1:CH2 to syn-7-methoxynorbornene (5b). Explanations for the substituent effects are offered based on both steric hindrance and interaction between 1:CH2 and the substituent, including formation and subsequent reaction of the ylide intermediates.
• US7887990B2
  申请人：——

  公开号：US7887990B2

  公开（公告）日：2011-02-15