magnesium;2-ethoxyethanolate | 46142-17-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: magnesium;2-ethoxyethanolate
• CAS: 46142-17-0
• 化学式: C8H18MgO4
• 分子量: 202.53
• InChiKey: CVPGMAAATOZCID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.61
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  64.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  magnesium;2-ethoxyethanolate 、 二(2-乙氧基乙醇)二(2-乙氧基乙醇)-钛 生成 Magnesium;dioxido(oxo)titanium
  参考文献：
  名称：

  SCHMIDT, F.;FELTZ, A., Z. ANORG. UND ALLG. CHEM., 573,(1989) N, C. 208-214

  摘要：

  DOI：
• 作为产物：
  描述：

  乙二醇乙醚 生成 magnesium;2-ethoxyethanolate
  参考文献：
  名称：

  OSWALD, ALEXIS A.;BHATIA, RAM N.;MOZELCAKI, EDMUND J.;BROWNAWELL, DARRELL+

  摘要：

  DOI：

文献信息

• Ziegler-Natta catalyst and a process for its preparation
  申请人：BP Chemicals Limited

  公开号：EP0319173A1

  公开（公告）日：1989-06-07

  A process for the preparation of a solid catalyst of the Ziegler-Natta type comprises precipitating the solid catalyst in a liquid hydrocarbon medium by reacting (A) a solution of a soluble magnesium alkoxide and (B) a transition metal halide which is a halide of Ti (IV), a halide of V (IV) or a halide of VO (III) in the presence of (C) at least one transition metal alkoxide which is free from halogen and soluble in liquid hydrocarbon. The precipitated solid catalyst consists of spheroidal particles having a mean diameter by mass of from 10 to 70 microns and a narrow particle size distribution such that the ratio of mean diameter by mass to the mean diameter by number is greater than 1.2 and smaller than 2.0.

  制备齐格勒-纳塔型固体催化剂的工艺包括在液态烃介质中沉淀固体催化剂，沉淀方法是：(A)可溶性氧化镁溶液和(B)过渡金属卤化物，过渡金属卤化物为Ti(IV)的卤化物、V(IV)的卤化物或VO(III)的卤化物，反应物为(C)至少一种不含卤素且可溶于液态烃的过渡金属氧化物。沉淀的固体催化剂由球形颗粒组成，其质量平均直径为 10 至 70 微米，粒度分布窄，质量平均直径与数量平均直径之比大于 1.2，小于 2.0。
• Modifield catalyst composition for polymerizing alpha-olefins
  申请人：MOBIL OIL CORPORATION

  公开号：EP0364636A1

  公开（公告）日：1990-04-25

  A modified catalyst for polymerizing alpha-olefins, for example, ethylene, is prepared by combining a chromium compound-comprising catalyst, supported on a refractory oxide support with at least one catalyst modifier of the formula R Mg R′ where R and R′ are the same or different C₁-C₁₂ hydrocarbyl, alkoxy, alkenoxy or oxygenated aromatic groups. The amount of the modifier is such that the modified catalyst composition has the molar ratio of magnesium to chromium of 0.2 to 1.25. The modified catalyst composition produces resins of relatively high HLMI at relatively low temperatures. There is also disclosed a process for polymerizing alpha-olefins, at relatively lower temperatures than was heretofore possible, to obtain resins of relatively high HLMI, using the modified catalyst composition. The resulting polymers can be used for the fabrication of blow-molded products, e.g., household and industrial containers.

  一种用于聚合α-烯烃（例如乙烯）的改性催化剂的制备方法是将一种含铬化合物的催化剂与至少一种式 R Mg R′的催化剂改性剂相结合，其中 R 和 R′是相同或不同的 C₁-C₁₂烃基、烷氧基、烯氧基或含氧芳香基。改性剂的用量应使改性催化剂组合物中镁与铬的摩尔比为 0.2 至 1.25。改性催化剂组合物能在相对较低的温度下生产出相对较高 HLMI 的树脂。 此外，还公开了一种使用改性催化剂组合物在比以前更低的温度下聚合α-烯烃以获得相对较高 HLMI 树脂的工艺。得到的聚合物可用于制造吹塑产品，如家用和工业容器。
• SCHMIDT, F.;FELTZ, A., Z. ANORG. UND ALLG. CHEM., 573,(1989) N, C. 208-214
  作者：SCHMIDT, F.、FELTZ, A.

  DOI：——

  日期：——
• OSWALD, ALEXIS A.;BHATIA, RAM N.;MOZELCAKI, EDMUND J.;BROWNAWELL, DARRELL+
  作者：OSWALD, ALEXIS A.、BHATIA, RAM N.、MOZELCAKI, EDMUND J.、BROWNAWELL, DARRELL+

  DOI：——

  日期：——
• FELTZ, ADALBERT;SCHMIDT, FRANK, Z. CHEM., 27,(1987) N 11, 414-415
  作者：FELTZ, ADALBERT、SCHMIDT, FRANK

  DOI：——

  日期：——