1-Methyl-1-azonia-3,5,7-adamantan | 48113-49-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪烷类
• 英文名称: 1-Methyl-1-azonia-3,5,7-adamantan
• 英文别名: N-Methyl-hexaminium；1-methyl-hexamethylenetetramine cation；1-Methyl-3,5,7-triaza-1-azoniatricyclo(3.3.1.13,7)decane iodide；1-methyl-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane
• CAS: 48113-49-1
• 化学式: C₇H₁₅N₄
• 分子量: 155.223
• InChiKey: ZWRDTZZCWMQVJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  盐酸甲胺 、 乙酸酐 、 1-Methyl-1-azonia-3,5,7-adamantan 在 溶剂黄146 作用下， 生成 1,3-dimethyl-hexamethylenetetraminediium; dinitrate
  参考文献：
  名称：

  Foss et al., Journal of the Chemical Society, 1950, p. 1691,1695

  摘要：

  DOI：

文献信息

• Oxypentafluorosulfate compositions and processes for making them
  申请人：Syvret Robert George

  公开号：US20080033164A1

  公开（公告）日：2008-02-07

  Novel compositions are provided containing a compound represented by the formula YOSF 5 or ZOSF 5 , where: (a) Y is: (i) an organic cation other than (Me 2 N) 3 S + or (ii) an inorganic cation, provided that when Y is the inorganic cation, the composition further includes a complexing agent; and (b) Z is C 1-20 alkyl, aryl, cycloalkyl, combinations thereof, or analogues thereof containing at least one heteroatom, provided that the compound represented by the formula ZOSF 5 is a molecular compound. Processes of making the cationic compounds are disclosed as are processes for using the compositions containing cationic compounds in nucleophilic replacement reactions to prepare the compositions containing molecular compounds including the OSF 5 group.

  提供含有由公式YOSF5或ZOSF5表示的化合物的小说组合物，其中：(a) Y是：(i) 除(Me2N)3S+之外的有机阳离子，或者(ii) 无机阳离子，但是当Y是无机阳离子时，组合物还包括络合剂；和(b) Z是C1-20烷基，芳香族，环烷基，它们的组合物，或者至少含有一个杂原子的类似物，但是由公式ZOSF5表示的化合物是一个分子化合物。公开了制备阳离子化合物的方法，以及使用含有阳离子化合物的组合物进行亲核取代反应以准备含有OSF5基团的分子化合物的方法。
• ORGANIC SYNTHESIS APPLICATIONS OF NON-AQUEOUS FLUORIDE SALT SOLUTIONS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20170057908A1

  公开（公告）日：2017-03-02

  Processes and reaction mixtures including non-aqueous solvent mixtures are presented. Non-aqueous solvent mixtures including fluoride salt and non-aqueous solvent combinations are provided that possess high fluoride ion concentrations useful for a range of applications, including organic synthesis. Further non-aqueous solvent mixtures are provided including a salt possessing a non-fluoride anion and a non-aqueous solvent that, when contacted with aqueous fluoride-containing reagents, extract fluoride ions to form non-aqueous fluoride-ion solutions possessing high fluoride-ion concentrations. The salts include an organic cation that does not possess a carbon in the β-position or does not possess a carbon in the β-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. The combination of these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents.

  提供了包括非水溶剂混合物的过程和反应混合物。提供了包括氟化物盐和非水溶剂组合的非水溶剂混合物，其具有高氟离子浓度，可用于一系列应用，包括有机合成。还提供了包括具有非氟离子的盐和非水溶剂的非水溶剂混合物，当与含氟化物的水溶试剂接触时，提取氟离子以形成具有高氟离子浓度的非水溶性氟离子溶液。这些盐包括一个有机阳离子，该阳离子在β位不含碳或在β位含有结合氢的碳。这种盐的结构有助于使其在无水条件下不分解。例如，无水氟化物盐包括(2,2-二甲基丙基)三甲基铵氟化物和双(2,2-二甲基丙基)二甲基铵氟化物。这些氟化物盐与至少一种含氟非水溶剂（例如双(2,2,2-三氟乙基)醚；(BTFE)）的组合促进了盐在非水溶剂中的溶解度。
• Crystallization of organically templated phosphomolybdate cluster-based solids from aqueous solution
  作者：MINAKSHI ASNANI、DINESH KUMAR、T DURAISAMY、ARUNACHALAM RAMANAN

  DOI：10.1007/s12039-012-0328-z

  日期：2012.11

  The paper reports the synthesis and structural characterization of several organic–inorganic solids involving phosphomolybdate clusters. The Strandberg-type P2Mo\(_5}^\rm VI}\)O23} and the lower-valent P4Mo\(_6}^\rm V}\)O31} cluster based solids were isolated in the presence of en (ethylenediamine) by controlling pH of the reaction medium. The lower-valent cluster invariably requires the presence

  该论文报道了几种涉及磷钼酸盐团簇的有机-无机固体的合成和结构表征。Strandberg型P 2 Mo \（_ 5} ^ \ rm VI} \） O 23 }和低价P 4 Mo \（_ 6} ^ \ rm V} \） O 31在存在en的情况下分离出基于团簇的固体通过控制反应介质的pH值（乙二胺）。低价簇总是需要存在合适的金属阳离子以进一步稳定。对系统进行了详细的研究，其中发现了三种不同的弱酸。草酸，琥珀酸和甘氨酸用于整个pH范围（1–12）。我们的结果表明，在适当的pH值下不存在有机酸的情况下，有机胺（en）单独能够还原钼核。因此，反应介质的pH与合适的温度结合有利于形成低价的磷钼酸盐簇。较高的pH值有利于沉淀出新的磷酸氢钠。 两种类型的磷钼酸盐簇，分别是完全氧化的Strandberg型P 2 Mo 5 VI O 23 }和完全还原的P 4 Mo 6 V O 31 }，可以
• METHOD OF FORMING PATTERN AND COMPOSITION FOR FORMING OF ORGANIC THIN-FILM FOR USE THEREIN
  申请人：Shimizu Daisuke

  公开号：US20100233635A1

  公开（公告）日：2010-09-16

  A method for forming a pattern contains (1) a step of forming an underlayer film containing (A) a radiation-sensitive acid generator capable of generating an acid upon exposure to radiation rays or (B) a radiation-sensitive base generator capable of generating a base upon exposure to radiation rays on a substrate; (2) a step of irradiating the underlayer film with radiation rays through a mask with a predetermined pattern to obtain an exposed underlayer film portion having been selectively exposed through the predetermined pattern; (3) a step of forming (C) an organic thin film on the underlayer film so as to attain chemical bonding of the exposed underlayer film portion with the organic thin-film formed on the exposed underlayer film portion; and (4) a step of removing the organic thin film formed on areas of the underlayer film other than the exposed underlayer film portion.

  一种形成图案的方法包括：（1）在基板上形成一个底层薄膜，该底层薄膜包含（A）一种辐射敏感的酸发生剂，能够在辐射射线的作用下产生酸，或者（B）一种辐射敏感的碱发生剂，能够在辐射射线的作用下产生碱；（2）通过一个预定图案的掩模，用辐射射线照射底层薄膜，以获得已通过预定图案选择性暴露的底层薄膜部分；（3）在底层薄膜上形成一层有机薄膜，以实现暴露的底层薄膜部分与形成在暴露的底层薄膜部分上的有机薄膜的化学键合；（4）去除除暴露的底层薄膜部分外的底层薄膜区域上形成的有机薄膜。
• Photobase generator and curable composition
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1564255B1

  公开（公告）日：2007-09-26